Advanced Nanoindentation in Materials

A special issue of Crystals (ISSN 2073-4352). This special issue belongs to the section "Inorganic Crystalline Materials".

Deadline for manuscript submissions: closed (31 May 2021) | Viewed by 9777

Special Issue Editors


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Guest Editor
Arts et Metiers Institute of Technology, MSMP, HESAM Université, F-59000 Lille, France
Interests: instrumented indentation; mechanical properties; plasticity; processing models; microcompression

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Guest Editor
LGCgE- ULR 4515, Université Lille, F- 59653 Villeneuve D’ascq, France
Interests: instrumented indentation; mechanical properties; residual stress; X-ray diffraction; coated materials

Special Issue Information

Dear Colleagues,

Indentation tests, intimately linked to hardness measurements, are some of the easiest tests to administer. They are performed by pressing the tip of known shape and recording the properties at the surface of a specimen. The ratio between the applied load and the size of the residual imprint gives the “hardness” of the material. Since the 1980s, indentation tests have been fully instrumented and the applied load and penetration depth of the tip are continuously recorded. The resulting so-called load-displacement curve is then processed with models in order to extract a wide range of mechanical properties such as hardness, elastic modulus, toughness, and residual stress. Moreover, applied loads have been reduced to micronewtons or less, leading to new insights into the properties and mechanisms of deformation at very small scales. Taking advantage of the reduced volumes stressed during indentation, researchers use this technique for complex material analysis of, for example, coated systems, porous materials, or even multiphasic material. Instrumented indentation has now become an essential technique in the panel of mechanical characterization.

Instrumental indentation can be now combined with other techniques for in situ testing (under SEM and X-ray diffraction) or performed in a controlled environment (high or low temperature in liquid), and recent advances afford the opportunity to probe the mechanical response at a wide range of strain rates.

We invite you to contribute to the Special Issue, “Advanced Nanoindentation in Materials”, of Crystals dedicated to the development of techniques and applications of material analysis.

Dr. Alex Montagne
Dr. Fancine Roudet
Guest Editors

Manuscript Submission Information

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Keywords

  • instrumented indentation
  • mechanical properties
  • mechanisms of deformation
  • behavior laws
  • complex materials (nanostructured, heterogeneous, etc.)
  • harsh environment (temperature, strain rate, etc.)
  • experiments and simulations
  • coated materials

Published Papers (3 papers)

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Research

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17 pages, 4293 KiB  
Article
Combinatorial Materials Design Approach to Investigate Adhesion Layer Chemistry for Optimal Interfacial Adhesion Strength
by Rachel L. Schoeppner, Barbara Putz, Aidan A. Taylor, Laszlo Pethö, Keith Thomas, Olivier Antonin, Thomas Nelis and Johann Michler
Crystals 2021, 11(4), 357; https://0-doi-org.brum.beds.ac.uk/10.3390/cryst11040357 - 30 Mar 2021
Cited by 3 | Viewed by 3040
Abstract
A combinatorial material adhesion study was used to optimize the composition of an adhesion promoting layer for a nanocrystalline diamond (NCD) coating on silicon. Three different adhesion promoting metals, namely W, Cr, and Ta, were selected to fabricate arrays of co-sputtered binary alloy [...] Read more.
A combinatorial material adhesion study was used to optimize the composition of an adhesion promoting layer for a nanocrystalline diamond (NCD) coating on silicon. Three different adhesion promoting metals, namely W, Cr, and Ta, were selected to fabricate arrays of co-sputtered binary alloy films, with patches of seven different, distinct alloy compositions for each combination, and single element reference films on a single Si wafer (three wafers in total; W–Cr, Cr–Ta, Ta–W). Scratch testing was used to determine the critical failure load and practical work of adhesion for the NCD coatings as a function of adhesion layer chemistry. All tested samples eventually exhibit delamination of the NCD coating, with buckles radiating perpendicularly away from the scratch track. Application of any of the presented adhesion layers yields an increase of the critical failure load for delamination as compared to NCD on Si. While the influence of adhesion layers on the maximum buckle length is less pronounced, shorter buckles are obtained with pure W and Cr–Ta alloy layers. As a general rule, the addition of an adhesion layer showed a 75% improvement in the measured adhesion energies of the NCD films compared to the NCD coating without an adhesion layer, with specific alloys and compositions showing up to 125% increase in calculated practical work of adhesion. Full article
(This article belongs to the Special Issue Advanced Nanoindentation in Materials)
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13 pages, 2416 KiB  
Article
An Attempt to Assess Recovery/Recrystallization Kinetics in Tungsten at High Temperature Using Statistical Nanoindentation Analysis
by Liz Karanja, Matthieu Lenci, David Piot, Claire Maurice, Alan Durif, Marianne Richou, Laurent Gallais, Marco Minissale and Guillaume Kermouche
Crystals 2021, 11(1), 37; https://0-doi-org.brum.beds.ac.uk/10.3390/cryst11010037 - 31 Dec 2020
Cited by 7 | Viewed by 1953
Abstract
Measurement of recovery and recrystallization kinetics of tungsten at high temperature is a key issue for many applications, such as plasma facing units in the framework of thermonuclear fusion. These kinetics are mostly derived from Vickers hardness and EBSD measurements, which can lead [...] Read more.
Measurement of recovery and recrystallization kinetics of tungsten at high temperature is a key issue for many applications, such as plasma facing units in the framework of thermonuclear fusion. These kinetics are mostly derived from Vickers hardness and EBSD measurements, which can lead to some inaccuracies due to the competition between recovery and recrystallization mechanisms. A complementary/alternative approach based on statistical grid nanoindentation is proposed in this paper. The basic idea is to assume that the fraction recrystallized can be deduced using the hardness probability density function measured on a fully recrystallized sample. The hardness probability density function of the set of non-recrystallized grains can then be analyzed. The methodology was applied to rolled tungsten samples annealed at high temperature. It was clearly observed that recovery and recrystallization overlapped in terms of softening fraction in the investigated time–temperature range. Activation energy of the static recovery mechanism is in the correct order of magnitude compared to bulk self-diffusion in tungsten. High-throughput nanoindentation analysis appears as a promising way to investigate recrystallization/recovery mechanisms in metals. Full article
(This article belongs to the Special Issue Advanced Nanoindentation in Materials)
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Review

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22 pages, 4524 KiB  
Review
Novel Nitride Materials Synthesized at High Pressure
by Pei Wang, Shanmin Wang, Yongtao Zou, Jinlong Zhu, Duanwei He, Liping Wang and Yusheng Zhao
Crystals 2021, 11(6), 614; https://0-doi-org.brum.beds.ac.uk/10.3390/cryst11060614 - 29 May 2021
Cited by 6 | Viewed by 3899
Abstract
Nitride materials including conventional manmade superhard light-element nitrides, such as cubic boron nitride (cBN), cubic silicon nitride (γ-Si3N4), and carbonitrides, have been extensively used for machining (e.g., turning, cutting, grinding, boring, drilling) and coating of ferr ous alloys due [...] Read more.
Nitride materials including conventional manmade superhard light-element nitrides, such as cubic boron nitride (cBN), cubic silicon nitride (γ-Si3N4), and carbonitrides, have been extensively used for machining (e.g., turning, cutting, grinding, boring, drilling) and coating of ferr ous alloys due to their remarkable performances of high rigidity, high melting-point, and prominent chemical and thermal stabilities. However, to some degree, superhard nitrides merely compensate for the adverse limitations of diamond: reaction (with iron), oxidation, and graphitization at moderate temperatures; they are still unable to dominate the market owing to their relatively low hardness when compared to diamond. Therefore, recent efforts toward the preparation of nitride materials with outstanding mechanical performance and chemical inertness have focused on synthesizing ternary light-element nitride compounds and harvesting the effect of work hardening through microstructure manipulations. These new light-element nitrides are potential candidates to displace diamond in the cutting business. On the other hand, incorporation of transition-metal atoms into the dinitrogen triple-bond can form novel hard transition-metal nitride alloys (TMNAs), such as Mo-N, W-N, Pt-N, Ir-N, Os-N, etc., which are potential candidates for the cutting, coating, and polishing of iron-group metals. However, synthesis of high-crystallinity and stoichiometric TMNAs via traditional routes is challenging, since the embedded nitrogen in the transition-metal lattice is thermodynamically unfavorable at ambient condition. A novel approach involving ion-exchange reactions under moderate pressure and temperature has been developed in recent years for preparation of well-crystallized stoichiometric TMNAs, which have quickly been realized as emergent materials in electronics, catalysts, and superconductors as well. Full article
(This article belongs to the Special Issue Advanced Nanoindentation in Materials)
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