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Additional Solvent Ionizing Power Values for Binary Water- 1,1,1,3,3,3-Hexafluoro-2-propanol Solvents

1
Department of Chemistry and Biochemistry, Northern Illinois University, Dekalb, Illinois 60115-2862, U.S.A.
2
Department of Chemistry, Dong-Eui University, 995 Eomgwangno, Busan-Jin-Gu, Busan 614-714, Korea
*
Author to whom correspondence should be addressed.
Int. J. Mol. Sci. 2006, 7(10), 451-455; https://0-doi-org.brum.beds.ac.uk/10.3390/i7100451
Received: 19 October 2006 / Accepted: 27 October 2006 / Published: 30 October 2006
Determinations of the specific rates of solvolysis of 1-adamantyl bromide and 1-adamantyl iodide in 1,1,1,3,3,3-hexafluoro-2-propanol-water mixtures, in conjunction withearlier reported values in 80% ethanol, have led to additional YBr and YI solvent ionizingpower values. These new values will be especially important in avoiding multicollinearitywhen the extended Grunwald-Winstein equation (extended by addition of a term involvingsolvent nucleophilicity) is used to correlate solvent-induced changes in the specific rates ofsolvolyses involving a bromide or iodide ion leaving group. View Full-Text
Keywords: 1-adamantyl bromide; 1-adamantyl iodide; 1; 1; 1; 3; 3; 3-hexafluoro-2-propanol; Grunwald-Winstein equation; solvent ionizing power. 1-adamantyl bromide; 1-adamantyl iodide; 1; 1; 1; 3; 3; 3-hexafluoro-2-propanol; Grunwald-Winstein equation; solvent ionizing power.
MDPI and ACS Style

Kevill, D.N.; Ryu, Z.H. Additional Solvent Ionizing Power Values for Binary Water- 1,1,1,3,3,3-Hexafluoro-2-propanol Solvents. Int. J. Mol. Sci. 2006, 7, 451-455. https://0-doi-org.brum.beds.ac.uk/10.3390/i7100451

AMA Style

Kevill DN, Ryu ZH. Additional Solvent Ionizing Power Values for Binary Water- 1,1,1,3,3,3-Hexafluoro-2-propanol Solvents. International Journal of Molecular Sciences. 2006; 7(10):451-455. https://0-doi-org.brum.beds.ac.uk/10.3390/i7100451

Chicago/Turabian Style

Kevill, Dennis N., and Zoon H. Ryu 2006. "Additional Solvent Ionizing Power Values for Binary Water- 1,1,1,3,3,3-Hexafluoro-2-propanol Solvents" International Journal of Molecular Sciences 7, no. 10: 451-455. https://0-doi-org.brum.beds.ac.uk/10.3390/i7100451

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