Effect of the Grafting Reaction of Aluminum Nitride on the Multi-Walled Carbon Nanotubes on the Thermal Properties of the Poly(phenylene sulfide) Composites
Abstract
:1. Introduction
2. Experimental
2.1. Materials
2.2. Covalent Functionalization of the MWCNTs
2.3. Surface Modification of the AlN Particles
2.4. The Grafting Reaction of the AlN Particles on the MWCNTs
2.5. Preparation of the PPS/MWCNTs/AlN Composites
2.6. Characterization
3. Results and Discussion
3.1. Characterization of the Surface Modification of the AlN Particles
3.2. Characterization of the Grafting Reaction of AlN Particles on the MWCNTs
3.3. Thermal Properties of the PPS/MWCNTs/AlN Composites
3.4. Morphological Differences of the PPS/MWCNTs/AlN Composites
4. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Sample code | fMWCNTs (wt %) | AlN (wt %) | Silane treated AlN (wt %) |
---|---|---|---|
PPSHP1 | 1 | - | - |
PPSHP1AlN10 | 10 | - | |
PPSHP1AlN20 | 20 | ||
PPSHP1sAlN10 | - | 10 | |
PPSHP1sAlN20 | 20 |
Sample | Elemental composition (at %) | ||||
---|---|---|---|---|---|
Al | N | C | O | Si | |
AlN | 30.8 | 15.2 | 28.5 | 25.5 | - |
Silane treated AlN | 20.7 | 9.2 | 35.2 | 30.3 | 4.6 |
Sample | Temperature at weight loss (°C) | Heat-resistance index (°C) | |
---|---|---|---|
5 wt % | 30 wt % | ||
Neat PPS | 492.36 | 531.97 | 252.90 |
PPSHP1 | 498.12 | 538.23 | 255.87 |
PPSHP1AlN10 | 503.53 | 547.58 | 259.68 |
PPSHP1AlN20 | 507.97 | 558.12 | 263.65 |
PPSHP1sAlN10 | 492.84 | 555.99 | 260.06 |
PPSHP1sAlN20 | 472.01 | 558.40 | 256.68 |
Sample | (°C) | (°C) | (J/g) | (°C) | (J/g) | (%) | Ref |
---|---|---|---|---|---|---|---|
Neat PPS | 89.09 | 244.28 | 45.97 | 282.84 | 37.06 | 48.44 | [34] |
PPSHP1 | 94.72 | 246.18 | 45.22 | 283.31 | 40.81 | 53.89 | |
PPSHP1AlN10 | 100.75 | 248.77 | 37.69 | 284.65 | 34.21 | 50.25 | - |
PPSHP1AlN20 | 99.71 | 251.13 | 32.40 | 285.04 | 30.69 | 50.78 | |
PPSHP1sAlN10 | 102.40 | 248.97 | 39.16 | 284.52 | 35.56 | 52.23 | |
PPSHP1sAlN20 | 95.29 | 251.08 | 39.39 | 284.79 | 37.03 | 61.27 |
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Kim, M.; Park, S.; Park, J. Effect of the Grafting Reaction of Aluminum Nitride on the Multi-Walled Carbon Nanotubes on the Thermal Properties of the Poly(phenylene sulfide) Composites. Polymers 2017, 9, 452. https://0-doi-org.brum.beds.ac.uk/10.3390/polym9090452
Kim M, Park S, Park J. Effect of the Grafting Reaction of Aluminum Nitride on the Multi-Walled Carbon Nanotubes on the Thermal Properties of the Poly(phenylene sulfide) Composites. Polymers. 2017; 9(9):452. https://0-doi-org.brum.beds.ac.uk/10.3390/polym9090452
Chicago/Turabian StyleKim, Myounguk, Sunmin Park, and Jongshin Park. 2017. "Effect of the Grafting Reaction of Aluminum Nitride on the Multi-Walled Carbon Nanotubes on the Thermal Properties of the Poly(phenylene sulfide) Composites" Polymers 9, no. 9: 452. https://0-doi-org.brum.beds.ac.uk/10.3390/polym9090452