High-Temperature Oxidation Resistance of Alumina-Forming Austenitic Stainless Steels Optimized by Refractory Metal Alloying
Abstract
:1. Introduction
2. Principles of Alloy Design
3. Materials and Methods
4. Results and Discussion
4.1. Microstructural Characterization
4.2. Hardness
4.3. High-Temperature Oxidation Resistance
5. Conclusions
- All samples exhibit single austenitic structure both after solutionizing at 1250 °C/1.5 h and aging at 800 °C/24 h.
- The hardness, under a load of 500 g, is approximately 150 HV at solutionizing state and 200 HV at aging state, which falls in the estimated range of Oak Ridge National Laboratory.
- After being air oxidized at 800 °C for up to 200 h, most samples can be classified to complete oxidation resistance level for their low oxidation rate, below 0.1 g/m2 × h, together with low oxidation-peeling mass, below 1.0 g/m2. Among them, Nb0.03Ta0.03Ni3.2Mo0.2, Nb0.03Ta0.03Ni3.2Mo0.07 and Nb0.06Ni3.2Mo0.04W0.03, which possess continuous Al2O3 layers with internal AlN particles, possess the lowest weight gain and thus the best high-temperature oxidation resistance. In contrast, the alloys without Ta and W have Cr2O3-type layers and internal Al2O3 particles.
- The addition of Ta or W promotes the formation of a continuous protective Al2O3 layer that inhibits oxygen from further diffusion inwards. In addition, W seems to inhibit nitrogen diffusion and additionally promote oxidation peeling, which is inferred from the thinnest internal nitride zone and highest oxidation peeling mass of Nb0.06Ni3.2Mo0.04W0.03, among all Ta/W containing alloys.
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
- Nie, S.H.; Chen, Y.; Ren, X.; Sridharan, K.; Allen, T.R. Corrosion of alumina-forming austenitic steel Fe–20Ni–14Cr–3Al–0.6Nb–0.1Ti in supercritical water. J. Nucl. Mater. 2010, 399, 231–235. [Google Scholar] [CrossRef]
- Kondo, K.; Miwa, Y.; Okubo, N.; Kaji, Y.; Tsukada, T. Development of corrosion-resistant improved Al-doped austenitic stainless steel. J. Nucl. Mater. 2011, 417, 892–895. [Google Scholar] [CrossRef]
- Xing, L.L.; Zheng, Y.J.; Yang, W.W.; Shao, M.Z.; Cui, L.S.; Lu, G.W. Effect of aluminum on high temperature oxidation resistance of alloy HK40. Corros. Sci. Prot. Technol. 2012, 24, 20–24. [Google Scholar]
- Fujioka, T.; Kinugasa, M.; Iizumi, S.; Teshima, S.; Shimizu, I. Oxidation-resisting austenitic stainless steel. U.S. Patent 4,108,641, 22 August 1978. [Google Scholar]
- Pivin, J.C.; Delaunay, D.; Roques-Carmes, C.; Huntz, A.M.; Lacombe, P. Oxidation mechanism of Fe-Ni-20-25Cr-5Al alloys-influence of small amounts of yttrium on oxidation kinetics and oxide adherence. Corros. Sci. 1980, 20, 351–373. [Google Scholar] [CrossRef]
- Ramakrishnan, V.; Mcgurty, J.A.; Jayaraman, N. Oxidation of high-aluminum austenitic stainless steels. Oxid. Met. 1988, 30, 185–200. [Google Scholar] [CrossRef]
- Satyanarayana, D.V.V.; Malakondaiah, G.; Sarma, D.S. Steady state creep behaviour of NiAl hardened austenitic steel. Mater. Sci. Eng. A 2002, 323, 119–128. [Google Scholar] [CrossRef]
- Pint, B.A.; Peraldi, R.; Maziasz, P.J. The use of model alloys to develop corrosion-resistant stainless steels. Mater. Sci. Forum 2004, 461, 815–822. [Google Scholar] [CrossRef]
- Adams, T.M.; Korinko, P.; Duncan, A. Evaluation of oxidation and hydrogen permeation in Al-containing stainless steel alloys. Mater. Sci. Eng. A 2006, 424, 33–39. [Google Scholar] [CrossRef]
- Brady, M.P.; Yamamoto, Y.; Santella, M.L.; Pint, B.A. Effects of minor alloy additions and oxidation temperature on protective alumina scale formation in creep-resistant austenitic stainless steels. Scripta Mater. 2007, 57, 1117–1120. [Google Scholar] [CrossRef]
- Yamamoto, Y.; Brady, M.P.; Lu, Z.P.; Liu, C.T.; Takeyama, M.; Maziasz, P.J.; Pint, B.A. Alumina-forming austenitic stainless steels strengthened by Laves phase and MC carbide precipitates. Metall. Mater. Trans. A 2007, 38, 2737–2746. [Google Scholar] [CrossRef]
- Yamamoto, Y.; Brady, M.P.; Lu, Z.P.; Maziasz, P.J.; Liu, C.T.; Pint, B.A.; More, K.L.; Meyer, H.M.; Payzant, E.A. Creep-resistant, Al2O3-forming austenitic stainless steels. Science 2007, 316, 433–436. [Google Scholar] [CrossRef] [PubMed]
- Brady, M.P.; Yamamoto, Y.; Santella, M.L.; Maziasz, P.J.; Pint, B.A.; Liu, C.T.; Lu, Z.P.; Bei, H. The development of alumina-forming austenitic stainless steels for high-temperature structural use. JOM 2008, 60, 12–18. [Google Scholar] [CrossRef]
- Yamamoto, Y.; Brady, M.P.; Santella, M.L.; Bei, H.; Maziasz, P.J.; Pint, B.A. Development of alumina-forming austenitic stainless steels. In Proceedings of the 22nd Annual Conference on Fossil Energy Materials, Pittsburgh, PA, USA, 8–10 July 2008. [Google Scholar]
- Yamamoto, Y.; Takeyama, M.; Lu, Z.P.; Liu, C.T.; Evans, N.D.; Maziasz, P.J.; Brady, M.P. Alloying effects on creep and oxidation resistance of austenitic stainless steel alloys employing intermetallic precipitates. Intermetallics 2008, 16, 453–462. [Google Scholar] [CrossRef]
- Brady, M.P.; Yamamoto, Y.; Santella, M.L.; Walker, L.R. Composition, microstructure, and water vapor effects on internal/external oxidation of alumina-forming austenitic stainless steels. Oxid. Met. 2009, 72, 311–333. [Google Scholar] [CrossRef]
- Pint, B.A.; Brady, M.P.; Yamamoto, Y.; Santella, M.L.; Howe, J.Y.; Trejo, R.; Maziasz, P.J. Development of alumina-forming austenitic alloys for advanced recuperators. In Proceedings of the ASME Turbo Expo 2009: Power for Land, Sea, and Air, Orlando, FL, USA, 8–12 June 2009; pp. 271–280. [Google Scholar]
- Yamamoto, Y.; Santella, M.L.; Brady, M.P.; Bei, H.; Maziasz, P.J. Effect of alloying additions on phase equilibria and creep resistance of alumina-forming austenitic stainless steels. Metall. Mater. Trans. A 2009, 40, 1868–1880. [Google Scholar] [CrossRef]
- Yamamoto, Y.; Santella, M.L.; Liu, C.T.; Evans, N.D.; Maziasz, P.J.; Brady, M.P. Evaluation of Mn substitution for Ni in alumina-forming austenitic stainless steels. Mater. Sci. Eng. A 2009, 524, 176–185. [Google Scholar] [CrossRef]
- Bei, H.; Yamamoto, Y.; Brady, M.P.; Santella, M.L. Aging effects on the mechanical properties of alumina-forming austenitic stainless steels. Mater. Sci. Eng. A 2010, 527, 2079–2086. [Google Scholar] [CrossRef]
- Brady, M.P.; Unocic, K.A.; Lance, M.J.; Santella, M.L.; Yamamoto, Y.; Walker, L.R. Increasing the upper temperature oxidation limit of alumina forming austenitic stainless steels in air with water vapor. Oxid. Met. 2011, 75, 337–357. [Google Scholar] [CrossRef]
- Pint, B.A.; Brady, M.P.; Yamamoto, Y.; Santella, M.L.; Maziasz, P.J.; Matthews, W.J. Evaluation of alumina-forming austenitic foil for advanced recuperators. J. Eng. Gas Turb. Power 2011, 133, 102301–102302. [Google Scholar] [CrossRef]
- Yamamoto, Y.; Brady, M.P.; Santella, M.L.; Bei, H.; Maziasz, P.J.; Pint, B.A. Overview of strategies for high-temperature creep and oxidation resistance of alumina-forming austenitic stainless steels. Metall. Mater. Trans. A 2011, 42, 922–931. [Google Scholar] [CrossRef] [Green Version]
- Yamamoto, Y.; Muralidharan, G.; Brady, M.P. Development of L12-ordered Ni3(Al,Ti)-strengthened alumina-forming austenitic stainless steel alloys. Scripta Mater. 2013, 69, 816–819. [Google Scholar] [CrossRef]
- Hull, F.C. Delta ferrite and martensite formation in stainless steels. Weld. J. 1973, 52, 193–203. [Google Scholar]
- Pickering, F.B. Physical Metallurgy and the Design of Steels; Applied Science Publishers Ltd.: Essex, UK, 1978; pp. 62–66. [Google Scholar]
- Tchizhik, A.A.; Tchizhik, T.A.; Tchizhik, A.A. Optimization of the heat treatment for steam and gas turbine parts manufactured from 9–12% Cr steels. J. Mater. Process. Technol. 1998, 77, 226–232. [Google Scholar] [CrossRef]
- Uggowitzer, P.J.; Bähre, W.-F.; Wohlfromm, H.; Speidel, M.O. Nickel-free high nitrogen austenitic stainless steels produced by metal injection moulding. Mater. Sci. Forum 1999. [Google Scholar] [CrossRef]
- Zhang, S.Q.; Dong, D.D.; Wang, Q.; Dong, C.; Yang, R. Composition design of alumina-forming austenitic stainless steels based on cluster-plus-glue-atom model. Acta Metall. Sin. 2021. under review. [Google Scholar]
- Cowley, J.M. Short- and long-range order parameters in disordered solid solutions. Phys. Rev. 1960, 120, 1648–1657. [Google Scholar] [CrossRef]
- Dong, C.; Qiang, J.B.; Yuan, L.; Wang, Q.; Wang, Y.M. A cluster-plus-glue-atom model for composition design of complex alloys. Chin. J. Nonferrous Met. 2011, 21, 2502–2510. [Google Scholar]
- Dong, C.; Dong, D.D.; Wang, Q. Chemical units in solid solutions and alloy composition design. Acta Metall. Sin. 2018, 54, 293–300. [Google Scholar]
- Wang, Q.; Zha, Q.F.; Liu, E.X.; Dong, C.; Chun, J.I. Composition design of high-strength martensitic precipitation hardening stainless steels based on a cluster model. Acta Metall. Sin. 2012, 48, 1201. [Google Scholar] [CrossRef]
- Wang, Q.; Ji, C.J.; Wang, Y.M.; Qiang, J.B.; Dong, C. β-Ti alloys with low Young’s moduli interpreted by cluster-plus-glue-atom model. Metall. Mater. Trans. A 2013, 44, 1872–1879. [Google Scholar] [CrossRef]
- Hong, H.L.; Wang, Q.; Dong, C.; Liaw, P.K. Understanding the Cu-Zn brass alloys using a short-range-order cluster model: Significance of specific compositions of industrial alloys. Sci. Rep. 2014, 4, 7065. [Google Scholar] [CrossRef]
- Ma, Y.; Wang, Q.; Li, C.L.; Santodonato, L.J.; Feygenson, M.; Dong, C.; Liaw, P.K. Chemical short-range orders and the induced structural transition in high-entropy alloys. Scripta Mater. 2018, 144, 64–68. [Google Scholar] [CrossRef]
- Zhang, Y.; Wang, Q.; Dong, H.G.; Dong, C.; Zhang, H.Y.; Sun, X.F. Nickel-based single-crystal superalloys (Ni,Co)-Al-(Ta,Ti)-(Cr,Mo,W) designed by cluster-plus-glue-atom model and their 1000h long-term aging behavior at 900 °C. Acta Metall. Sin. 2018, 54, 591–602. [Google Scholar]
- Jiang, B.B.; Wen, D.H.; Wang, Q.; Che, J.D.; Dong, C. Design of near-α Ti alloys via a cluster formula approach and their high-temperature oxidation resistance. J. Mater. Sci. Technol. 2019, 35, 1008–1016. [Google Scholar] [CrossRef]
- Xu, X.; Zhang, X.; Chen, G.; Lu, Z. Improvement of high-temperature oxidation resistance and strength in alumina-forming austenitic stainless steels. Mater. Lett. 2011, 65, 3285–3288. [Google Scholar] [CrossRef]
- Xu, X.; Zhang, X.; Sun, X.; Lu, Z.P. Effects of silicon additions on the oxide scale formation of an alumina-forming austenitic alloy. Corros. Sci. 2012, 65, 317–321. [Google Scholar] [CrossRef]
- Xu, X.; Zhang, X.; Sun, X.; Lu, Z.P. Roles of manganese in the high-temperature oxidation resistance of alumina-forming austenitic steels at above 800 °C. Oxid. Met. 2012, 78, 349–362. [Google Scholar] [CrossRef]
- Zhou, M.X. Microstructure of hot rolled high aluminum 304, 316L austenitic stainless steel and the mechanism of aluminum elements. Cailiao Rechuli Xuebao/Trans. Mater. Heat Treat. 2012, 35, 55–60. [Google Scholar]
- Sa, X.R. Properties and Mechanism of Elements of Cast High Aluminum 304, 316 L, 310S Steel; Lanzhou University of Technology: Lanzhou, China, 2013. [Google Scholar]
- Yao, L. Effect of Al on Microstructure and Properties of 17-7PH, 2205 Stainless Steels and Its Mechanism; Lanzhou University of Technology: Lanzhou, China, 2013. [Google Scholar]
- Chen, B.C.; Li, G.F.; Yang, W. Conversion relation of Leeb-hardness, vickers-hardness and strength of austenitic stainless steels. Mater. Mech. Eng. 2009, 33, 37–40. [Google Scholar] [CrossRef]
- Wen, D.H.; Li, Z.; Jiang, B.B.; Wang, Q.; Chen, G.Q.; Tang, R.; Zhang, R.Q.; Dong, C.; Liaw, P.K. Effects of Nb/Ti/V/Ta on phase precipitation and oxidation resistance at 1073 K in alumina-forming austenitic stainless steels. Mater. Charact. 2018, 144, 86–98. [Google Scholar] [CrossRef]
- Aviation Industry Corporation of China. Testing method of oxidation resistance for steels and superalloys. In Chinese Aircraft Industry Standard; No. HB 5258-2000; Commission of Science, Technology and Industry for National Defense: Beijing, China, 2000. [Google Scholar]
Mixing Enthalpy ΔH | Shell Atoms | |||
---|---|---|---|---|
Fe | Mn | Ni | ||
Center atoms | Al | −11 | −19 | −22 |
Si | −35 | −45 | −40 | |
Ti | −17 | −8 | −35 | |
V | −7 | −1 | −18 | |
Nb | −16 | −4 | −30 | |
Ta | −15 | −4 | −29 | |
Glue atoms | Cr | −1 | 2 | −7 |
Mo | −2 | 5 | −7 | |
W | 0 | 6 | −3 |
No. | Composition Formula | Mark | Element Content/wt. % | Solutionized Hardness /HV | Aged Hardness /HV | Creq | Nieq | Creq/Nieq |
---|---|---|---|---|---|---|---|---|
1-1 | Al0.8Si0.05Nb0.15-Fe8.7Ni3.0Mn0.3-Cr2.8Mo0.2 | Al0.8Ni3.0 | Fe-2.45Al-0.16Si-1.58Nb-19.99Ni-1.87Mn-16.53Cr-2.18Mo-0.10C | 181.44 | 223.56 | 28.8 | 23.0 | 0.80 |
1-2 | Al1.0 Si0.05Nb0.15-Fe8.7Ni3.0Mn0.3-Cr2.6Mo0.2 | Al1.0Ni3.0 | Fe-3.08Al-0.16Si-1.59Nb-20.10Ni-1.88Mn-15.43Cr-2.19Mo-0.10C | 224.46 | 255.38 | 29.3 | 23.1 | 0.79 |
1-3 | Al1.1 Si0.05Nb0.15-Fe8.7Ni3.0Mn0.3-Cr2.5Mo0.2 | Al1.1Ni3.0 | Fe-3.40Al-0.16Si-1.60Nb-20.16Ni-1.89Mn-14.88Cr-2.20Mo-0.10C | 239.60 | 280.84 | 29.5 | 23.2 | 0.79 |
1-4 | Al1.0 Si0.05Nb0.15-Fe8.5Ni3.2Mn0.3-Cr2.6Mo0.2 | Al1.0Ni3.2 | Fe-3.08Al-0.16Si-1.59Nb-21.43Ni-1.88Mn-15.42Cr-2.19Mo-0.10C | 235.60 | 274.82 | 29.3 | 24.5 | 0.84 |
1-5 | Al1.0 Si0.05Nb0.15-Fe8.3Ni3.4Mn0.3-Cr2.6Mo0.2 | Al1.0Ni3.4 | Fe-3.08Al-0.16Si-1.59Nb-22.75Ni-1.88Mn-15.41Cr-2.19Mo-0.10C | 231.35 | 271.62 | 29.2 | 25.8 | 0.88 |
1-6 | Al1.0 Si0.05Nb0.15-Fe8.0Ni3.7Mn0.3-Cr2.6Mo0.2 | Al1.0Ni3.7 | Fe-3.07Al-0.16Si-1.59Nb-24.74Ni-1.88Mn-15.40Cr-2.19Mo-0.10C | 218.21 | 277.80 | 29.2 | 27.8 | 0.95 |
1-7 | Al1.0 Si0.05Nb0.15-Fe7.7Ni4.0Mn0.3-Cr2.6Mo0.2 | Al1.0Ni4.0 | Fe-3.07Al-0.16Si-1.59Nb-26.72Ni-1.88Mn-15.38Cr-2.18Mo-0.10C | 242.79 | 304.81 | 29.2 | 29.7 | 1.02 |
2-1 | Al0.89Si0.05Nb0.06-Fe8.7Ni3.0Mn0.3-Cr2.8Mo0.2 | Nb0.06Ni3.0Mo0.2 | Fe-2.74Al-0.16Si-0.64Nb-20.13Ni-1.88Mn-16.64Cr-2.19Mo-0.08C | 139.64 | 184.75 | 28.0 | 22.7 | 0.81 |
2-2 | Al0.89Si0.05Nb0.06-Fe8.7Ni3.0Mn0.3-Cr2.93Mo0.07 | Nb0.06Ni3.0Mo0.07 | Fe-2.76Al-0.16Si-0.64Nb-20.26Ni-1.90Mn-17.53Cr-0.77Mo-0.08C | 133.01 | 196.25 | 26.8 | 22.9 | 0.85 |
2-3 | Al0.89Si0.05Nb0.03Ta0.03-Fe8.7Ni3.0Mn0.3-Cr2.93Mo0.07 | Nb0.03Ta0.03Ni3.0Mo0.07 | Fe-2.75Al-0.16Si-0.32Nb-20.20Ni-1.89Mn-17.47Cr-0.77Mo-0.623Ta-0.08C | 149.18 | 196.46 | 26.2 | 22.8 | 0.87 |
2-4 | Al0.89Si0.05Nb0.06-Fe8.5Ni3.2Mn0.3-Cr2.8Mo0.2 | Nb0.06Ni3.2Mo0.2 | Fe-2.74Al-0.16Si-0.64Nb-21.45Ni-1.88Mn-16.63Cr-2.19Mo-0.08C | 158.78 | 192.03 | 28.0 | 24.1 | 0.86 |
2-5 | Al0.89Si0.05Nb0.03Ta0.03-Fe8.5Ni3.2Mn0.3-Cr2.8Mo0.2 | Nb0.03Ta0.03Ni3.2Mo0.2 | Fe-2.73Al-0.16Si-0.32Nb-21.39Ni-1.88Mn-16.58Cr-2.19Mo-0.618Ta-0.08C | 148.03 | 203.66 | 27.3 | 24.0 | 0.88 |
2-6 | Al0.89Si0.05Nb0.06-Fe8.5Ni3.2Mn0.3-Cr2.93Mo0.07 | Nb0.06Ni3.2Mo0.07 | Fe-2.76Al-0.16Si-0.64Nb-21.59Ni-1.89Mn-17.52Cr-0.77Mo-0.08C | 145.91 | 194.01 | 26.8 | 24.2 | 0.91 |
2-7 | Al0.89Si0.05Nb0.06-Fe8.5Ni3.2Mn0.3-Cr2.93Mo0.04W0.03 | Nb0.06Ni3.2Mo0.04W0.03 | Fe-2.75Al-0.16Si-0.64Nb-21.53Ni-1.89Mn-17.46Cr-0.44Mo-0.63W-0.08C | 145.63 | 197.61 | 27.1 | 24.2 | 0.89 |
2-8 | Al0.89Si0.05Nb0.03Ta0.03-Fe8.5Ni3.2Mn0.3-Cr2.93Mo0.07 | Nb0.03Ta0.03Ni3.2Mo0.07 | Fe-2.75Al-0.16Si-0.32Nb-21.53Ni-1.89Mn-17.46Cr-0.77Mo-0.622Ta-0.08C | 145.04 | 192.02 | 26.1 | 24.2 | 0.92 |
No. | Samples | Average Oxidation Rate (g/m2 × h) | Average Oxidation-Peeling Mass (g/m2) |
---|---|---|---|
2-1 | Nb0.06Ni3.0Mo0.2 | 0.0200 | 0.3333 |
2-2 | Nb0.06Ni3.0Mo0.07 | −0.1242 | 6.3038 |
2-3 | Nb0.03Ta0.03Ni3.0Mo0.07 | 0.0239 | 0.3679 |
2-4 | Nb0.06Ni3.2Mo0.2 | 0.0131 | 0.3750 |
2-5 | Nb0.03Ta0.03Ni3.2Mo0.2 | 0.0059 | 0.3916 |
2-6 | Nb0.06Ni3.2Mo0.07 | 0.0148 | 0.3711 |
2-7 | Nb0.06Ni3.2Mo0.04W0.03 | 0.0081 | 0.8125 |
2-8 | Nb0.03Ta0.03Ni3.2Mo0.07 | 0.0093 | 0.3728 |
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Zhang, S.; Dong, D.; Wang, Q.; Dong, C.; Yang, R. High-Temperature Oxidation Resistance of Alumina-Forming Austenitic Stainless Steels Optimized by Refractory Metal Alloying. Metals 2021, 11, 213. https://0-doi-org.brum.beds.ac.uk/10.3390/met11020213
Zhang S, Dong D, Wang Q, Dong C, Yang R. High-Temperature Oxidation Resistance of Alumina-Forming Austenitic Stainless Steels Optimized by Refractory Metal Alloying. Metals. 2021; 11(2):213. https://0-doi-org.brum.beds.ac.uk/10.3390/met11020213
Chicago/Turabian StyleZhang, Shuqi, Dandan Dong, Qing Wang, Chuang Dong, and Rui Yang. 2021. "High-Temperature Oxidation Resistance of Alumina-Forming Austenitic Stainless Steels Optimized by Refractory Metal Alloying" Metals 11, no. 2: 213. https://0-doi-org.brum.beds.ac.uk/10.3390/met11020213