Assessment of Copper and Heavy Metals in Family-Run Vineyard Soils and Wines of Campania Region, South Italy
Abstract
:1. Introduction
2. Materials and Methods
2.1. Soil Sampling and Site Description
2.2. Grapevine Branches and Wine Samples
2.3. Chemical Analysis of Soil and Wine Samples
3. Results and Discussion
3.1. Soil Analysis
3.2. Wine Analysis
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Acknowledgments
Conflicts of Interest
References
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ID Site | V50 | Tr | T20 |
---|---|---|---|
Latitudo(°N) | 41°11′35.92″ | 41°11′34.68″ | 41°11′31.65″ |
Longitudo(°E) | 15°08′07.66″ | 15°08′07.51″ | 15°08′10.08″ |
Land Surface Areas (sq.m) | 4.4 | 3.33 | 800 |
Details from Cadaster | Folio number 13, Parcel number 248 | Folio number 13, Parcel number 247 | Folio number 13, Parcel number 246 |
Metal | Sample 1A | Sample 1B | Sample 2 | Sample 3 | Sample 4 |
---|---|---|---|---|---|
Al | 32,879 ± 350 | 35,967 ± 375 | 41,273 ± 435 | 34,141 ± 330 | 36.03 ± 0.50 |
As | 13.41 ± 0.18 | 11.94 ± 0.15 | 11.26 ± 0.16 | 14.60 ± 0.20 | 0.29 ± 0.04 |
Be | 3.36 ± 0.08 | 3.42 ± 0.10 | 3.52 ± 0.10 | 2.58 ± 0.05 | <5 ppb |
Cd | 0.57 ± 0.03 | 0.63 ± 0.04 | 0.54 ± 0.03 | 0.50 ± 0.03 | <5 ppb |
Co | 24.14 ± 0.30 | 18.85 ± 0.25 | 18.22 ± 0.28 | 12.65 ± 0.18 | 0.10 ± 0.03 |
Cr tot | 24.50 ± 0.22 | 20.99 ± 0.17 | 22.22 ± 0.20 | 19.85 ± 0.18 | 0.44 ± 0.02 |
Cu | 180.47 ± 2.22 | 129.27 ± 1.15 | 35.41 ± 0.88 | 121.63 ± 1.75 | 16.59 ± 0.45 |
Fe | 22,925 ± 250 | 24,321 ± 330 | 25,725 ± 458 | 22,250 ± 290 | 45.40 ± 0.66 |
Hg | <5 ppb | <5 ppb | <5 ppb | <5 ppb | <5 ppb |
Mn | 1901.7 ± 20.3 | 1400.3 ± 17.8 | 1295.5 ± 15.9 | 910.53 ± 12.6 | 32.27 ± 0.49 |
Ni | 26.78 ± 0.34 | 19.76 ± 0.29 | 20.53 ± 0.31 | 18.94 ± 0.33 | 0.37 ± 0.01 |
Pb | 89.89 ± 0.95 | 81.50 ± 0.88 | 92.82 ± 1.06 | 73.94 ± 0.99 | 7.90 ± 0.30 |
Se | <5 ppb | <5 ppb | <5 ppb | <5 ppb | <5 ppb |
Tl | 5.72 ± 0.17 | <5 ppb | <5 ppb | <5 ppb | 9.89 ± 0.24 |
V | 64.16 ± 0.79 | 70.70 ± 0.89 | 72.49 ± 1.01 | 56.65 ± 0.63 | 0.64 ± 0.05 |
Zn | 75.74 ± 0.95 | 80.56 ± 1.11 | 69.19 ± 0.82 | 68.38 ± 0.77 | 66.99 ± 0.69 |
Cr VI | <5 ppb | <5 ppb | <5 ppb | <5 ppb | <5 ppb |
Sb | 3.37 ± 0.09 | 2.56 ± 0.06 | 2.62 ± 0.07 | 1.49 ± 0.03 | 1.71 ± 0.04 |
Metal | Sample 5 | Sample 6 | Sample 7 |
---|---|---|---|
Al | 55.7 ± 0.8 | 104 ± 3 | 66.2 ± 0.9 |
As | 12.1 ± 0.5 | 8.4 ± 0.3 | 7.2 ± 0.4 |
Be | <5 ppb | <5 ppb | <5 ppb |
Cd | <5 ppb | <5 ppb | <5 ppb |
Cr tot | 15.3 ± 0.3 | <5 ppb | <5 ppb |
Cu | 5.76 ± 0.04 | 17.8 ± 0.2 | 12.0 ± 0.1 |
Fe | 705 ± 10 | 258 ± 7 | 1020 ± 30 |
Hg | <5 ppb | <5 ppb | <5 ppb |
Mn | 70.4 ± 0.6 | 50.7 ± 0.4 | 99.2 ± 0.9 |
Ni | 37.7 ± 1.4 | <5 ppb | <5 ppb |
Pb | <5 ppb | <5 ppb | 9.5 ± 0.3 |
Se | 20.5 ± 0.3 | 16.9 ± 0.5 | 9.1 ± 0.4 |
Tl | <5 ppb | <5 ppb | <5 ppb |
V | <5 ppb | <5 ppb | <5 ppb |
Zn | 21.6 ± 0.2 | 37.4 ± 0.5 | 211 ± 15 |
Cr (VI) | <5 ppb | <5 ppb | <5 ppb |
Sb | <5 ppb | <5 ppb | <5 ppb |
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Roviello, V.; Caruso, U.; Dal Poggetto, G.; Naviglio, D. Assessment of Copper and Heavy Metals in Family-Run Vineyard Soils and Wines of Campania Region, South Italy. Int. J. Environ. Res. Public Health 2021, 18, 8465. https://0-doi-org.brum.beds.ac.uk/10.3390/ijerph18168465
Roviello V, Caruso U, Dal Poggetto G, Naviglio D. Assessment of Copper and Heavy Metals in Family-Run Vineyard Soils and Wines of Campania Region, South Italy. International Journal of Environmental Research and Public Health. 2021; 18(16):8465. https://0-doi-org.brum.beds.ac.uk/10.3390/ijerph18168465
Chicago/Turabian StyleRoviello, Valentina, Ugo Caruso, Giovanni Dal Poggetto, and Daniele Naviglio. 2021. "Assessment of Copper and Heavy Metals in Family-Run Vineyard Soils and Wines of Campania Region, South Italy" International Journal of Environmental Research and Public Health 18, no. 16: 8465. https://0-doi-org.brum.beds.ac.uk/10.3390/ijerph18168465