Inorganics, Volume 9, Issue 3 (March 2021) – 3 articles
Cover Story (view full-size image): Organotin derivatives resulting from the insertion of carbon dioxide into Sn-X bonds (X = N, H, P) have been reviewed from a structural point of view. Notably, the synthetic aspects and X-ray structures of carbamato, formato and phosphinoformato tin complexes are successively described and discussed. In addition, the last chapter is devoted to bimetallic transition-metal/tin complexes with bridging carbon dioxide, also named metallocarboxylato tin complexes. Completing a previous review dedicated to hemicarbonato and carbonato derivatives, this new inventory continues to show that CO2 derivatives of molecular tin compounds can truly be considered as a class of compounds in their own right. View this paper.
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