Recycling, Volume 7, Issue 3 (June 2022) – 16 articles

Acid mine drainage (AMD) is a global problem with severe consequences for the environment. South Africa’s abandoned mines are a legacy from the country’s economic dependence on the mining sector, with consequent negative impacts on ecosystems. AMD remediation includes active and passive techniques. Constructed wetlands (a passive technique) have lower operational costs but require larger spaces and longer timeframes to achieve the remediation of AMD, and are supported by anaerobic sulphate-reducing bacteria (SRB), which capable of remediating high-sulphate-laden AMD while precipitating dissolved metals from the AMD. Organic substrates supporting these activities are often the limiting factor. When enhancing existing passive AMD remediation technologies, alternative waste material research that may support SRB activity is required to support the circular economy through the reduction in waste products. Chicken feathers show potential as a substrate enhancer, boosting organic carbon availability to SRB, which sustains passive AMD treatment processes by achieving pH elevation, sulphate and metal reductions in AMD water for reuse. Microbial biodiversity is essential to ensure the longevity of passive treatment systems, and chicken feathers are proven to have an association with SRB microbial taxa. However, the longer-term associations between the AMD water parameters, microbial diversity and the selected substrates remain to be further investigated. Full article

Disposing of waste tires is a major environmental and economic issue. Different recycling methods have been studied to account for its re-usage. This project aims to evaluate the possible usage of shredded waste tires in thermal energy storage (TES) applications, whether they are sensible or latent materials. An experimental setup has been developed with seven compartments. Each compartment contains different TES materials, including tire crumbs, paraffin wax, paraffin wax with shredded tires, pebbles, pebbles with shredded tires, concrete, and concrete with shredded tires. In all cases of the mixture, the base materials are 60%vol, and the tire crumbs are 40%vol. The experimental included three locations for temperature measurements in each compartment, solar irradiation, and ambient temperature. The tests were carried out from 9:00 a.m. till 7:00 p.m. and repeated for five days to account for the weather’s daily change. Results revealed that mixed 60%vol pebbles and 40%vol shredded tires have the highest recorded temperature, at 112.5 °C, with a 39.5% increment compared to pure pebbles. The interesting finding is that the added tire crumbs reduced the storage capacity of the paraffin wax, which is latent TES material. At the same time, it increased the storage capacity of the concrete and pebbles, which are sensible TES materials. Adding 40%vol of tire crumbs to the paraffin wax has a negative effect, where the thermal storage capacity is reduced by 43%, and the discharge capacity is reduced by 57%. In contrast, the concrete and the pebbles show enhanced storage capacity. Adding 40%vol of crumbs to the concrete increased the charging capacity by 54% and discharging capacity by 33.7%. The 40%vol added tire crumbs to the pebbles increased its charging capacity by 25% and the discharging capacity by 33%. The rudimentary assessment encourages further investigations on using the wasted tires crumbs for TES. The results reveal the probability of a circular economy using wasted tires with sensible TES for solar-to-thermal energy conversion. Full article

At present, global waste tire generation considerably exceeds consumption. Moreover, waste rubber tires (WRTs) are a cause of concern, as huge volumes are being discarded and buried, thus causing serious environmental pollution. Rubberized waste concrete (RWC) is a type of environmentally friendly construction material. The main challenge encountered when manufacturing rubberized concrete is the low adhesive properties between the cement paste and rubber particles. This paper demonstrates the effects, through experiments, of using waste tire rubber instead of recycled coarse aggregate (RCA) on two types of cement, i.e., sulfate-resistant cement (SRC) and ordinary Portland cement (OPC), where SRC is a specially blended cement designed to improve concrete performance and workability in the most aggressive environments. All tested samples contained 10% silica fume (SF) and 0.2% fly ash (FA), and the substitution of recycled aggregate content with waste rubber tier (WRT) at different percentages of 100%, 75%, and 50% was evaluated. The research investigated the synergistic effect on the workability and mechanical properties of various cement types with different amounts of rubber aggregate. It was found that the sulfate-resistant (SRC) type can increase the compressive strength than OPC with a percentage of 25% with the same content of WRT at concrete mix. Moreover, ductility and cracking behavior are improved, and it appears that it is also possible to make lightweight rubber aggregate concrete with this type of mixture.. Using this type of cement, it is possible to restore satisfactory ductility to the waste tires, thus facilitating a reduction in the formation of potential plastic cracks. Moreover, the indicative compressive strength development for SRC with recycled rubber in concrete positively contributes to a reduction in formed cracks. However, SEM microstructural analyses suggest a higher proportion of C–S–H intermixed with sulfate reaction phases of SRC rubberized mortar than those of OPC; thus, given that crystal growth results in a decreased percentage of air voids rather than decreased internal cracking, it is clearly shown that the average crack width increases in OPC mortar compared with SRC. Finally, t-testing was used as an inferential statistical tool to determine whether there is a sizeable distinction between the properties of the two categories of materials, OPC and SRC, by comparing the mean and standard deviation of the values for compressive and tensile strength. Full article

Efficient packaging waste management systems are essential considering recent revisions of the European legislation on packaging waste management that sets ambitious targets. European rules aim to deal with the increasing quantities of packaging waste, which cause environmental problems. Consequently, it is necessary to identify functional packaging waste management systems to achieve these targets effectively and efficiently. However, given the heterogeneity of the different packaging management systems, policymakers, scholars, and industry operators struggle to have a comparative view. The number of non-harmonized laws in force across countries, autonomous recycling targets, and constant updates are prominent problems that make it difficult to obtain comparable information for research, business, and policymaking. To fill this gap, our research question consists of assigning responsibilities for prevention, collection, recycling, and recovery and an overview of some models at a glance with respect to the general governance and functioning of the system. We base our research on a multiple-case design since more cases are examined using complementary data collection methods, analysis of the previous literature, reports, legislation, and business and institutional websites. Our results provide insights from the following cases: Germany, France, the United Kingdom, the Netherlands, Portugal, Denmark, Spain, and Italy. In addition, policy implications emerge as our insights help overcome barriers in the European market’s development caused by the different rules on packaging management and design serving policymakers that aim to harmonize the management of packaging waste. The paper also contains managerial implications for circular economy business models that can be used by managers who aim to design or upgrade their business models according to both recent legislative upgrades and packaging management systems. Full article

Reinforced concrete based on ordinary Portland cement (OPC) is one of the most commonly used materials in modern buildings. Due to the global growth of the building industry, concrete components have been partially or completely replaced with waste materials that can be used as binders or aggregates. Besides the ecological aspects, modern architecture widely needs materials to make the concrete durable, resisting large loads and various detrimental forces in the environment. This opens the possibilities of managing waste materials and applying them in practice. This paper presents a concise review of the green solutions for ecofriendly materials in the building industry that deal with the practical application of materials commonly treated as waste. The main emphasis was placed on their influence on the properties of the building material, optimal composition of mixtures, and discussion of the advantages and disadvantages of each of the “green” additives. It turned out that some solutions are far from being ecofriendly materials, as they leech and release numerous harmful chemicals into the environment during their presence in concrete. Finally, the paper suggests a research direction for the development of an ecofriendly structural material for a sustainable future. Full article

There is an urgent and growing need to further advance the plastic waste management system globally and in South Africa, due to the increasing impact of plastic waste. This study focused on the adequacy of plastic policies to sustainably manage plastic waste. Policies need to address the plastic material supply systems and the options up the waste hierarchy for them to be effective and support material circularity. The study used qualitative content analysis to assess how the evolution of plastic policies for plastic waste management in South Africa aligned with national plastic material flows and promoted options higher up the waste hierarchy. This was benchmarked with Norway and Germany, which have some of the highest plastic recycling rates. The results showed that the evolution of existing plastic policies for South Africa addresses stages of production, trade and consumption, and recycling. There is no focus on waste generation, collection and sorting. None aligned with the waste hierarchy options of rethink, reduce, reuse, repair, refurbish, remanufacture and repurpose. This policy gap supports the need for broader national plastic policy frameworks that embed a policy drive in the value chain points and promote the priority higher value measures of the waste hierarchy. Full article

The Sultanate of Oman has experienced rapid development over the last thirty years and has constructed environmentally friendly and sustainable infrastructure while it continues to find economical alternative resources to achieve the goals of the Oman 2040 vision. The primary concerns are preserving natural resources and reducing the impact of carbon dioxide (CO₂) emissions on the environment. This review aims to encourage the sustainable use of reclaimed asphalt pavement (RAP) materials in pavement construction and focuses primarily on employing RAP materials in new pavement projects. Currently, new construction projects utilise a significant percentage of demolished asphalt pavement to save costs and natural resources. The key issue that arises when mixing RAP into new asphalt mixtures is the effects on the mixtures’ resistance to permanent disfigurements, such as fatigue cracks, that influence asphalt mixture performance. Numerous studies have assessed the impact of using RAP in asphalt mixtures and found that RAP increases the stiffness of asphalt mixtures, and thus improves rutting resistance at high temperatures. Nevertheless, the findings for thermal and fatigue cracking were found to be contradictory. This review will address the primary concerns regarding the use of RAP in asphalt pavements, and aims to encourage highway agencies and academic researchers in the Gulf countries to develop frameworks for the practical usage of RAP in the construction of sustainable pavement systems. Full article

There is approximately 30% of grey sedge (Lepironia articulata) residue remaining from weaving production that could add value to support zero waste management. Therefore, the aim of this research was to study the feasibility of using a residue of grey sedge or Krajood strips from weaving production to form a value-added product. To obtain preliminary data, Krajood strip residue was examined for its biological and physical properties. In addition, the biological and physical properties of Krajood strip residue in combination with loam soil (KSRL) were examined and compared with the properties of loam soil (LS) itself. The results showed that the total microbe and moisture content of the Krajood strip residue was significantly higher than that of the products made from Krajood strips (KS). The stress value of Krajood strips was higher than the stress values of other samples except for that of a bag made of paper. Identification of bacteria and mold by MALDI Biotyper and DNA sequencing compared with BLAST revealed the presence of the types of soil microbes that benefit plants. KSRL was enriched with larger amounts of the primary elements important for plant growth: nitrogen, phosphorus, and potassium, and the three second tier elements. The pH of KS, LS, and KSRL were 6.40 ± 0.14, 5.87 ± 0.04, and 5.26 ± 0.02, respectively. These results could support the use of this beneficial residue for bioresource sustainability. Full article

Lithium-ion batteries have become a crucial part of the energy supply chain for transportation (in electric vehicles) and renewable energy storage systems. Recycling is considered one of the most effective ways for recovering the materials for spent LIB streams and circulating the material in the critical supply chain. However, few review articles have been published in the research domain of recycling and the circular economy, with most mainly focusing on either recycling methods or the challenges and opportunities in the circular economy for spent LIBs. This paper reviewed 93 articles (66 original research articles and 27 review articles) identified in the Web of Science core collection database. The study showed that publications in the area are increasing exponentially, with many focusing on recycling and recovery-related issues; policy and regulatory affairs received less attention than recycling. Most of the studies were experiments followed by evaluation and planning (as per the categorization made). Pre-treatment processes were widely discussed, which is a critical part of hydrometallurgy and direct physical recycling (DPR). DPR is a promising recycling technique that requires further attention. Some of the issues that require further consideration include a techno-economic assessment of the recycling process, safe reverse logistics, a global EV assessment revealing material recovery potential, and a lifecycle assessment of experiments processes (both in the hydrometallurgical and pyrometallurgical processes). Furthermore, the application of the circular business model and associated stakeholders’ engagement, clear and definitive policy guidelines, extended producer responsibility implications, and material tracking, and identification deserve further focus. This study presents several future research directions that would be useful for academics and policymakers taking necessary steps such as product design, integrated recycling techniques, intra-industry stakeholder cooperation, business model development, techno-economic analysis, and others towards achieving a circular economy in the LIB value chain. Full article

The exponential growth of digitalisation and the continuous increase in sustainability needs are currently reshaping the European manufacturing industry through its entire value chain. Industrial sectors have undergone significant changes globally in recent years, and they will continue to face this deep transformation. The manufacturing sectors, more specifically, companies, need to develop a relevant strategy that can support their organisation to handle the upcoming future technological developments and sustainability requirements properly. In order to implement the strategy effectively and achieve an adequate digital and green transformation, their main focus should be the development of a multi-skilled workforce. This competent workforce can only be built by foreseeing the changes in the needed skills for the manufacturing industry and then updating the skills of the current workforce accordingly. As an answer to this need, we developed an automated skill database for the manufacturing industry, particularly transversal occupations of this sector related to the industrial symbiosis (IS) and energy efficiency (EE). Differently from the conventional ones, the generated database incorporated not only the current but also the future skill needs for each profile. During the development of the future skills for each occupation in the database, we identified the foreseen skill needs for the manufacturing industry through detailed desk research. Therefore, this paper presents a valuable perspective on the subject. Our work aimed to fill the gap for a database specifically developed for the manufacturing industry, which provides the end-users with data about the new skills requirements resulting from industrial changes and sustainability needs. We believe that companies, education and training institutions and policymakers can make use of the generated database as a complementary tool for developing their training programmes or strategy roadmaps to cover the emerging changes in each individual industrial sector. Full article

The tannery industry is characterized by the consumption of a large quantity of water, around 30–40 m³ for processing 1000 kg of hide or skin. This amount becomes wastewater, containing about 300 kg of different chemicals, mainly refractory organic compounds, with high chemical oxygen demand (COD), total dissolved salts (TDS), chromium, and evolution of toxic gases, such as ammonia and sulfides, etc. The remaining tanning chemicals are released as effluent having high resistance against biological degradation, becoming a serious environmental issue. Usually, end-of-pipe treatment is not sufficient to meet the concerns of environmental issues. In terms of cleaner production options, the redesigning of the existing effluent treatment procedures with alternate or additional treatment techniques, which “supports resource recovery with no added chemicals”, is expected to give a sustainable solution for the management of toxic effluent. The Zero Liquid Discharge (ZLD) system serves to ensure zero water emission, as well as treatment facilities by recycling, recovery, and reuse of the treated wastewater using advanced cleanup technology. The international scenario shows the implementation of ZLD thanks to pressure from regulatory agencies. The ZLD system consists of a pre-treatment system with conventional physicochemical treatment, tertiary treatment, softening of the treated effluent, reverse osmosis (RO) treatment for desalination, and thermal evaporation of the saline reject from RO to separate the salts. By adopting this system, water consumption is reduced. Moreover, ZLD also becomes effective in disaster mitigation in areas where the tannery industry is a strong economic actor. With this review, we aim to give an outlook of the current framework. Full article

The waste amount coming from construction and demolition (CDW) has significant volume and potential to provide the backbone of a secondary material bank. Up to now, little attention is paid to waste gypsum recycling from CDW while a shift in global attitude toward waste management brings motivation to use CDW gypsum as secondary raw material. The present research investigates the properties of gypsum binder obtained from secondary raw materials originating from CDW. Three types of drywall boards and cast monolithic gypsum from interior walls, treated in the laboratory, and a gypsum binder was obtained. Comparison has been studied and the most effective solutions regarding CDW treatment are represented. Separation, crushing, and milling were done. DTA/TG, XRD, SEM, and particle size distribution were characterized by CDW gypsum. The heat treatment temperature was selected at 130 °C for 4 or 24 h and 180 °C for 4 h. Consistency, set time, and mechanical properties were characterized. Results indicate that a gypsum binder with a strength up to 3.7 MPa can be obtained. Low strength is associated with fineness of CDW gypsum and a high water/gypsum ratio (from 0.6 to 1.396). Gypsum content in CDW (38 to 92 wt.%) should be considered as an important factor during gypsum CDW recycling. Full article

The exponential growth of waste plastic accumulation has had an irreversible and lasting impact on the world. An imminent threat to marine and terrestrial ecosystems of massive proportions, plastic waste accumulation is a global problem that will not only have to be tackled by current generations but for many generations to follow. The scale of current recycling technologies and efforts to reduce consumption by for-profit and non-profit institutions, governments, and consumers will need to be rapidly increased to combat the negative impacts plastic waste has had on the planet since its conception. This is especially the case in areas with limited infrastructure to properly collect, manage, and dispose of plastic waste. Solutions to plastic waste accumulation crisis that are appropriate for the developing world are urgently needed. Conversion of plastic waste to liquid fuel by slow pyrolysis is a technology that is particularly suitable for developing countries due to its ability to convert polyolefin waste plastic into a useful product, thus preventing its eventual accumulation in the ecosystem. However, in developing countries, conversion techniques that do not rely on sophisticated technologies are needed. Since processing time and operating temperature are the simplest variables to control, an analytical study has been conducted to assess how the molecular composition of plastic derived fuel oil (PDFO) is impacted by these parameters. The results of gas chromatography-mass spectrometry (GC-MS) and thermogravimetric analysis (TGA) studies of PDFO from high- and low-density polyethylene plastic waste produced using appropriate technology techniques are presented alongside a comparison with traditional diesel fuel and kerosene. This approach is novel in that it differs from previously conducted research, which has studied the use of catalysts, additives, or single operating temperatures to assess the composition of PDFO. Therefore, this research contribution presents a simplistic and inexpensive approach for tuning PDFO composition in appropriate technology settings. Full article

Aluminium, iron and plastic are materials which are extensively used at both industry and individual levels. However, significant amounts of aluminium, iron and plastic end up in the environment. Specifically, bottle caps made of these materials are often thrown away, with or without bottles, and appear among the common plastic debris entering the world’s oceans and beaches. More than 20 million bottle caps and lids have been identified during beach-cleaning campaigns over the last 30 years. To recover bottle caps from the shores, conventional technologies can be used. In this paper, the physical properties of used metal and plastic bottle caps were examined and related to the settling and rising velocities of the caps, as well as their drag coefficients and hydrodynamic modes in water environments, with respect to gravity separation. The sample contained aluminium, iron, high-density polyethylene (HDPE), low-density polyethylene (LDPE), and polypropylene (PP) bottle caps. The findings revealed that the density differences between the bottle caps resulted in the terminal settling velocities of aluminium and iron particles, which were significantly higher than the rising velocities of the plastic caps. The results allowed us to design a flowsheet for bottle cap recovery from beach coasts in order to reduce environmental impact and produce add-on plastic and metal products. Full article

In this study, a chemical dissolution treatment was used to recover rubber and carbon black (CB) from truck tire scrap, with gas oil acting as the solvent and 4-Hydroxy-TEMPO acting as the catalyst for the chemical reactions. Montmorillonite clay was used to separate the rubber solution from the CB and the other non-dissolved tire additives. The recovered rubber and CB were characterized together with the original scrap tire sample by XRD, SEM, BET and thermal analysis, as well as FTIR and ¹H NMR spectral analyses. Characterization of the chemical structure of the recovered rubber showed that the main functional groups of styrene−butadiene rubber blend with natural rubber. The thermal behavior and crystalline structure of the recovered rubber, as well as its morphological images, showed that the properties of the rubber sample were acceptable and similar to natural rubber. The recovered CB characterizations showed that the sample after pyrolysis was a highly crystalline nanocomposite structure with a high specific surface area and scattered pores. Full article

The rapid development of light-emitting-diode (LED) technology is attributed to its superiority over light sources of earlier generations. Although LED lamps, compared to compact fluorescent lamps, are considered less harmful to the environment, there is still no efficient solution to deal with them at the end of their lifecycle. The first part of the study provides a detailed characterisation of LED lamps, focusing on their most interesting component: the LED module. LED packages attached to the module are highly enriched with Ga, In, Pd, Ag, Au, Sr, Y, Ce, Eu, Gd, and Lu, with the content of each element varying greatly depending on the LED technology. In the second part of this research, two new approaches for liberation and concentration of valuable components from LED modules are presented and compared: a chemical route and a thermal route. The chemical treatment leads to a highly selective separation of LED chips and encapsulation. Enrichment factors up to about 125 are achieved, and a concentrate is obtained containing approximately 14 wt% of the aforementioned valuable components. However, the process requires aromatic solvents, which are viewed as toxic. The thermal treatment results in separation of the aluminium heat sink from all other components of the LED module. Enrichment is approximately ten times lower, but the approach is technically feasible. Full article