Use of Nano-/Microscale Materials to Control Physical/Chemical Processes

A special issue of Micromachines (ISSN 2072-666X). This special issue belongs to the section "D:Materials and Processing".

Deadline for manuscript submissions: closed (1 March 2022) | Viewed by 2148

Special Issue Editor


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Guest Editor
Department of Electrical and Biomedical Engineering, University of Vermont, Burlington, VT 05405, USA
Interests: plasma processing of electronic nano-materials; low temperature growth of thin epitaxial, heteroepitaxial and layers of one dimensional nano-structures
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Special Issue Information

Dear Colleagues, 

I would like to invite you to submit your unpublished research work on the use of nano-/microscale (N/M) materials that, as a result of their dimensions, control whether a physical or chemical process will occur. One example is the observed melting of N/M structures in high-temperature materials upon irradiation and the absorption of infrared radiation. The application of a related ability can be found in the fabrication of an electrochemical catalyst structure used on the input/output surface of a PEM fuel cell, converting stored chemical energy into electrical energy. The reverse of this specific process would involve another catalyst material film used in a PEM chemical generator found in a system converting harvested solar power into stored chemical energy, such as hydrogen. 

Nanoscale membranes can also be used as selectively permeable filters or as components in electrochemical devices. An application of N/M materials used in the transition of energy involves a freestanding nanoscale membrane that permits the free flow of ionic species in a chemical reactor. A specific example would be a graphene membrane used as a H+-permeable membrane in a PEM electrolyzer cell. A further example of this process could be a membrane controlling the flow of ions in a solid-state battery. 

In all cases, the manuscripts should clearly explain proposed physical processes that are made possible with N/M-sized materials. 

Prof. Dr. Walter Varhue
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Micromachines is an international peer-reviewed open access monthly journal published by MDPI.

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Keywords

  • Electrochemical catalyst
  • Selectively permeable membrane
  • Activation
  • Energy
  • Electric field enhancement
  • Quantum mechanical tunneling
  • Phonon isolation.

Published Papers (1 paper)

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Research

11 pages, 3279 KiB  
Article
RuO2 Nanorods as an Electrocatalyst for Proton Exchange Membrane Water Electrolysis
by Michael W. Cross, Richard P. Smith III and Walter J. Varhue
Micromachines 2021, 12(11), 1412; https://0-doi-org.brum.beds.ac.uk/10.3390/mi12111412 - 17 Nov 2021
Cited by 3 | Viewed by 1726
Abstract
A custom-built PEM electrolyzer cell was assembled using 6” stainless-steel ConFlat flanges which were fitted with a RuO2 nanorod-decorated, mixed metal oxide (MMO) ribbon mesh anode catalyst. The current density–voltage characteristics were measured for the RuO2 nanorod electrocatalyst while under constant [...] Read more.
A custom-built PEM electrolyzer cell was assembled using 6” stainless-steel ConFlat flanges which were fitted with a RuO2 nanorod-decorated, mixed metal oxide (MMO) ribbon mesh anode catalyst. The current density–voltage characteristics were measured for the RuO2 nanorod electrocatalyst while under constant water feed operation. The electrocatalytic behavior was investigated by making a series of physical modifications to the anode catalyst material. These experiments showed an improved activity due to the RuO2 nanorod electrocatalyst, resulting in a corresponding decrease in the electrochemical overpotential. These overpotentials were identified by collecting experimental data from various electrolyzer cell configurations, resulting in an improved understanding of the enhanced catalytic behavior. The micro-to-nano surface structure of the anode electrocatalyst layer is a critical factor determining the overall operation of the PEM electrolyzer. The improvement was determined to be due to the lowering of the potential barrier to electron escape in an electric field generated in the vicinity of a nanorod. Full article
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