Effect of Re on the Microstructure and Mechanical Properties of NbTiZr and TaTiZr Equiatomic Alloys
Abstract
:1. Introduction
2. Materials and Methods
3. Results
3.1. Mechanical Properties
3.2. X-ray Diffraction
3.3. Microstructure
3.3.1. NbTiZr
3.3.2. TaTiZr
3.3.3. Re0.3NbTiZr
3.3.4. Re0.3TaTiZr
4. Discussion
4.1. Effect of Re on the Microstructure and Phase Composition
4.1.1. NbTiZr and TaTiZr
4.1.2. Re0.3NbTiZr
4.1.3. Re0.3TaTiZr
4.2. Effect of Re on Mechanical Properties
5. Summary and Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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ρ g/cm3 | Nb at.% | Re at.% | Ta at.% | Ti at.% | Zr at.% | O ppm | N ppm | C ppm | |
---|---|---|---|---|---|---|---|---|---|
NbTiZr | 6.63 | 35.6 | - | - | 32.5 | 31.9 | 120 | 63 | 21 |
TaTiZr | 9.06 | - | - | 32.3 | 33.8 | 33.9 | 70 | 20 | 21 |
Re0.3NbTiZr | 7.85 | 28.8 | 10.6 | - | 31.4 | 29.0 | 90 | 20 | 16 |
Re0.3TaTiZr | 9.90 | - | 9.3 | 30.2 | 29.5 | 31.0 | 110 | 20 | 17 |
Alloy | NbTiZr | Re0.3NbTiZr | TaTiZr | Re0.3TaTiZr |
---|---|---|---|---|
Hv (GPa) | 3.40 ± 0.02 | 4.14 ± 0.08 | 4.36 ± 0.07 | 5.40 ± 0.14 |
T, °C | Property | NbTiZr | TaTiZr | Re0.3NbTiZr | Re0.3TaTiZr |
---|---|---|---|---|---|
25 | σy, MPa εf | 920 ± 18 >0.6 | 1670 ± 30 0.025 ± 0.005 | 1220 ± 24 0.53 ± 0.07 | 1715 ± 30 0.10 ± 0.01 |
800 | σy, MPa εf * | 465 ± 9 >0.69 | 157 ± 6 >0.69 | 805 ± 15 >0.69 | 243 ± 7 >0.69 |
1000 | σy, MPa εf * | 146 ± 5 >0.69 | 103 ± 5 >0.69 | 323 ± 8 >0.69 | 122 ± 5 >0.69 |
1200 | σy, MPa εf * | 61 ± 3 >0.69 | 63 ± 3 >0.69 | 89 ± 4 >0.69 | 71 ± 3 >0.69 |
Alloy | HIP’d at 1400 °C | Deformed at 1000 °C |
---|---|---|
NbTiZr | BCC, a = 0.3404 nm | BCC, a = 0.3404 nm |
Re0.3NbTiZr | BCC, a = 0.3346 nm | BCC, a = 0.3352 nm |
FCC, a = 0.7560 nm | FCC, a = 0.7569 nm | |
TaTiZr | BCC1, a = 0.3421 nm | BCC1, a = 0.3488 nm |
BCC2, a = 0.3320 nm | BCC2, a = 0.3316 nm | |
Re0.3TaTiZr | BCC1, a = 0.3423 nm | BCC1, a = 0.3501 nm |
BCC2, a = 0.3255 nm | BCC2, a = 0.3269 nm |
Element | Ta | Ti | Zr |
---|---|---|---|
Matrix (BCC1) | 15.8 ± 5.0 | 33.0 ± 4.1 | 51.2 ± 4.2 |
Particles (BCC2) | 62.7 ± 3.1 | 27.1 ± 1.8 | 10.2 ± 2.2 |
Condition | Constituent | Vf | Re | Nb | Ti | Zr |
---|---|---|---|---|---|---|
HIP’d | Matrix phase | 0.86 | 7.5 ± 0.9 | 33.4 ± 0.4 | 31.3 ± 1.0 | 27.8 ± 0.4 |
Particles | 0.14 | 33.2 ± 2.3 | 15.5 ± 0.5 | 19.2 ± 0.8 | 32.0 ± 1.1 | |
Deformed | Matrix phase | 0.87 | 7.7 ± 1.1 | 31.9 ± 1.0 | 31.6 ± 0.6 | 28.9 ± 0.7 |
Particles | 0.13 | 33.7 ± 0.5 | 14.4 ± 0.5 | 19.6 ± 0.5 | 32.3 ± 0.4 |
Condition | Constituent | Vf | Re | Ta | Ti | Zr |
---|---|---|---|---|---|---|
HIP’d | Matrix | 0.53 | 1.1 ± 0.1 | 9.4 ± 0.5 | 35.1 ± 0.5 | 54.4 ± 0.7 |
Particles | 0.47 | 15.1 ± 0.8 | 53.3 ± 0.9 | 24.8 ± 0.5 | 6.8 ± 0.3 | |
Deformed | Matrix | 0.52 | 1.2 ± 0.1 | 8.7 ± 0.5 | 35.6 ± 0.4 | 54.5 ± 0.7 |
Particles | 0.48 | 17.6 ± 0.1 | 49.3 ± 0.1 | 27.1 ± 0.2 | 6.0 ± 0.1 |
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Senkov, O.N.; Gorsse, S.; Wheeler, R.; Payton, E.J.; Miracle, D.B. Effect of Re on the Microstructure and Mechanical Properties of NbTiZr and TaTiZr Equiatomic Alloys. Metals 2021, 11, 1819. https://0-doi-org.brum.beds.ac.uk/10.3390/met11111819
Senkov ON, Gorsse S, Wheeler R, Payton EJ, Miracle DB. Effect of Re on the Microstructure and Mechanical Properties of NbTiZr and TaTiZr Equiatomic Alloys. Metals. 2021; 11(11):1819. https://0-doi-org.brum.beds.ac.uk/10.3390/met11111819
Chicago/Turabian StyleSenkov, Oleg N., Stéphane Gorsse, Robert Wheeler, Eric J. Payton, and Daniel B. Miracle. 2021. "Effect of Re on the Microstructure and Mechanical Properties of NbTiZr and TaTiZr Equiatomic Alloys" Metals 11, no. 11: 1819. https://0-doi-org.brum.beds.ac.uk/10.3390/met11111819