Phosphineoxide-Chelated Europium(III) Nanoparticles for Ceftriaxone Detection
Abstract
:1. Introduction
2. Experimental Section
3. Results and Discussion
3.1. Synthesis of Ligands c and d
3.2. Synthesis of [Ln(L)x] Complexes, Ln = Eu3+, Tb3+, L = a, b, c, x = 1,2,3 and XRD Data
3.3. Absorption and Luminescent Properties of Ln(c)
3.4. Synthesis of PSS-[Ln(L)x] Nanoparticles, L = a, b, c, x = 1,2, 3, Ln = Tb, Eu
3.5. Detection of Ceftriaxone Using PSS-[Eu(a)3] Colloids
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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R | Tau_Rad (ms) | lexc (nm) | Tau_Meas(ms) | PL Efficiency | |
---|---|---|---|---|---|
[Tb(a)3] | - | - | 2.20 | ||
[Tb(b)2(NO3)3] | - | - | 4.79 | ||
[Tb(c)(NO3)3(H2O)] | - | - | 3.05 | ||
[Eu(a)3] | 11.22 | 1.49 | 275 | 1.5 | 1.00 |
[Eu(b)2(NO3)3] | 1.52 | 6.86 | 271 | 3.90 | 0.57 |
[Eu(c)(NO3)3(H2O)] | 1.38 | 7.40 | 271 | 4.20 | 0.57 |
PSS-[Eu(a)3] | 12.18 | 1.41 | 273 | 0.46 | 0.33 |
PSS-[Eu(b)2(NO3)3] | 1.17 | 8.10 | 271 | 3.50 | 0.43 |
PSS[Eu(c)(NO3)3(H2O)] | 0.86 | 10.13 | 271 | 3.33 | 0.33 |
Name | dh (nm) | PDI | ζ (mV) |
---|---|---|---|
[Eu(a)3] | 1305.0 ± 62.7 | 0.199 ± 0.182 | –32.9 ± 0.6 |
[Eu(b)2(NO3)3] | 878.6 ± 28.9 | 0.659 ± 0.016 | 35.7 ± 0.5 |
[Eu(c)(NO3)3(H2O)] | 1922.0 ± 133.5 | 0.265 ± 0.157 | 28.3 ± 1.2 |
PSS-[Eu(a)3] | 314.9 ± 11.2 | 0.272 ± 0.006 | –27.1 ± 0.7 |
PSS-[Eu(b)2(NO3)3] | 522.2 ± 58.3 | 0.549 ± 0.040 | –67.1 ± 0.8 |
PSS-[Eu(c)(NO3)3(H2O)] | 646.9 ± 68.5 | 0.561 ± 0.038 | –62.0 ± 2.3 |
Introduced | Remain within the Composition of Colloids | CLn in Supernatant 1 | CLn in Supernatant 2 | Total Loss of Ln(III) | |||||
---|---|---|---|---|---|---|---|---|---|
мM | мM | % | мM | % | мM | % | мM | % | |
PSS-[Eu(a)3] | 0.5 | 0.344 | 68.94 | 0.13 | 26.50 | 0.023 | 4.55 | 0.155 | 31.05 |
PSS-[Eu(b)2(NO3)3] | 0.5 | 0.108 | 21.69 | 0.37 | 73.49 | 0.024 | 4.82 | 0.392 | 78.31 |
PSS-[Eu(c)(NO3)3(H2O)] | 0.5 | 0.116 | 23.29 | 0.38 | 37.67 | 0.007 | 1.38 | 38.36 | 76.71 |
Luminescent Compound | LOD (M) |
---|---|
CdSe/CdS/ZnS quantum dots [59] | 1 × 10–6 |
Ceftriaxone converted into a fluorescent compound [60] | 3.5 × 10−8 |
Chemiluminescence emission generated from the oxidation of ceftriaxone sodium [61] | 4.5 × 10–8 |
Ceftriaxone converted into a fluorescent product [62] | 2.3 × 10–9 |
Carbonized blue crab shell carbon dots [63] | 9.0 × 10–9 |
Chicken drumstick-derived carbon dots [64] | 4.4 ×10–10 |
Graphene quantum dots in a molecularly imprinted polymer MIP-GQDs [65] | 1.8 × 10–10 |
L-cysteine (Cys) coated CdS QDs [66] | 1.3 × 10–9 |
L-cysteine capped ZnS (L-Cys-ZnS) QDs [67] | 9.0 × 10−8 |
Our paper | 9.7 × 10–7 |
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Zairov, R.; Dovzhenko, A.; Terekhova, N.; Kornev, T.; Zhou, Y.; Huang, Z.; Tatarinov, D.; Nizameeva, G.; Fayzullin, R.R.; Gubaidullin, A.T.; et al. Phosphineoxide-Chelated Europium(III) Nanoparticles for Ceftriaxone Detection. Nanomaterials 2023, 13, 438. https://0-doi-org.brum.beds.ac.uk/10.3390/nano13030438
Zairov R, Dovzhenko A, Terekhova N, Kornev T, Zhou Y, Huang Z, Tatarinov D, Nizameeva G, Fayzullin RR, Gubaidullin AT, et al. Phosphineoxide-Chelated Europium(III) Nanoparticles for Ceftriaxone Detection. Nanomaterials. 2023; 13(3):438. https://0-doi-org.brum.beds.ac.uk/10.3390/nano13030438
Chicago/Turabian StyleZairov, Rustem, Alexey Dovzhenko, Natalia Terekhova, Timur Kornev, Ying Zhou, Zeai Huang, Dmitry Tatarinov, Guliya Nizameeva, Robert R. Fayzullin, Aidar T. Gubaidullin, and et al. 2023. "Phosphineoxide-Chelated Europium(III) Nanoparticles for Ceftriaxone Detection" Nanomaterials 13, no. 3: 438. https://0-doi-org.brum.beds.ac.uk/10.3390/nano13030438