Advanced Ceramic and Glass Devices

A special issue of Micromachines (ISSN 2072-666X). This special issue belongs to the section "D:Materials and Processing".

Deadline for manuscript submissions: closed (31 October 2022) | Viewed by 13006

Special Issue Editor


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Guest Editor
School of Mechanical and Electrical Engineering, University of Electronic Science and Technology of China, Chengdu 611731, China
Interests: hydrogen energy; electrochemical devices; energy and environmental sciences; nanoscale materials; fuel cells
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Special Issue Information

Dear Colleagues,

Advanced ceramic and glass devices have gained a great deal of attention in the last couple of years, which can make significant energy and environmental reforms to the world. This has given rise to the research and development of fuel cells, electrolysis cells, solid-state batteries, solar cells, supercapacitors, sensors, detectors, photoelectrochemical cells, membrane reactors, integrated circuits, micro-electro-mechanical system, as well as many other energy and environmental technologies. Recently, there has been huge interest in exploring solid-state devices based on ceramic and glass materials with the aim of high safety, high performance and good economy that might be the key technologies to solve the energy and environmental problems in the future. However, the development of advanced ceramic and glass devices do tend to be limited by the core contact issues taking place at a great number of solid-solid interfaces. These solid-solid interfaces will play a significant role in the overall device performance.

Accordingly, this Special Issue seeks to display original research papers and review articles that focus on advanced materials, theoretical and experimental studies, and device and system manufacturing for energy and environmental applications in advanced ceramic and glass devices.

Prof. Dr. Bin Lin
Guest Editor

Manuscript Submission Information

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Keywords

  • ceramic and glass devices
  • energy conversion and storage
  • ceramic materials
  • glass materials
  • fuel cells
  • electrolysis cells
  • solid-state batteries
  • solar cells
  • supercapacitors
  • sensors
  • detectors
  • photoelectrochemical cells
  • membrane reactors
  • integrated circuits
  • micro-electro-mechanical system

Published Papers (5 papers)

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Research

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13 pages, 8970 KiB  
Article
Effect of Al2O3 and ZrO2 Filler Material on the Microstructural, Thermal and Dielectric Properties of Borosilicate Glass-Ceramics
by Dilara Arıbuğa, Oğuz Karaahmet, Özge Balcı-Çağıran and Buğra Çiçek
Micromachines 2023, 14(3), 595; https://0-doi-org.brum.beds.ac.uk/10.3390/mi14030595 - 02 Mar 2023
Cited by 2 | Viewed by 1248
Abstract
Various glass-ceramics are widely used or considered for use as components of microelectronic materials due to their promising properties. In this study, borosilicate glass was prepared using the powder metallurgical route and then mixed with different amounts of Al2O3 and [...] Read more.
Various glass-ceramics are widely used or considered for use as components of microelectronic materials due to their promising properties. In this study, borosilicate glass was prepared using the powder metallurgical route and then mixed with different amounts of Al2O3 and ZrO2 filler materials. Glass-ceramics are produced by high-energy ball milling and conventional sintering process under Ar or air. In this study, the effects of different filler materials and different atmospheres on the microstructural, thermal and dielectric properties were investigated. The data showed that ZrO2 filler material led to better results than Al2O3 under identical working conditions and similar composite structures. ZrO2 filler material significantly enhanced the densification process of glass-ceramics (100% relative density) and led to a thermal conductivity of 2.904 W/K.m, a dielectric constant of 3.97 (at 5 MHz) and a dielectric loss of 0.0340 (at 5 MHz) for the glass with 30 wt.% ZrO2 sample. This paper suggests that prepared borosilicate glass-ceramics have strong sinterability, high thermal conductivity, and low dielectric constants, making them promising candidates for microelectronic devices. Full article
(This article belongs to the Special Issue Advanced Ceramic and Glass Devices)
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11 pages, 2925 KiB  
Article
Enhanced Performance of La0.8Sr0.2FeO3-δ-Gd0.2Ce0.8O2-δ Cathode for Solid Oxide Fuel Cells by Surface Modification with BaCO3 Nanoparticles
by Halefom G. Desta, Yang Yang, Birkneh Sirak Teketel, Quan Yang, Kai Song, Shiyue Zhu, Dong Tian, Yonghong Chen, Tianyong Luo and Bin Lin
Micromachines 2022, 13(6), 884; https://0-doi-org.brum.beds.ac.uk/10.3390/mi13060884 - 31 May 2022
Cited by 7 | Viewed by 2154
Abstract
Recently, Fe-based perovskite oxides, such as Ln1-xSrxFeO3-δ (Ln = La, Pr, Nd, Sm, Eu) have been proposed as potential alternative electrode materials for solid oxide fuel cells (SOFCs), due to their good phase stability, electrocatalytic activity, and low [...] Read more.
Recently, Fe-based perovskite oxides, such as Ln1-xSrxFeO3-δ (Ln = La, Pr, Nd, Sm, Eu) have been proposed as potential alternative electrode materials for solid oxide fuel cells (SOFCs), due to their good phase stability, electrocatalytic activity, and low cost. This work presents the catalytic effect of BaCO3 nanoparticles modified on a cobalt-free La0.8Sr0.2FeO3-δ-Gd0.2Ce0.8O2-δ (LSF-GDC) composite cathode at an intermediate-temperature (IT)-SOFC. An electrochemical conductivity relaxation investigation (ECR) shows that the Kchem value of the modified LSF-GDC improves up to a factor of 17.47, demonstrating that the oxygen reduction process is effectively enhanced after surface impregnation by BaCO3. The area-specific resistance (ASR) of the LSF-GDC cathode, modified with 9.12 wt.% BaCO3, is 0.1 Ω.cm2 at 750 °C, which is about 2.2 times lower than that of the bare cathode (0.22 Ω.cm2). As a result, the anode-supported single cells, with the modified LSF-GDC cathode, deliver a high peak power density of 993 mW/cm2 at 750 °C, about 39.5% higher than that of the bare cell (712 mW/cm2). The single cells based on the modified cathode also displayed good performance stability for about 100 h at 700 °C. This study demonstrates the effectiveness of BaCO3 nanoparticles for improving the performance of IT-SOFC cathode materials. Full article
(This article belongs to the Special Issue Advanced Ceramic and Glass Devices)
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13 pages, 3222 KiB  
Article
The Grain Growth Control of ZnO-V2O5 Based Varistors by PrMnO3 Addition
by Maofeng Xu, Changkun Cai, Yu Shi, Manyi Xie, Yanlong Wu, Yuanyuan Liu, Jun Peng, Jinxiao Bao and Shengli An
Micromachines 2022, 13(2), 214; https://0-doi-org.brum.beds.ac.uk/10.3390/mi13020214 - 29 Jan 2022
Cited by 4 | Viewed by 2029
Abstract
In this study, the grain growth behaviour of ZnO-V2O5-based ceramics with 0.25–0.75 mol% additions of PrMnO3 was systematically investigated during sintering from 850 °C to 925 °C. with the aim to control the ZnO grain size for their [...] Read more.
In this study, the grain growth behaviour of ZnO-V2O5-based ceramics with 0.25–0.75 mol% additions of PrMnO3 was systematically investigated during sintering from 850 °C to 925 °C. with the aim to control the ZnO grain size for their application as varistors. It was found that with the increased addition of PrMnO3, in addition to the decrease in the average grain size, the grain size distribution also narrowed and eventually changed from a bimodal to unimodal distribution after a 0.75 mol% PrMnO3 addition. The grain growth control was achieved by a pinning effect of the secondary ZnCr2O4 and PrVO4 phases at the ZnO grain boundaries. The apparent activation energy of the ZnO grain growth in these ceramics was found to increase with increased additions of PrVO4, hence the observed reduction in the ZnO grain sizes. Full article
(This article belongs to the Special Issue Advanced Ceramic and Glass Devices)
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7 pages, 1388 KiB  
Article
Facile Preparation of Mesoporous MCM-48 Containing Silver Nanoparticles with Fly Ash as Raw Materials for CO Catalytic Oxidation
by Dong Tian, Yonghong Chen, Xiaoyong Lu, Yihan Ling and Bin Lin
Micromachines 2021, 12(7), 841; https://0-doi-org.brum.beds.ac.uk/10.3390/mi12070841 - 19 Jul 2021
Cited by 4 | Viewed by 1892
Abstract
An environmentally friendly method was proposed to prepare mesoporous Mobil Composition of Matter No.48 (MCM-48) using fly ash as the silica source. Silver nanoparticles were infiltrated on MCM-48 facilely by an in situ post-reduction method and evaluated as an effective catalyst for CO [...] Read more.
An environmentally friendly method was proposed to prepare mesoporous Mobil Composition of Matter No.48 (MCM-48) using fly ash as the silica source. Silver nanoparticles were infiltrated on MCM-48 facilely by an in situ post-reduction method and evaluated as an effective catalyst for CO oxidation. The as-prepared MCM-48 and Ag/MCM-48 nanoparticles were characterized by XRD, N2 adsorption/desorption, and TEM. Investigations by means of XPS for Ag/MCM-48 were performed in order to illuminate the surface composition of the samples. Studies revealed the strong influence of the loading of Ag nanoparticles on catalysts in the oxidation of CO. CO conversion values for Ag/MCM-48 of 10% and 100% were achieved at temperatures of 220 °C and 270 °C, respectively, indicating that the Ag-decorated MCM-48 catalyst is extremely active for CO oxidation. Full article
(This article belongs to the Special Issue Advanced Ceramic and Glass Devices)
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Review

Jump to: Research

20 pages, 3779 KiB  
Review
A Comprehensive Review of Micro/Nano Precision Glass Molding Molds and Their Fabrication Methods
by Md. Ali Asgar, Jun Kim, Muhammad Refatul Haq, Taekyung Kim and Seok-min Kim
Micromachines 2021, 12(7), 812; https://0-doi-org.brum.beds.ac.uk/10.3390/mi12070812 - 12 Jul 2021
Cited by 13 | Viewed by 4799
Abstract
Micro/nano-precision glass molding (MNPGM) is an efficient approach for manufacturing micro/nanostructured glass components with intricate geometry and a high-quality optical finish. In MNPGM, the mold, which directly imprints the desired pattern on the glass substrate, is a key component. To date, a wide [...] Read more.
Micro/nano-precision glass molding (MNPGM) is an efficient approach for manufacturing micro/nanostructured glass components with intricate geometry and a high-quality optical finish. In MNPGM, the mold, which directly imprints the desired pattern on the glass substrate, is a key component. To date, a wide variety of mold inserts have been utilized in MNPGM. The aim of this article is to review the latest advances in molds for MNPGM and their fabrication methods. Surface finishing is specifically addressed because molded glass is usually intended for optical applications in which the surface roughness should be lower than the wavelength of incident light to avoid scattering loss. The use of molds for a wide range of molding temperatures is also discussed in detail. Finally, a series of tables summarizing the mold fabrication methods, mold patterns and their dimensions, anti-adhesion coatings, molding conditions, molding methods, surface roughness values, glass substrates and their glass transition temperatures, and associated applications are presented. This review is intended as a roadmap for those interested in the glass molding field. Full article
(This article belongs to the Special Issue Advanced Ceramic and Glass Devices)
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