Two-Dimensional Materials for Energy Applications

A special issue of Crystals (ISSN 2073-4352). This special issue belongs to the section "Materials for Energy Applications".

Deadline for manuscript submissions: closed (15 September 2021) | Viewed by 11470

Special Issue Editors


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Guest Editor
Frontier Research Institute for Interdisciplinary Sciences, Tohoku University, Sendai, Japan
Interests: thermoelectricity; artificial muscles; nanomechanics; first-principles calculations
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Research Center for Physics, Indonesian Institute of Sciences (LIPI), Jakarta, Indonesia
Interests: solid-state physics; low-dimensional materials
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China
Interests: electronic and lattice vibrational properties in low-dimensional systems, including atomic layers and van der Waals Moiré superlattices; electron–photon and electron–phonon coupling and their significance in spectroscopy; development and applications of computer software to the relevant study
Special Issues, Collections and Topics in MDPI journals

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Foundation for Research, Technology Hellas-Institute of Chemical Engineering Sciences (FORTH/ICE-HT), GR 26504 Patras, Greece
Interests: graphene; 2D materials; mechanical properties of 2D materials; raman and tip Enhanced raman spectroscopy of 2D materials; CVD growth of 2D materials; laser patterning of 2D materials; graphene inks and RFID tags; low friction nanocomposites; device design for nanomechanics of 2D materials
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

In our daily lives, energy is consumed a lot in homes, workplaces, and communities in which complex networks or social relations exist. Therefore, energy demand can be a cause of social and political unrest. A growing focus in energy research is to find strategies to promote shifts toward a sustainable energy future, in which the integration of two-dimensional (2D) materials in batteries, thermoelectric, supercapacitors, photovoltaics, photocatalysis, and devices for energy harvesting offers opportunities to tackle challenges in energy applications. Various 2D crystals, such as graphene, black phosphorus, transition metal dichalcogenides (e.g., MoS2, MoSe2, WSe2), and MXenes, have flexibility, a large surface area, and chemical stability, which, combined with their excellent electrical and thermal conductivities, make them promising for portable and wearable energy devices. In addition, the advantage of using the 2D crystals is the possibility of designing and creating extremely large “artificial” structures based on van der Waals heterostructures. This approach can tune new properties in a material that can address emerging energy needs.

Here, we especially invite researchers to submit original and review papers related to two major sections for applying the 2D crystals: (1) energy conversion (thermoelectrics, photovoltaics, photocatalysts or fuel cells) and (2) storage (batteries, hydrogen storage, or supercapacitors). Beyond the two major sections, in this Special Issue, we also would like to invite contributions in other emerging energy applications such as water splitting and piezoelectric-based energy generators to reflect the broad field of the energy applications. Therefore, we very much look forward to your valued contributions to this Special Issue.

Dr. Nguyen Tuan Hung
Dr. Ahmad Ridwan Tresna Nugraha
Prof. Dr. Teng Yang
Dr. John Parthenios
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Crystals is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • 2D materials for thermoelectrics
  • 2D materials for photocatalysis
  • 2D materials for photovoltaics
  • 2D materials for energy storage
  • Piezoelectricity of 2D materials for mechanical energy harvesting
  • Theory and modeling of 2D materials and related energy applications

Published Papers (3 papers)

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Research

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12 pages, 1380 KiB  
Article
Electronic, Optical, and Thermoelectric Properties of Bulk and Monolayer Germanium Tellurides
by Wenny V. Sinambela, Sasfan A. Wella, Fitri S. Arsyad, Nguyen Tuan Hung and Ahmad R. T. Nugraha
Crystals 2021, 11(11), 1290; https://0-doi-org.brum.beds.ac.uk/10.3390/cryst11111290 - 25 Oct 2021
Cited by 5 | Viewed by 3514
Abstract
Electronic, optical, and thermoelectric properties of germanium tellurides (GeTe) were investigated through a series of first-principles calculations of band structures, absorption coefficients, and thermoelectric transport coefficients. We consider bulk GeTe to consist of cubic and rhombohedral phases, while the two-dimensional (2D) GeTe monolayers [...] Read more.
Electronic, optical, and thermoelectric properties of germanium tellurides (GeTe) were investigated through a series of first-principles calculations of band structures, absorption coefficients, and thermoelectric transport coefficients. We consider bulk GeTe to consist of cubic and rhombohedral phases, while the two-dimensional (2D) GeTe monolayers can form as a 2D puckered or buckled honeycomb crystals. All of the GeTe variants in the bulk and monolayer shapes are excellent light absorbers in a wide frequency range: (1) bulk cubic GeTe in the near-infrared regime, (2) bulk rhombohedral GeTe and puckered monolayer GeTe in the visible-light regime, and (3) buckled monolayer GeTe in the ultraviolet regime. We also found specifically that the buckled monolayer GeTe exhibits remarkable thermoelectric performance compared to the other GeTe phases due to a combination of electronic band convergence, a moderately wide band gap, and unique 2D density of states from the quantum confinement effect. Full article
(This article belongs to the Special Issue Two-Dimensional Materials for Energy Applications)
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12 pages, 3263 KiB  
Article
Three-Dimensional Flower-like Fe, C-Doped-MoS2/Ni3S2 Heterostructures Spheres for Accelerating Electrocatalytic Oxygen and Hydrogen Evolution
by Xuefeng Lv, Guangsheng Liu, Song Liu, Wenting Chen, Dehua Cao, Taize Song, Nannan Wang and Yanqiu Zhu
Crystals 2021, 11(4), 340; https://0-doi-org.brum.beds.ac.uk/10.3390/cryst11040340 - 28 Mar 2021
Cited by 14 | Viewed by 3098
Abstract
The exploration of high-efficiency bifunctional electrocatalysts for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) has long been challenging. The rational design of a catalyst by constructing heterostructures and a doping element are possibly expected to achieve it. Herein, the utilization of [...] Read more.
The exploration of high-efficiency bifunctional electrocatalysts for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) has long been challenging. The rational design of a catalyst by constructing heterostructures and a doping element are possibly expected to achieve it. Herein, the utilization of flower-like Fe/C-doped-MoS2/Ni3S2-450 spherical structural materials for electrocatalytic HER and OER is introduced in this study. The carboxyferrocene-incorporated molybdenum sulfide/nickel sulfide (MoySx/NiS) nanostructures were prepared by solvothermal method. After annealing, the iron and carbon elements derived from ferrocenecarboxylic acid enhanced the electrical transport performance and provided rich electronic sites for HER and OER in alkaline media. Specifically, the optimized flower-like Fe/C-doped-MoS2/Ni3S2-450 exhibited efficient bifunctional performance in alkaline electrolyte, with low overpotentials of 188 and 270 mV required to deliver a current density of 10 mA cm−2 for HER and OER, respectively. This work provides valuable insights for the rational design of energy storage and conversion materials by the incorporation of transition metal and carbon elements into metal sulfide structures utilizing metallocene. Full article
(This article belongs to the Special Issue Two-Dimensional Materials for Energy Applications)
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Review

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17 pages, 1873 KiB  
Review
Recent Advances in Graphene and Conductive Polymer Composites for Supercapacitor Electrodes: A Review
by Xinwei Cai, Kangkang Sun, Yangshuai Qiu and Xuan Jiao
Crystals 2021, 11(8), 947; https://0-doi-org.brum.beds.ac.uk/10.3390/cryst11080947 - 14 Aug 2021
Cited by 28 | Viewed by 3614
Abstract
Supercapacitors (SCs) have generated a great deal of interest regarding their prospects for application in energy storage due to their advantages such as long life cycles and high-power density. Graphene is an excellent electrode material for SCs due to its high electric conductivity [...] Read more.
Supercapacitors (SCs) have generated a great deal of interest regarding their prospects for application in energy storage due to their advantages such as long life cycles and high-power density. Graphene is an excellent electrode material for SCs due to its high electric conductivity and highly specific surface area. Conductive polymers (CPs) could potentially become the next-generation SC electrodes because of their low cost, facile synthesis methods, and high pseudocapacitance. Graphene/CP composites show conspicuous electrochemical performance when used as electrode materials for SCs. In this article, we present and summarize the synthesis and electrochemical performance of graphene/CP composites for SCs. Additionally, the method for synthesizing electrode materials for better electrochemical performance is discussed. Full article
(This article belongs to the Special Issue Two-Dimensional Materials for Energy Applications)
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