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Article

Highly Scattering Hierarchical Porous Polymer Microspheres with a High-Refractive Index Inorganic Surface for a Soft-Focus Effect

by
Joonsik Yoon
1,
Ji Hyun Lee
2,
Jun Bae Lee
2 and
Jun Hyup Lee
3,*
1
Department of Chemical Engineering, Myongji University, Yongin 17058, Korea
2
Cosmax R&I Center, Innovation Lab, Cosmax, Seongnam 13486, Korea
3
Department of Chemical Engineering, Soongsil University, Seoul 06978, Korea
*
Author to whom correspondence should be addressed.
Polymers 2020, 12(10), 2418; https://0-doi-org.brum.beds.ac.uk/10.3390/polym12102418
Submission received: 29 September 2020 / Revised: 17 October 2020 / Accepted: 19 October 2020 / Published: 20 October 2020
(This article belongs to the Special Issue Hybrid Polymeric Materials II)
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Versions Notes

Abstract

:
Functional light scattering materials have received considerable attention in various fields including cosmetics and optics. However, a conventional approach based on optically active inorganic materials requires considerable synthetic effort and complicated dispersion processes for special refractive materials. Here, we report a simple and effective fabrication strategy for highly scattering hierarchical porous polymer microspheres with a high-refractive index inorganic surface that mitigates the disadvantages of inorganic materials, producing organic-inorganic hybrid particles with an excellent soft-focus effect. Hierarchical organic-inorganic hybrid particles were synthesized using the simple physical mixing of porous poly (methyl methacrylate) (PMMA) microparticles with different pore sizes and regularities as the organic core and titanium dioxide (TiO2) nanoparticles with different particle sizes as the inorganic shell. The polar noncovalent interactions between polar PMMA microspheres and the polar surface of TiO2 nanoparticles could induce the hierarchical core-shell structure of hybrid particles. The synthesized hybrid particles had increased diffuse reflectance properties of up to 160% compared with single inorganic particles. In addition, the light scattering efficiency and soft-focus effect could be increased further, depending on the size of the TiO2 nanoparticles and the pore characteristics of the PMMA microspheres. The proposed study can provide a facile and versatile way to improve the light scattering performance for potential cosmetics.

Graphical Abstract

1. Introduction

Since the beginning of the industrial era, several studies have been conducted on organic-inorganic hybrid materials in various fields [1,2,3,4,5,6,7]. The combination of organic and inorganic materials improves the properties of each component while reducing the specific limitations of each material. These functional hybrid materials generally contain two or more different components, such as inorganic materials (inorganic particles, metal ions, salts, oxides, etc.) and organic materials (organic groups or molecules, organic ligands, organic polymers, etc.). They are also combined by various methods—such as self-assembly, electrostatic interaction, intermolecular interactions, and bonding in molecular structural units—to improve the synergistic effect of their functional properties. The chemical and physical bonding between organic and inorganic components can be achieved through hydrogen bonding, van der Waals bonding, ionic boding, or covalent bonding [8,9,10,11]. These organic-inorganic hybrid functional materials are widely utilized in various industries, including catalysts, drugs, optics, energy storage, environmental remediation, health, cosmetics, and packaging, and provide potential platforms for versatile applications [10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26]. In particular, various studies using the optical properties of organic-inorganic hybrid materials have been conducted in applications such as lenses, optical filters, optical adhesives, optical films, anti-reflective films, and cosmetics [27,28,29,30].
The soft-focus effect refers to the phenomenon in which the lens is blurred in photography. This blurring phenomenon can be achieved by soft-focus powder as a filler in various fields, and a representative example is cosmetic powder [31,32,33,34,35]. Current cosmetic foundations focus on raw materials that exhibit optical properties through high-refractive-index inorganic particles in order to provide a good coverage for three-dimensional skin defects such as wrinkles, spots, pores, and irregularities. This improves the appearance of the skin by introducing light scattering and reflection functions into an inorganic powder with a high refractive index to visually blur skin defects. Inorganic powders with such characteristics mainly include titanium dioxide, zirconium oxide, and zinc oxide. However, the high opacity of the above particles, when accumulated in three-dimensional skin, causes troubles such as pores and wrinkles, contrasts with other skin, and interferes with natural makeup [36]. A commonly used foundation is often dispersed in water or oil, and it is important that the pigment has a stable and uniform dispersion phase. However, it is difficult to stably disperse inorganic powders in water or oil, which raises concerns of aggregation on the skin [37,38,39]. In order to solve this problem, we have prepared organic-inorganic hybrid particles by combining porous organic polymer microparticles with advantages such as high oil absorption and sebum adsorption power and inorganic nanoparticles with high refractive properties (Figure 1). Organic polymer particles have a considerably lower refractive index than inorganic particles, which decreases the scattering effect of light. However, the high refractive index difference between the two materials on the bonding surface of the organic and inorganic materials is expected to greatly amplify the light scattering effect. In addition, the prepared organic-inorganic hybrid particles have an extremely irregular and rough surface owing to the porous surface of the polymer particle and inorganic nanoparticles irregularly bonded to the core particles [40,41,42,43,44]. This peculiar surface of the manufactured hybrid particles could further enhance the diffuse reflection and scattering characteristics of light.
In this study, we present a simple and effective strategy for the fabrication of hierarchical organic-inorganic hybrid polymer microparticles with a high-refractive index inorganic surface to induce a maximum light scattering performance for excellent soft-focus effect. Organic-inorganic hybrid particles were prepared using porous poly(methyl methacrylate) (PMMA) microparticles with a low refractive index (n = 1.49) as the organic core and titanium dioxide (TiO2) nanoparticles with a high refractive index (n = 2.61) as the inorganic shell [45,46,47]. The prepared hybrid particles enhanced the light scattering characteristics through multiple effects of the porous morphology, the refractive index difference between the organic core and inorganic shell, and the rough high-refractive index surface. Organic-inorganic hybrid particles were named “organic PMMA@inorganic TiO2”. The method involved inducing polar interfacial boding between two particles through physical agitation in a solvent dispersion phase in an easy, fast, and economical manner. The nanoscale morphology and particle size of the prepared organic-inorganic hybrid polymer particles were analyzed using field emission scanning electron microscopy; additionally, Fourier transform infrared spectroscopy was conducted to confirm the structure of the hybrid particles. To examine the diffuse reflectance characteristics, hybrid polymer particles were mixed with an acrylate-based resin to prepare a thin polymer film with a constant thickness. To compare the soft-focus characteristics, the prepared hybrid particles were mixed with a nitrocellulose collodion. Various optical properties according to the structure of PMMA microparticle and TiO2 nanoparticle were compared and discussed.

2. Materials and Methods

2.1. Materials

Titanium dioxide (TiO2) and poly(methyl methacrylate) (PMMA) particles were obtained from Cosmax (Seongnam, Korea). For TiO2, white powdery particles with average diameters of 20 nm and 250 nm were prepared using a simple sol-gel and calcination method [48]. For PMMA, round bead microparticles with different pore characteristics were synthesized through dispersion polymerization [49,50]. The characteristics of each particle, including the particle size, pore size, and pore uniformity, are shown in Table 1. Acrylate-type resin was received from TMS (Ilsan, Korea). Nitrocellulose collodion was purchased from Sigma Aldrich (Seoul, Korea).

2.2. Synthesis of Oranic-Inorganic Hybrid Polymer Particles

For the synthesis of organic-inorganic hybrid particles, a solution of porous PMMA and TiO2 nanoparticles was prepared as a first step. Porous PMMA powder (8 g) was added to 100 mL of ethanol and stirred at room temperature at 1000 rpm for 10 min. In another beaker, 8 g of TiO2 powder was added to 100 mL of ethanol, and then stirred at room temperature at 1000 rpm for 10 min. Thereafter, the two solutions were subjected to ultrasonic dispersion for 10 min. The solution in which the porous PMMA was dispersed was then added to the TiO2 dispersion solution. The resulting solution was stirred at 1000 rpm for 4 h at room temperature. In the second step, filtration was performed using filter paper (3 μm pores) to separate the uncoupled TiO2 nanoparticles. A vacuum pump was used for fast filtration. Since a small number of uncoupled TiO2 nanoparticles were found in the scanning electron microscope analysis, it is supposed that the microscale filtration process is an effective method for the removal of TiO2 nanoparticles. After the filtration step, the obtained hybrid particles were dried in a vacuum oven at room temperature for 24 h to remove any residual solvent.

2.3. Preparation of Polymer Thin Films Containing Organic-Inorganic Hybrid Particles

To measure the diffuse reflectance, polymer thin films containing hybrid particles were prepared using an acrylate-type resin containing a photoinitiator. First, 0.5 g of hybrid particles was added to 9.5 g of acrylate resin and mixed using a paste mixer of a revolution/rotation system (AR-100, Thinky, Tokyo, Japan). The mixing process was carried out at a speed of 2200/800 rpm (revolution/rotation) for 30 min. After the mixed resin was applied between two release films (polyethylene terephthalate film coated with silicon), a uniform thin film with a thickness of 150 μm was prepared using a roll-to-roll coater. The prepared film was UV-cured with 4 J cm−2 using a UV curing machine (KJPHT-101, KJUV, Incheon, Korea). As a result, various thin film samples including pure thin film without any particles, thin films with only organic PMMA particles, thin films with only inorganic TiO2 particles, and thin films with organic-inorganic hybrid particles were prepared.

2.4. Characterization

A Fourier transform infrared spectrometer (FT-IR, model: Agilent, Cary 660 FTIR, Santa Clara, CA, USA) was used to analyze the chemical structure of organic, inorganic, and organic-inorganic hybrid particles. The FT-IR measurement was performed by mixing the sample and KBr in the form of pellets and then subjecting them to wavelengths in the range of 4000–500 cm−1 (8 cm−1-resolution and 30 infrared scans). A field emission scanning electron microscope (FE-SEM, model: Hitachi, SU-70, Tokyo, Japan) was used to examine the morphology and size of the organic, inorganic, and organic-inorganic hybrid particles. The FE-SEM images were measured by placing the sample on carbon tape and coating it with platinum. A thermogravimetric analysis (TGA, model: TA Instruments, SDT Q-600, New Castle, DE, USA) was carried out to determine the composition of the organic-inorganic hybrid particles. Visible, near-infrared, and shortwave-infrared spectroscopy (VNIR-SWIR, model: Malvern Panalytical, ASD LabSpec 4, Malvern, UK) equipped with a contact probe was performed to examine the diffuse reflectance of thin films embedded with hybrid particles. With the black substrate as the base line, the diffuse reflectance was measured by contacting the sample with a probe that simultaneously generates incident light and detects reflected light. A goniophotometer (Murakami Color Research Laboratory, GP-5, Tokyo, Japan) was used to examine the light scattering characteristics of the hybrid particles and obtain a soft-focus factor. Each hybrid particle was mixed with nitrocellulose collodion, which is used as a makeup matrix or surgical dressing, and measured as coated on the black substrate. The scattered light was measured in the range of 0° to 180°.

3. Results and Discussion

3.1. Structural Characterization of Hierarchical Organic-Inorganic Hybrid Polymer Microspheres

A FT-IR analysis was performed to analyze the chemical structure of the organic-inorganic hybrid particles synthesized by a simple mixing and drying process. Commonly, organic-inorganic hybrid particles have been prepared by a chemical bonding method using the electrostatic charge interactions between different particles [1,2,3,4,5,6,7,8,9,10,11]. However, the chemical bonding method requires a complex and long synthetic procedure. Therefore, the used physical mixing method can provide the fast and simple fabrication of hybrid particles using the polar interfacial interactions between polar PMMA microspheres and the polar surface of TiO2 nanoparticles. It is reported that PMMA and TiO2 nanoparticles can interact chemically and physically due to the presence of polar functional groups, offering an excellent compatibility between the two materials [51,52,53]. Figure 2a shows the FT-IR spectra of pure TiO2 nanoparticles (T1), pristine PMMA (NPP), and hybrid particles (NPP@T1). First, in the spectrum of the TiO2 nanoparticle, the Ti-O-Ti peak of TiO2 was observed broadly at 500–800 cm−1 [54]. In the spectrum of the PMMA polymer microparticle, C-H stretching vibration peaks were observed at 2951 and 2998 cm−1, and C=O carbonyl peaks were observed at 1728 and 1145 cm−1 [55]. Meanwhile, in the spectrum of the organic-inorganic hybrid particle (NPP@T1), the characteristic peaks of both T1 and NPP particles were observed. Therefore, it was confirmed that both the PMMA microparticles and TiO2 nanoparticles were incorporated into the organic-inorganic hybrid polymer microparticles. Figure 2b shows the FT-IR spectra of the prepared organic-inorganic hybrid particles. Similar spectral features were obtained for other hybrid particles, indicating the successful preparation of organic-inorganic hybrid particles.
Next, an FE-SEM analysis was performed to confirm the size and morphology of the organic-inorganic hybrid particles. Figure 3 shows FE-SEM images of pure TiO2 nanoparticles and pristine PMMA microparticles. The T1 and T2 nanoparticles exhibited angular shapes of about 20 and 250 nm, respectively. In the case of pristine PMMA, spherical particles with average diameters of about 10 μm were observed. While non-porous NPP has a smooth surface without pores, the three porous PMMA particles have a large number of pores with different sizes and regularities, as summarized in Table 1. Notably, PP1 and PP3 showed uniform pore diameters of about 400 and 200 nm, respectively, and PP2 exhibited a nonuniform pore size of about 300 nm. Figure 4 shows FE-SEM images of the prepared organic-inorganic hybrid particles. All the hybrid particles maintained the spherical morphologies of pristine PMMA microparticles, however their surface morphologies were changed to irregular and rough surfaces with a great number of TiO2 protrusions, suggesting the successful binding between PMMA microparticles and TiO2 nanoparticles. The polar interfacial interactions between polar PMMA microspheres and the polar surface of TiO2 nanoparticles could lead to the hierarchical core-shell structure of hybrid particles. These irregular and rough surfaces of the hybrid core-shell particles with high-refractive index TiO2 protrusions are expected to enhance the light scattering and diffuse reflection characteristics.
To quantitatively determine the composition of the organic-inorganic hybrid particles, a thermogravimetric analysis was performed. Figure 5 shows the TGA thermograms of pure TiO2 (T1), pristine PMMA (NPP), and organic-inorganic hybrid particles (NPP@T1). While the pure TiO2 particles maintained their initial weight even at 600 °C, a complete degradation at 500 °C was observed for pristine PMMA. In addition, a final weight loss of about 49% was detected for the NPP@T1 hybrid particle, indicating that the organic-inorganic hybrid particle prepared with a mixing ratio of 1:1 retains the exact chemical composition of TiO2:PMMA = 1:1.

3.2. Optical Properties of Hierarchical Organic-Inorganic Hybrid Polymer Microspheres

Figure 6 shows photographs of the thin polymer films embedded with organic-inorganic hybrid particles. In order to visually compare the actual appearance and transparency of the films, the manufactured films were cut into 3 × 3 cm2 sizes, respectively, and placed on paper printed with the logo. The first row showed pure thin films without any particles and thin films with only PMMA microparticles. These thin films exhibited transparent logo images due to the good compatibility and similar refractive indices between the PMMA microparticles and the acrylate-based matrix resin. The second and third rows displayed the thin films embedded with only TiO2 nanoparticles and hybrid particles, and opaque and blurry images were obtained for all samples compared to those of the pure and PMMA-embedded thin films. This result is ascribed to the light scattering effect of high-refractive index TiO2 nanoparticles in the low-refractive index acrylate-based matrix. Notably, the thin films with large-sized TiO2 nanoparticles (T2) showed much blurrier images than those with small TiO2 (T1) [56]. Based on these results, thin films embedded with organic-inorganic hybrid particles are expected to have good light scattering characteristics comparable to those with only inorganic TiO2 nanoparticles.
To examine the difference in the light scattering performance, the diffuse reflectance spectra of the pure film and thin films with only PMMA, only TiO2 nanoparticles, and hybrid particles were measured and their diffuse reflectances at 600 nm were compared [57]. A diffuse reflectance analysis on the thin films was performed using contact reflectance measuring equipment. The prepared thin films were placed on a black substrate, and incident light generated from a contact probe was absorbed or reflected by the thin films embedded with light scattering particles. Figure 7 shows the diffuse reflectance spectra of the pure film and thin films with only PMMA (PP3), only TiO2 nanoparticles (T1 and T2), and hybrid particles (PP3@T1 and PP3@T2). Pure thin film without any particles and thin films with only PP3 polymer showed low diffuse reflectances of approximately 10% and 13% at a wavelength of 600 nm due to the low refractive indices of PMMA microparticles and acrylate-based matrix, which is in accordance with the visual analysis results. On the contrary, the thin films embedded with only T1 or T2 nanoparticles exhibited high diffuse reflectances of approximately 39% and 57%, respectively, owing to the high refractive index of TiO2 nanoparticles [58]. In addition, the introduction of organic-inorganic hybrid particles into the thin films led to the improved diffuse reflectances of 48% and 62% for PP3@T1 and PP3@T2, respectively. These results suggest that the rough surface of the hybrid porous PMMA microsphere with high-refractive index TiO2 protrusions induces enhanced light scattering characteristics for organic-inorganic hybrid particles. Moreover, hybrid particles with large TiO2 nanoparticles (PP3@T2) showed a higher diffuse reflectance than those with small TiO2 (PP3@T1) due to the rougher surface structure. Table 2 and Table 3 summarize the diffuse reflectance characteristics of all the thin films at 600 nm. The organic-inorganic hybrid structure including the porous PMMA microsphere as the core and the large-sized TiO2 nanoparticles as the shell could maximize the light scattering performance. As a consequence, the thin film embedded with the PP3@T2 hybrid particle showed an about 620% higher diffuse reflectance than the pure thin film, which was 488% higher than the thin film with only NPP polymer, 160% higher than the thin film with only inorganic T1 nanoparticles, and 110% higher than the thin film with only T2 nanoparticles.

3.3. Soft-Focus Properties of Hierarchical Organic-Inorganic Hybrid Polymer Microspheres

To compare the soft-focus characteristics of the hybrid particles for potential cosmetic applications, light intensity distribution curves were measured using a goniophotometer. A schematic diagram of the goniophotometer analysis is shown in Figure 8a. Incident light from 45° was applied to the sample, and the reflected light in the range of 0°–180° was measured by the detector. The light intensities for specular reflection at 135° and diffuse reflection at 65° were named Ls and Ld, respectively. Especially, Ld can represent the cover effect of hybrid particles on skin defects due to the diffuse light scattering and resulting opacity. The soft-focus factor (SFF) for the quantitative light scattering performance is defined as in Equation (1) [59].
Soft   focus   factor   SFF   = L d L s
An SFF value of more than 0.5 indicates a good soft-focus performance, and the maximum soft-focus effect of particles can be achieved with an extremely high SFF value close to 1.0 [60]. The excellent light scattering performance of the hybrid particles can lead to high SFF values due to the increased diffuse reflection. Figure 8b shows the light intensity distribution curves of mica as a reference material for cosmetic application and hybrid particles. While the mica particles exhibited extremely low diffuse reflectance due to their flat and smooth surface, an enhanced diffuse reflection was observed for the organic-inorganic hybrid particles. In addition, the hybrid particles with large TiO2 nanoparticles showed excellent soft-focus effects compared to those with small TiO2, which is quite in accord with the diffuse reflectance results.
Figure 9 shows the SFF values of mica, pure TiO2 (T1 and T2), pristine PMMA (NPP), and hybrid particles. The organic-inorganic hybrid porous particles showed remarkably high SFF values compared to those of the conventional mica particles. The large TiO2 nanoparticles and irregular or small pore size porous PMMA particles resulted in high SFF values and excellent soft-focus effects. Basically, the refractive index difference between the PMMA core and the inorganic TiO2 shell induces good light scattering properties for hybrid particles and, furthermore, the irregular and rough surface leads to an additional improvement in the light scattering performance. Consequently, the PP3@T2 hybrid particle showed the highest SFF value of 0.85, which is about 944% higher than that of mica particles, 285% higher than that of pristine PMMA polymer, and 163% higher than that of pure T2 nanoparticles.

4. Conclusions

In this study, we fabricated highly scattering hierarchical porous polymer microspheres with a high-refractive index inorganic surface for an excellent soft-focus effect. Nano-sized TiO2 and micro-sized porous PMMA with different pore sizes and regularities were used as organic and inorganic materials for the synthesis of hierarchical hybrid particles. The thin film embedded with organic-inorganic hybrid particles showed 488% or 160% higher diffuse reflectance characteristics than those with only PMMA or TiO2 particles. The synergistic effects of the porous morphology, the refractive index difference between the organic core and inorganic shell, and the rough high-refractive index surface can provide high light scattering properties for hybrid particles. In addition, the PP3@T2 hybrid particle comprising porous PMMA microspheres with the smallest pore size and large TiO2 nanoparticles exhibited the highest SFF value among the prepared hybrid particles. The light scattering characteristics could be greatly improved by controlling the pore characteristics of the organic PMMA particles and the size of the inorganic TiO2 nanomaterial. Based on these results, it was confirmed that the pore characteristics of the polymer microsphere and the size of high-refractive index inorganic material are important factors for the design of highly scattering organic-inorganic hybrid particles. This study can provide an effective and versatile approach for achieving highly light-scattering materials with excellent soft-focus effects for potential cosmetic applications including skin coverage.

Author Contributions

J.Y. conducted the experiments. J.Y., J.B.L., and J.H.L. (Jun Hyup Lee) conceptualized the phenomenon. J.H.L. (Ji Hyun Lee) designed the project. J.B.L. and J.H.L. (Jun Hyup Lee) supervised the whole project. J.Y. and J.H.L. (Jun Hyup Lee) wrote the manuscript and analyzed the data. All authors have read and agreed to the published version of the manuscript.

Funding

This work was supported by Cosmax Co., Ltd., and by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. NRF-2018R1A5A1024127).

Conflicts of Interest

The authors declare no conflict of interest. The funders had no role in the design of the study; in the collection, analysis, or interpretation of data; in the writing of the manuscript; or in the decision to publish the results.

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Polymers 12 02418 g001 550
Figure 1. Schematic of a hierarchical organic-inorganic hybrid polymer microsphere with an excellent light scattering performance.
Figure 1. Schematic of a hierarchical organic-inorganic hybrid polymer microsphere with an excellent light scattering performance.
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Figure 2. (a) FT-IR spectra of pure TiO2 (T1), pristine PMMA (NPP), and organic-inorganic hybrid particles (NPP@T1). (b) FT-IR spectra of other porous hybrid particles.
Figure 2. (a) FT-IR spectra of pure TiO2 (T1), pristine PMMA (NPP), and organic-inorganic hybrid particles (NPP@T1). (b) FT-IR spectra of other porous hybrid particles.
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Figure 3. FE-SEM images of pure TiO2 nanoparticles and pristine PMMA microparticles.
Figure 3. FE-SEM images of pure TiO2 nanoparticles and pristine PMMA microparticles.
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Figure 4. FE-SEM images of hierarchical organic-inorganic hybrid particles.
Figure 4. FE-SEM images of hierarchical organic-inorganic hybrid particles.
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Figure 5. TGA thermograms of pure TiO2 (T1), pristine PMMA (NPP), and hybrid particles (NPP@T1).
Figure 5. TGA thermograms of pure TiO2 (T1), pristine PMMA (NPP), and hybrid particles (NPP@T1).
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Figure 6. Photographs of the pure thin film and thin films with only PMMA, only TiO2, and hybrid particles.
Figure 6. Photographs of the pure thin film and thin films with only PMMA, only TiO2, and hybrid particles.
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Figure 7. Diffuse reflectance spectra of the black substrate, pure thin film, and thin films with PP3, T1, T2, PP3@T1, and PP3@T2 particles.
Figure 7. Diffuse reflectance spectra of the black substrate, pure thin film, and thin films with PP3, T1, T2, PP3@T1, and PP3@T2 particles.
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Figure 8. (a) Schematic of the goniophotometer analysis. (b) Light intensity distribution curves of the mica and hybrid particles.
Figure 8. (a) Schematic of the goniophotometer analysis. (b) Light intensity distribution curves of the mica and hybrid particles.
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Figure 9. Soft-focus factor values of mica, T1, T2, NPP, and hybrid particles.
Figure 9. Soft-focus factor values of mica, T1, T2, NPP, and hybrid particles.
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Table
Table 1. Characteristics of PMMA microparticles and TiO2 nanoparticles.
Table 1. Characteristics of PMMA microparticles and TiO2 nanoparticles.
No.CodeMaterialAverage Particle SizeAverage Pore SizePore Uniformity
1NPPPMMA9 μmnon-porous-
2PP1PMMA12 μm400 nmuniform
3PP2PMMA11 μm300 nmnonuniform
4PP3PMMA13 μm200 nmuniform
5T1TiO220 nmnon-porous-
6T2TiO2250 nmnon-porous-
Table
Table 2. Diffuse reflectance of the pure thin film and thin films with only PMMA or TiO2 particles at 600 nm.
Table 2. Diffuse reflectance of the pure thin film and thin films with only PMMA or TiO2 particles at 600 nm.
MaterialsPure FilmNPPPP1PP2PP3T1T2
Reflectance (%)10.0 ± 0.412.7 ± 0.312.7 ± 0.112.6 ± 0.312.7 ± 0.239.1 ± 0.656.6 ± 0.8
Table
Table 3. Diffuse reflectance of the thin films with organic-inorganic hybrid particles at 600 nm.
Table 3. Diffuse reflectance of the thin films with organic-inorganic hybrid particles at 600 nm.
MaterialsNPP@T1NPP@T2PP1@T1PP1@T2PP2@T1PP2@T2PP3@T1PP3@T2
Reflectance (%)42.2 ± 0.755.8 ± 0.246.6 ± 0.559.1 ± 0.848.0 ± 0.358.4 ± 0.747.6 ± 0.462.0 ± 1.1
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Yoon, J.; Lee, J.H.; Lee, J.B.; Lee, J.H. Highly Scattering Hierarchical Porous Polymer Microspheres with a High-Refractive Index Inorganic Surface for a Soft-Focus Effect. Polymers 2020, 12, 2418. https://0-doi-org.brum.beds.ac.uk/10.3390/polym12102418

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Yoon J, Lee JH, Lee JB, Lee JH. Highly Scattering Hierarchical Porous Polymer Microspheres with a High-Refractive Index Inorganic Surface for a Soft-Focus Effect. Polymers. 2020; 12(10):2418. https://0-doi-org.brum.beds.ac.uk/10.3390/polym12102418

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Yoon, Joonsik, Ji Hyun Lee, Jun Bae Lee, and Jun Hyup Lee. 2020. "Highly Scattering Hierarchical Porous Polymer Microspheres with a High-Refractive Index Inorganic Surface for a Soft-Focus Effect" Polymers 12, no. 10: 2418. https://0-doi-org.brum.beds.ac.uk/10.3390/polym12102418

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