Sustainable Development Goal 6: Clean Water and Sanitation (43898)

Conserving clean and safe freshwater is a global challenge, with nitrogen (N) and phosphorus (P) as frequent limiting factors affecting water quality due to eutrophication. This paper provides a critical overview of the spatiotemporal variability in both nutrient concentrations and their total mass ratio (TN:TP) in the canal network of the Hydro system Danube–Tisza–Danube at 21 measuring locations monitored by the Environmental Protection Agency of the Republic of Serbia over a length of almost 1000 km, collected once a month during the last decade. A spatiotemporal variation in nutrient concentrations in the tested surface water samples was confirmed by correlations and cluster analyses. The highest TN concentrations were found in winter and early spring (non-vegetation season), and the highest TP concentrations in the middle of the year (vegetation season). The TN:TP mass ratio as an indicator of the eutrophication pointed out N and P co-limitation (TN:TP 8–24) in 64% of samples, N limitation (TN:TP < 8) was detected in 27% and P limitation (TN:TP > 24) in the remaining 9% of water samples. Such observations indicate slow-flowing, lowland water courses exposed to the effects of non-point and point contamination sources as nutrient runoff from the surrounding farmlands and/or urban and industrial zones, but further investigation is needed for clarification. These results are an important starting point for reducing N and P runoff loads and controlling source pollution to improve water quality and underpin recovery from eutrophication in the studied watershed. Full article

Algeria is a wealthy country with natural resources, namely, nuclear, renewable, and non-renewable sources. The non-renewable energy sources are considered the lion’s share for energy production (98%). Algeria’s efforts to ensure and strengthen its energy security will take an important step in the coming decades by commissioning new energy infrastructure based on intensive use of water, coal, nuclear, non-renewable, and renewable sources. The implementation of new power infrastructure is expected to be operational from 2030. The renewable power realization in Algeria is relatively less compared to other African countries, i.e., Morocco, Egypt, South Africa, etc. The total renewable power installed capacity in Algeria reached 686 MW in 2020, as part of its national energy portfolio, although the Algerian government has spent tremendous efforts on introducing new sustainable technologies to enable the transition towards a cleaner and sustainable energy system. Indeed, the country announced its plan to install around 22 GW of renewable energy capacity by 2030. It will include 1 GW bio-power from the waste, 13.5 GW from solar PV, 2 GW from CSP, 15 MW from geothermal, 400 MW cogeneration, and, finally, 5 GW from wind. The scope of the present research provides general information about the usage of energy resources such as fossil, nuclear, and renewable sources in Algeria and also covers the energy supply outlook. The present effort is the first of its kind which discusses the application of the coal and nuclear as clean energy sources as part of renewable energy transition. Additionally, it also includes the description of the existing Algerian energy sector and information about water and water desalination and their usage in other sectors. Full article

Wastewater treatment plants (WWTPs) are important contributors to global greenhouse gas (GHG) emissions, partly due to their huge emission of nitrous oxide (N₂O), which has a global warming potential of 298 CO₂ equivalents. Anaerobic ammonium-oxidizing (anammox) bacteria provide a shortcut in the nitrogen removal pathway by directly transforming ammonium and nitrite to nitrogen gas (N₂). Due to its energy efficiency, the anammox-driven treatment has been applied worldwide for the removal of inorganic nitrogen from ammonium-rich wastewater. Although direct evidence of the metabolic production of N₂O by anammox bacteria is lacking, the microorganisms coexisting in anammox-driven WWTPs could produce a considerable amount of N₂O and hence affect the sustainability of wastewater treatment. Thus, N₂O emission is still one of the downsides of anammox-driven wastewater treatment, and efforts are required to understand the mechanisms of N₂O emission from anammox-driven WWTPs using different nitrogen removal strategies and develop effective mitigation strategies. Here, three main N₂O production processes, namely, hydroxylamine oxidation, nitrifier denitrification, and heterotrophic denitrification, and the unique N₂O consumption process termed nosZ-dominated N₂O degradation, occurring in anammox-driven wastewater treatment systems, are summarized and discussed. The key factors influencing N₂O emission and mitigation strategies are discussed in detail, and areas in which further research is urgently required are identified. Full article

The individual application of pure and active compounds such as methionine may help to address water scarcity issues without compromising the yield of wheat. As organic plant growth stimulants, amino acids are popularly used to promote the productivity of crops. However, the influence of the exogenous application of methionine in wheat remains elusive. The present investigation was planned in order to understand the impact of methionine in wheat under drought stress. Two wheat genotypes were allowed to grow with 100% field capacity (FC) up to the three-leaf stage. Twenty-five-day-old seedlings of two wheat genotypes, Galaxy-13 and Johar-16, were subjected to 40% FC, denoted as water deficit-stress (D), along with 100% FC, called control (C), with and without L-methionine (Met; 4 mM) foliar treatment. Water deficit significantly reduced shoot length, shoot fresh and dry weights, seed yield, photosynthetic, gas exchange attributes except for transpiration rate (E), and shoot mineral ions (potassium, calcium, and phosphorus) in both genotypes. A significant increase was recorded in superoxide dismutase (SOD), catalase (CAT), hydrogen peroxide (H₂O₂), malondialdehyde (MDA), and sodium ions (Na⁺) due to water deficiency. However, foliar application of Met substantially improved the studied growth, photosynthetic, and gas exchange attributes with water deficit conditions in both genotypes. The activities of SOD, POD, and CAT were further enhanced under stress with Met application. Met improved potassium (K), calcium (Ca²⁺), and phosphorus (P) content. In a nutshell, the foliar application of Met effectively amended water deficit stress tolerance by reducing MDA and H₂O₂ content under water deficit conditions in wheat plants. Thus, we are able to deduce a positive association between Met-induced improved growth attributes and drought tolerance. Full article

The Tongtian River is the source of the Yangtze River and is a national key ecological reserve in China. Monitoring and predicting the changes and mechanisms of the Tongtian River channel morphology are beneficial to protecting the “Asian Water Tower”. This study aims to quantitatively monitor and predict the accretion and erosion area of the Tongtian River channel morphology during the past 30 years (1990–2020). Firstly, the water bodies of the Tongtian River were extracted and the accretion and erosion areas were quantified using 1108 Landsat images based on the combined method of three water-body indices and a threshold, and the surface-water dataset provided by the European Commission Joint Research Centre. Secondly, an intelligent lightweight neural-network model was constructed to predict and analyze the accretion and erosion area of the Tongtian River. Results indicate that the Tongtian River experienced apparent accretion and erosion with a total area of 98.3 and 94.9 km², respectively, during 1990–2020. The braided (meandering) reaches at the upper (lower) Tongtian River exhibit an overall trend of accretion (erosion). The Tongtian River channel morphology was determined by the synergistic effect of sediment-transport velocity and streamflow. The lightweight neural network well-reproduced the complex nonlinear processes in the river-channel morphology with a final prediction error of 0.0048 km² for the training session and 4.6 km² for the test session. Results in this study provide more effective, reasonable, and scientific decision-making aids for monitoring, protecting, understanding, and mining the evolution characteristics of rivers, especially the complex change processes of braided river channels in alpine regions and developing countries. Full article

Remote sensing and GIS approaches have provided valuable information on modeling water resources, particularly in arid regions. The Sahara of North Africa, which is one of the driest regions on Earth, experienced several pluvial conditions in the past that could have stored significant amounts of groundwater. Thus, harvesting the stored water by revealing the groundwater prospective zones (GWPZs) is highly important to water security and the management of water resources which are necessary for sustainable development in such regions. The Shuttle Radar Topography Mission (SRTM) digital elevation model (DEM), Advanced Land Observing Satellite (ALOS)/Phased Array type L-band Synthetic Aperture Radar (PALSAR), Tropical Rainfall Measuring Mission (TRMM), and Landsat-8 OLI data have all successfully revealed the geologic, geomorphic, climatic, and hydrologic features of Wadi El-Tarfa east of Egypt’s Nile River. The fusion of eleven predictive GIS maps including lithology, radar intensity, lineament density, altitude, slope, depressions, curvature, topographic wetness index (TWI), drainage density, runoff, and rainfall data, after being ranked and normalized through the GIS-based analytic hierarchy process (AHP) and weighted overlay methods, allowed the GWPZs to be demarcated. The resulting GWPZs map was divided into five classes: very high, high, moderate, low, and very low potentiality, which cover about 10.32, 24.98, 30.47, 24.02, and 10.20% of the entire basin area, respectively. Landsat-8 and its derived NDVI that was acquired on 15 March 2014, after the storm of 8–9 March 2014, along with existing well locations validated the GWPZs map. The overall results showed that an integrated approach of multi-criteria through a GIS-based AHP has the capability of modeling groundwater resources in arid regions. Additionally, probing areas of GWPZs is helpful to planners and decision-makers dealing with the development of arid regions. Full article

Sustainability and a circular economy (CE) are crucial for the development of society. The CE approach should start by designing new products or processes or retrofitting existing ones to achieve the best efficiency and extend their life cycle. Designs that enable CE require the guidance of a design theory. Axiomatic design (AD) theory allows for the classification of designs and achieving the targets if appropriate requirements are adopted. This paper aimed to show that sustainability and productivity can be made compatible by ensuring functional independence, as defined in AD and using the circular economy concept. The paper presents how a salt washing machine could be improved concerning its performance. The analysis of the existing design showed fewer design parameters than the functional requirements. A viable enhancement was the addition of one design parameter, which made it possible to control the separation and washing independently. The resulting machine retrofitting increased the production rate by 20% to 30%—the productivity and the quality of the final product was also improved. The washing process now used less water and energy. Moreover, the brine feeding system was also redesigned, so that the brine was now reused, the land use was reduced as was the operating time, and the operators now worked in a more friendly environment. The industrial case study presented in this paper is an example of how innovative engineering design that fits the design science research (DSR) with the generation of knowledge. The objective of this design solution was to increase the efficiency of the entire process and consequently increase the productivity and sustainability. Full article

Salinity is becoming a serious threat to global food security, as it can significantly reduce crop yields and irreversibly damage soil fertility. Moreover, this problem is currently exacerbated by the impact of climate change, especially in drylands. Hence, introducing and adapting salinity-tolerant species, such as quinoa (Chenopodium quinoa, Willd.), could be among the ways to enhance the value of saline land, increasing its productivity and improving small farmers’ income in rural areas. Quinoa, originally cultivated in the Andean region, has gained more attention throughout the Mediterranean region because it yields well even in marginal soils. It is also considered one of the world’s healthiest foods, as its grains contain a balanced composition of minerals, vitamins, dietary fiber, fats, and high-quality, gluten-free proteins, with a balanced profile of all amino acids. In Morocco, quinoa was introduced in 2000, but its expansion is still limited to certain regions. In Eastern Morocco, for the first time, an experiment was carried out in 2019–2020 aiming to assess the response of five quinoa cultivars (INIA-420 Negra, Titicaca, Puno, ICBA-Q4 and ICBA-Q5) to saline irrigation. For this, we used two levels of water irrigation salinity: 1.50 dS.m⁻¹ as a no-salt control from Tagma’s source in Tafoghalt village and 10.5 dS.m⁻¹ as salt treatment from local water drilling. Agronomic parameters, mainly dry matter, leaf area, grain yield and 1000-kernel weight, were measured to assess quinoa cultivars’ responses to saline irrigation. Statistical analysis revealed that all investigated parameters were significantly affected by salinity, quinoa variety and their interaction (p < 0.05). Furthermore, significant differences in terms of salinity tolerance among the five quinoa cultivars were observed, with the highest (2.17 t.ha⁻¹) and lowest (0.33 t.ha⁻¹) yields recorded for ICBA-Q5 and INIA-420 Negra, respectively. However, the same varieties tested previously in Southern Morocco tolerated a higher level of salinity (12 dS.m⁻¹). We assume that other factors interfered with salinity and variety, such as the sowing date, which was relatively late and exposed the flowering and grain filling stages to high heat in May and June. Full article

Precision agriculture is a concept that encompasses various technologies aimed at optimizing the management of agricultural activities. The main aim of this investigation is to evaluate the environmental and economic performance of precision agriculture practices on the production of a stone fruit crop (nectarine) using a life cycle approach and to consider a cradle-to-farm gate scope. The results have been compared against the traditional uniform application (UA). The analysis considers five impact categories, including climate change, photochemical ozone formation, acidification, eutrophication, and water use. The foreground inventory data was provided by a local producer in Southern Spain, and the background information was sourced from commercial Life Cycle Inventory (LCI) databases. The results show that the manufacturing of crop inputs (mainly fertilizers, but also crop management inputs) is responsible for most of the damage generated in all the impact categories, except for water use. The reduced input requirements associated with the application of VA techniques resulted in significantly lower economic costs and environmental savings throughout the life cycle of the production system, which ranged on average between 12–26%. Full article

The advancement of innovative underwater remote sensing detection and imaging methods, such as continuous wave laser line scan or pulsed laser (i.e., LiDAR—Light Detection and Ranging) imaging approaches can provide novel solutions for studying biological substrates and manmade objects/surfaces often encountered in underwater coastal environments. Such instruments can be used shipboard or coupled with proven and available deployment platforms as AUVs (Autonomous Underwater Vehicles). With the right planning, large areas can be surveyed, and more extreme and difficult-to-reach environments can be studied. A prime example, and representing a certain navigational challenge, is the under ice in the Arctic/Antarctic or winter/polar environments or deep underwater survey. Among many marine biological substrates, numerous species of macroalgae can be found worldwide in shallow down to 70+ m (clear water) coastal habitats and are essential ecosystem service providers through the habitat they provide for other species, the potential food resource value, and carbon sink they represent. Similarly, corals also provide important ecosystem services through their structure and diversity, are found to harbor increased local diversity, and are equally valid targets as “keystone” species. Hence, we expand current underwater remote sensing methods to combine macroalgal and coral surveys via the development of a multispectral laser serial imager designed for classification via spectral response. By using multiple continuous wave laser wavelength sources to scan and illuminate recreated benthic environments composed of macroalgae and coral, we show how elastic (i.e., reflectance) and inelastic (i.e., fluorescence) spectral responses can potentially be used to differentiate algal color groups and certain coral genus. Experimentally, three laser diodes (450 nm, 490 nm, 520 nm) are sequentially used in conjunction with up to 5 emission filters (450 nm, 490 nm, 520 nm, 580 nm, 685 nm) to acquire images generated by laser line scan pattern via high-speed galvanometric mirrors. Placed directly adjacent to a large saltwater imaging tank fitted with optical viewports, the optical system records target substrate spectral response using a photomultiplier preceded by a filter and is synchronously digitized to the scan rate by a high sample rate Analog-to-Digital Converter (ADC). Acquired images are normalized to correct for imager optical effects allowing for fluorescence intensity-based pixel segmentation via intensity thresholding. Overall, the multispectral laser serial imaging technique shows that the resulting high resolution data can be used for detection and classification of benthic substrates by their spectral response. These methods highlight a path towards eventual pixel-wise spectral response analysis for spectral differentiation. Full article

Swimming pool owners worldwide face the challenging task of keeping their pool water balanced and free from contaminants. However, swimming pool water (SPW) quality management is complex with the countless processes and interactions of interlinked system variables. For example, contamination with sunscreen residues is inevitable as users apply sunscreen to protect their skin from damaging ultraviolet (UV) radiation. Nanoparticulate titanium dioxide (nano-TiO₂) is one such residues that have received criticism due to potential human health and environmental risks. Despite ongoing research studies, management strategies of nano-TiO₂ in swimming pools are still limited. Therefore, this paper focuses on developing a multi-method approach for identifying and understanding interdependencies between TiO₂ particles and an aquatic environment such as a swimming pool. Given the complexity of the system to be assessed, the authors utilise a systems approach by integrating cross-matrix multiplication (MICMAC) and Systems Thinking techniques. The developed conceptual model visually depicts the complex system, which provides users with a basic understanding of swimming pool chemistry, displaying the numerous cause-and-effect relationships and enabling users to identify leverage points that can effectively change the dynamics of the system. Such systems-level understanding, and actions will help to manage nano-TiO₂ levels in an efficient manner. The novelty of this paper is the proposed methodology, which uses a systems approach to conceptualise the complex interactions of contaminants in swimming pools and important pathways to elevated contaminant levels. Full article

Urban water supply systems (WSS) are complex and challenging to manage since the properties of water in the WSS change from source to the end user over time. However, understanding these changes requires a more profound knowledge of the WSS. This study describes the urban water cycle within the WSS of Ljubljana, Slovenia, where different water parameters such as temperature, electrical conductivity, total alkalinity, δ²H, δ¹⁸O, and δ¹³C_DIC were monitored from September to November 2018. Altogether 108 samples were collected, including from the source (3) and at different levels of the WSS: wells (41), joint exits from water pumping stations (7), reservoirs (22), water treatment locations (2), drinking fountains (13), taps (19) and wastewater system (1). The data show that although the ranges of δ²H and δ¹⁸O values were small, each well is represented by a unique fingerprint when considering additional parameters. A statistically significant difference was observed between sampling months, and temperature and most parameters showed higher variability within the wells than across the WSS, suggesting a more unified WSS. Finally, based on δ¹³C_DIC values, a distinction could be made between river/groundwater interactions within the WSS and between shallower and deeper wells and their distance from the river bank. Full article

The lattice Boltzmann method (LBM) is characterised by its simplicity, parallel processing and easy treatment of boundary conditions. It has become an alternative powerful numerical method in computational physics, playing a more and more important role in solving challenging problems in science and engineering. In particular, the lattice Boltzmann method with the single relaxation time (SLBM) is the simplest and most popular form of the LBM that is used in research and applications. However, there are two long-term unresolved problems that prevent the SLBM from being an automatic simulator for any flows: (1) stability problem associated with the single relaxation time and (2) no method of direct implementation of physical variables as boundary conditions. Recently, the author has proposed the macroscopic lattice Boltzmann method (MacLAB) to solve the Navier–Stokes equations for fluid flows, resolving the aforementioned problems; it is unconditionally stable and uses physical variables as boundary conditions at lower computational cost compared to conventional LBMs. The MacLAB relies on one fundamental parameter of lattice size $\delta x$, and is a minimal version of the lattice Boltzmann method. In this paper, the idea of the MacLAB is further developed to formulate a macroscopic lattice Boltzmann method for shallow water equations (MacLABSWE). It inherits all the advantages from both the MacLAB and the conventional LBM. The MacLABSWE is developed regardless of the single relaxation time $\tau$. Physical variables such as water depth and velocity can directly be used as boundary conditions, retaining their initial values for Dirichlet’s boundary conditions without updating them at each time step. This makes not only the model to achieve the exact no-slip boundary condition but also the model’s efficiency superior to the most efficient bounce-back scheme for approximate no-slip boundary condition in the LBMs, although the scheme can similarly be implemented in the proposed model when it is necessary. The MacLABSWE is applied to simulate a 1D unsteady tidal flow, a 2D steady wind-driven flow in a dish-shaped lake and a 2D steady complex flow over a bump. The results are compared with available analytical solutions and other numerical studies, demonstrating the potential and accuracy of the model. Full article

Ecological pattern evolution of Poyang Lake wetland, the largest freshwater lake in China, is critical for regional ecological protection and sustainable development of migratory bird habitats; however, this information is still not fully explored. In this study, we quantitatively reconstructed the spatial distribution and landscape ecological pattern of Poyang Lake wetlands in three periods in the past 100 years based on the military topographic map in the 1930s and the Landsat satellite remote sensing image data in 1979 and 2021. Further, use the Fragstats software to analyze the ecological pattern index of wetland reconstruction results. The results show that the wetland area in the Poyang Lake region has experienced a continuous reduction process over the past 100 years, and it decreased from 3857 km² in the 1930s to 3673 km² in the 1970s, and then to 3624 km² in the 2020s. The current wetland area has decreased by about 6.04% compared with the 1930s. The general trend of changes in the spatial pattern of Poyang Lake wetlands is that the surface water decreases and the open land increases. Nevertheless, the trend has certain spatial differences as a large area of wetlands disappeared in the southwest and west of Poyang Lake and the areas with enlarged wetland density values mainly appeared in the northeastern and northern parts of the study area. The NP (number of patches) in the wetlands of Poyang Lake over the past 100 years showed a downward trend during the 1930s–1970s, and an increasing trend during the 1970s–2010s. Due to the increases of constructed wetlands, the number and density of patches also increased, and PD (patch density) reached a maximum value of 0.142 in 2020s. The LPI (largest patch index) has shown a gradual downward trend in the past 100 years. Compared with the 1930s, the wetlands in 2020s dropped by about 26.64%, and the wetlands further showed a trend of fragmentation. The AI index, which indicates the concentration of wetland patches, reached the maximum value in 2020s, but the LSI (landscape shape index) showed a downward trend in general, indicating that the shape of wetland patches has been simplified over the past 100 years. The research results can provide basic data and decision-making basis for Poyang Lake wetland protection, construction of migratory bird reserve and regional sustainable development. Full article

In this study, initially 11 different bacterial strains were tested for the degradation capabilities against Basic Orange 2 dye. In initial screening with 78.90% degradation activity, Escherichia coli emerged as the most promising strain to degrade the selected dye, and was then employed in subsequent experiments. For further enhancing the degradation capability of selected bacteria, the effects of various physicochemical parameters were also evaluated. Among the tested parameters, 20 ppm dye concentration, 1666 mg/L glucose concentration, a temperature of 40 °C, 666 mg/L sodium chloride concentration, pH 7, 1000 mg/L urea concentration, a 3-day incubation period and the use of sodium benzoate as a redox mediator (666 mg/L) were found to be ideal conditions to get the highest decolorization/degradation activities. Finally, all the mentioned parameters were combined in a single set of experiments, and the decolorization capacity of the bacteria was enhanced to 89.88%. The effect of pH, dye concentration, incubation time and temperature were found to be responsible for the optimum degradation of dye (p < 0.05), as predicted from the ANOVA (analysis of variance) of the response surface methodology. The metabolites were collected after completion of the process and characterized through Fourier transform irradiation (FTIR) and gas chromatography mass spectrometry (GC-MS). From the data obtained, a proposed mechanism was deduced where it was assumed that the azo bond of the dye was broken by the azoreductase enzyme of the bacteria, resulting in the formation of aniline and 3, 4-diaminobezeminium chloride. The aniline was then further converted to benzene by deamination by the action of the bacterial deaminase enzyme. The benzene ring, after subsequent methylation, was transformed into o-xylene, while 3, 4-diaminobezeminium chloride was converted to p-xylene by enzymatic action. These findings suggest that Escherichia coli is a capable strain to be used in the bioremediation of textile effluents containing azo dyes. However, the selected bacterial strain may need to be further investigated for other dyes as well. Full article

This 2-year field study analyzed plastic film mulching (PFM) effects on nitrogen use efficiency (NUE), and soil N pools under rainfed dryland conditions. Compared to no-mulching (NM, control), maize yields under PFM were increased by 36.3% (2515.7 kg ha⁻¹) and 23.9% (1656.1 kg ha⁻¹) in the 2020 and 2021 growing seasons, respectively. The PFM improved (p < 0.01) the water use efficiency (WUE) of maize by 39.6% and 33.8% in the 2020 and 2021 growing seasons, respectively. The 2-year average NUE of maize under the PFM was 40.1, which was 30.1% greater than the NM. The average soil total N, particulate organic N, and microbial biomass N contents under the PFM soil profile were increased by 22.3%, 51.9%, and 35%, respectively, over the two growing seasons. The residual ¹⁵N content (%TN) in soil total N pool was significantly higher (p < 0.05) under the PFM treatment. Our results suggest that PFM could increase maize productivity and sustainability of rainfed dryland faming systems by improving WUE, NUE, and soil N pools. Full article

Productive water use can be an effective adaptation strategy for improving crop performance. A 2-year field study was undertaken in 2018 and 2019 to investigate the effect of sowing date and genotype on water-use efficiency of lentils grown in diverse locations in Australia. Above-ground dry matter accumulation, grain yield, soil evaporation, water use, and water-use efficiency (WUE) were measured and/or calculated at crop maturity. Early sowing (SD1/mid-April), late maturity and supplementary irrigation increased water use. The long growth cycle resulting from early sowing influenced WUE for dry matter production and grain yield. WUE ranged from 10.5 to 18.8 kg dry matter ha⁻¹ mm⁻¹ (WUE_ET (evapotranspiration)) and 17.1 to 28.3 kg dry matter ha⁻¹ mm⁻¹ (WUE_T (transpiration)) for dry matter production. For grain yield, WUE ranged from 2.11 to 5.65 kg grain ha⁻¹ mm⁻¹ (WUE_ET) and 4.71 to 9.19 kg grain ha⁻¹ mm⁻¹ (WUE_T). There was more water loss through soil evaporation in SD1 compared to the other sowing dates. Excessive or limited availability of water did not translate to more dry matter accumulation and grain yield. The study concluded that SD1 gives the maximum water productivity for biomass, and SD2 (end of April) and SD3 (mid-May) for grain yield. Full article

Evaluating the performance of AquaCrop models under the drip irrigation of maize with soil conditioners is of great significance for improving coastal saline–alkali land crop management strategies. This study aimed to evaluate the performance of an AquaCrop model for maize growth simulation under different soil conditions (humic acid (HA) and sodium carboxymethyl cellulose (CMC)) and dosages and different levels of irrigation in the Shandong coastal saline–alkali area, China, and to optimize the amount of irrigation. Three years of experiments were carried out in the growing season of maize (Ludan 510) in 2019, 2020, and 2021. The dosages of HA were 5, 15, 25, and 35 g/m², the dosages of CMC were 1, 2, 3, and 5 g/m², and the levels of irrigation from 2019 to 2021 were all 120 mm. The model was calibrated with data from 2019, and the model was verified with data from 2020 to 2021, according to the recommended corn parameters in the AquaCrop model manual. The results showed that the model had a good simulation effect on canopy coverage, with a root-mean-square error (RMSE) of less than 15.2%, and the simulated aboveground biomass and yield were generally low. The simulated value of soil water content was generally high, with some treatments having errors of more than 15.0%. The simulation effect of irrigated maize from 2019 to 2020 was better than maize in 2021. The simulation effect of HA was better than that of CMC, while the simulation effect of a low-gradient modifier was better than that of high-gradient conditioner when compared with CMC. In conclusion, the AquaCrop model could be a viable method for predicting maize development under different soil conditioners in this area. The suitable levels of irrigation under HA and CMC treatments were 47.0–65.9 mm and 61.0–92.4 mm, respectively, according to the principle of high yield and water use efficiency. The results provided a reference for optimizing the drip irrigation of maize under the application of soil conditioners in coastal saline–alkali areas. Full article

Obesity may cause metabolic syndrome and has become a global public health problem, and dietary fibers (DF) could alleviate obesity and metabolic syndrome by regulating intestinal microbiota. We developed a functional fiber (FF) with a synthetic mixture of polysaccharides, high viscosity, water-binding capacity, swelling capacity, and fermentability. This study aimed to investigate the effect of FF on obesity and to determine its prevention of obesity by modulating the gut microbiota. Physiological, histological, and biochemical parameters, and gut microbiota composition were investigated in the following six groups: control group (Con), high-fat diet group (HFD), low-fat diet group (LFD, conversion of HFD to LFD), high-fat +8% FF group (8% FF), high-fat +12% FF group (12% FF), and high-fat +12% FF + antibiotic group (12% FF + AB). The results demonstrated that 12% FF could promote a reduction in body weight and epididymal adipocyte area, augment insulin sensitivity, and stimulate heat production from brown adipose tissue (BAT) (p < 0.05). Compared with the HFD, 12% FF could also significantly improve the intestinal morphological integrity, attenuate systemic inflammation, promote intestinal microbiota homeostasis, and stabilize the production of short-chain fatty acids (SCFAs) (p < 0.05). Consistent with the results of 12% FF, the LFD could significantly reduce the body weight and epididymal adipocyte area relative to the HFD (p < 0.05), but the LFD and HFD showed no significant difference (p > 0.05) in the level of inflammation and SCFAs. Meanwhile, 12% FF supplementation showed an increase (p < 0.05) in the abundance of the Bifidobacterium, Lactococcus, and Coprococcus genus in the intestine, which had a negative correlation with obesity and insulin resistance. Additionally, the treatment with antibiotics (12% FF + AB) could inhibit the effect of FF in the HFD. The Kyoto Encyclopedia of Genes and Genomes (KEGG) function prediction revealed that 12% FF could significantly inhibit the cyanogenic amino acid metabolic pathway and decrease the serum succinate concentration relative to the HFD group. The overall results indicate that 12% FF has the potential to reduce obesity through the beneficial regulation of the gut microbiota and metabolites. Full article

Multi-date remotely sensed SPOT images of 1991, 2000, 2009 and 2017 were used to reconstruct changes in land cover in the Gamtoos River Estuary, Eastern Cape province, South Africa. These images were complemented by near-anniversary aerial photographs and Google Earth images that were used as ancillary sources of ground truth. The long-term trend direction of change was determined by calculating percentage changes and performing linear trend analysis. The magnitude of change was established by calculating Sen Slope estimates (SSE) and the influence of climate change on changes in land cover tested by correlating changes in rainfall and different cover types. The greatest and lowest changes were for noncultivated land and surface water (−7.94%, y = −1.2032x + 21.275, SSE = −0.292, and 0.44%, y = −0.4261x + 9.657, SSE = 0.007, respectively). Correlations between rainfall and all cover types were weak and ranged between 0.453816 and −0.643962. Rainfall exhibited a significant decrease (p = 0.0411, σ 0.05; y = −7.175x + 734.55, SSE = −11.130) that was highly correlated with changes in surface water distribution (0.813709, Critical R = 0.805). Overall, the results of this investigation point to the combined influence of climate change and human agency, with the latter tending to play a more prominent role by exerting increasing pressure on the environment’s natural supporting potentials. We therefore urge the scientific community to continue exploring actionable interventions that can be used to enhance the sustainability of this ecosystem and others elsewhere. Full article

In large projects such as dams, embankments, and seawalls, it is sometimes important to determine the compressive properties of a mixture containing soil and gravel with particle sizes exceeding 75 mm. The Saemangeum Renewable Energy Vision Proclamation Ceremony, held in October 2018 in Korea, confirmed and promulgated the plan to build a total of 4.0 GW of renewable energy power generation complex in the Saemangeum area. The project will be carried out on an area of 31.95 km², and a 1.0 GW offshore wind power development plan is in progress. Since most of the Saemangeum area has a soft ground layer that has been reclaimed, a key research institute is absolutely necessary to lead in the stabilization of the supporting structures for power generation facilities and to achieve the renewable energy 3020 policy in extreme environments. Hence, it is meaningful to investigate the effect of gravel content (P) on the ground strength characteristics. However, such investigation cannot be routinely performed due to the limited size of the equipment available. Several equations have been proposed in the literature to modify the compaction properties of gravel-mixed soils containing coarse aggregates. Among these is the proposed equation by Walker and Holtz, which has widely been used. However, the use of this equation in the case of high gravel content is not appropriate because the physical meaning of this equation is not clear and does not apply to materials with gravel content exceeding 40%. Therefore, a better quantitative evaluation method in determining material characteristics according to gravel content must be established through laboratory tests on samples of acceptable particle size for the experimental equipment. To obtain the compressive properties of decomposed granite soil (D-G-S), in this study, the results from large-scale one-dimensional compression tests on samples compacted at various gravel concentrations, constant compaction energy, and constant water content were analyzed. To quantitatively evaluate the properties of D-G-S according to the gravel content, a modified formula based on the two-phase mixing theory was utilized. It was shown that the degree of mixing between the gravel and sand for the conditions of D-G-S used in the experiments was high, at 0.85. To estimate the compression curves of D-G-S at various gravel content, the compression curves of purely sand (P = 0%) and purely gravel (P = 100%) materials, and the value of R_m = 0.85 were utilized, and it was shown that the compression index and swelling index curves estimated using the method presented in this study were in good agreement with the experimental results. To confirm the engineering applicability of the presented method, finite element analysis was performed, and as a result, it was revealed that it can be sufficiently applied in the simulation of embankment settlement. In order to obtain more reliable results in the future, verification using various samples is required. Full article

Advanced maternal age (≥35 years) increases the risk of vascular complications in pregnancy that can result in fetal growth restriction and preeclampsia. Endoplasmic reticulum (ER) stress has been linked to adverse pregnancy outcomes in these complicated pregnancies. However, the role of ER stress in advanced maternal age is not known. We hypothesize that increased ER stress contributes to altered vascular function and poor pregnancy outcomes, and that treatment with the ER-stress inhibitor TUDCA will improve pregnancy outcomes. First, young and aged non-pregnant/pregnant rats were used to assess ER stress markers in mesenteric arteries; mesenteric artery phospho-eIF2α and CHOP expression were increased in aged dams compared to young dams. In a second study, young and aged control and TUDCA-treated dams were studied on gestational day (GD) 20 (term = 22 days). TUDCA treatment was provided via the drinking water throughout pregnancy (GD0-GD20; calculated dose of 150 mg/kg/day TUDCA). ER stress markers were quantified in mesenteric arteries, blood pressure was measured, pregnancy outcomes were recorded, mesenteric and main uterine arteries were isolated and vascular function was assessed by wire myography. Aged dams had increased phospho-eIF2α and CHOP expression, reduced fetal weight, reduced litter size, and impaired uterine artery relaxation. In the aged dams, TUDCA treatment reduced phospho-eIF2α and CHOP expression, reduced blood pressure, improved fetal body weight, and tended to improve uterine artery function compared to control-treated aged dams. In conclusion, our data illustrate the role of ER stress, as well as TUDCA as a potential therapeutic that may benefit pregnancy outcomes in advanced maternal age. Full article

Climate change is currently one of agriculture’s main problems in achieving sustainability. It causes drought, increased rainfall, and increased diseases, causing a decrease in food production. In order to combat these problems, Agricultural Big Data contributes with tools that improve the understanding of complex, multivariate, and unpredictable agricultural ecosystems through the collection, storage, processing, and analysis of vast amounts of data from diverse heterogeneous sources. This research aims to discuss the advancement of technologies used in Agricultural Big Data architectures in the context of climate change. The study aims to highlight the tools used to process, analyze, and visualize the data, to discuss the use of the architectures in crop, water, climate, and soil management, and especially to analyze the context, whether it is in Resilience Mitigation or Adaptation. The PRISMA protocol guided the study, finding 33 relevant papers. However, despite advances in this line of research, few papers were found that mention architecture components, in addition to a lack of standards and the use of reference architectures that allow the proper development of Agricultural Big Data in the context of climate change. Full article

Warmer temperatures and frequent drought directly affect urban tree health. Both abiotic conditions also affect tree health via increased density of some insect pests. Warming is predicted to benefit urban trees by increasing carbon sequestration and allocation to biomass. However, increased drought and pests are rarely considered despite often co-occurring with heat. To determine the combined effects of these abiotic and biotic factors, we manipulated water availability for established urban red maple trees across a gradient of warming and pest density and measured leaf-level processes and tree growth over two years. We find that water availability is a major determinant of tree growth, physiological processes, and resilience to urban stress factors. Maples performed better with more water, which also made them resistant to effects of temperature and pest density. However, when drought became too severe, leaf-level processes declined with warming. Tree basal area growth was unaffected after two years, but stem elongation increased with increasing water, temperature, and pest density. We discuss potential mechanisms driving these responses and the implications in the context of urban forest management. Urban forest designs that reduce drought and align species adaptations to local conditions are critical for designing more resilient and productive urban forests. Full article

Oxygen and hydrogen generated by water electrolysis may be utilized as a clean chemical fuel with high gravimetric energy density and energy conversion efficiency. The hydrogen fuel will be the alternative to traditional fossil fuels in the future, which are near to exhaustion and cause pollution. In the present study, flowery-shaped In₂MnSe₄ nanoelectrocatalyst is fabricated by anion exchange reaction directly grown on nickel foam (NF) in 1.0 M KOH medium for oxygen evolution reaction (OER). The physiochemical and electrical characterization techniques are used to investigate the chemical structure, morphology, and electrical properties of the In₂MnSe₄ material. The electrochemical result indicates that synthesized material exhibits a smaller value of Tafel slope (86 mV/dec), lower overpotential (259 mV), and high stability for 37 h with small deterioration in the current density for a long time. Hence, the fabricated material responds with an extraordinary performance for the OER process and for many other applications in the future. Full article

Since 1974, more than 800 disinfection byproducts (DBPs) have been identified from disinfected drinking water, swimming pool water, wastewaters, etc. Some DBPs are recognized as contaminants of high environmental concern because they may induce many detrimental health (e.g., cancer, cytotoxicity, and genotoxicity) and/or ecological (e.g., acute toxicity and development toxicity on alga, crustacean, and fish) effects. However, the information on whether DBPs may elicit potential endocrine-disrupting effects in human and wildlife is scarce. It is the major objective of this paper to summarize the reported potential endocrine-disrupting effects of the identified DBPs in the view of adverse outcome pathways (AOPs). In this regard, we introduce the potential molecular initiating events (MIEs), key events (KEs), and adverse outcomes (AOs) associated with exposure to specific DBPs. The present evidence indicates that the endocrine system of organism can be perturbed by certain DBPs through some MIEs, including hormone receptor-mediated mechanisms and non-receptor-mediated mechanisms (e.g., hormone transport protein). Lastly, the gaps in our knowledge of the endocrine-disrupting effects of DBPs are highlighted, and critical directions for future studies are proposed. Full article

Appropriate irrigation and nitrogen (N) management strategies are necessary to achieve a sustainable yield of maize with relatively low water and N inputs. Here, a 2-year field experiment with two irrigation methods (drip irrigation and flood irrigation) and five N application rates (0, 225, 300, 375, and 450 kg N ha⁻¹) was conducted to evaluate maize yield and water and N use efficiency in the North China Plain (NCP). Compared with flood fertigation (FF), drip fertigation (DF) improved the soil water content (SWC) in the 0 to 40 cm soil layer and maintained a greater soil mineral N content (N_min) of that soil layer. This resulted in increased soil N_min in the 0 to 40 cm soil layer for the 375 kg ha⁻¹ (N3) under DF compared with the 450 kg N ha⁻¹ (N4) treatment under FF during both pre- and post-silking of maize. The maize crop accumulated greater N at both pre- and post-silking compared using N3 under DF compared to N4 under FF. Greater pre-silking N accumulation increased both leaf area and plant growth rate, leading to more dry matter (DM) accumulation and develop more kernels, while sufficient post-silking N accumulation maintained high leaf area to produce more DM post-silking and promote maize ability to support grain filling. As a result, maximum maize yield (10.4 Mg ha⁻¹) was achieved due to increased kernel number and kernel weight for N3 (375 kg N ha⁻¹) under DF with a 20% reduction in N fertilizer input compared with the N4 (450 kg N ha⁻¹) treatment under FF. Due to greater grain yield and N uptake and less water consumption, the agronomic N efficiency (AE_N), N partial factor productivity (PFP_N), water use efficiency (WUE) and net income for the N3 treatment under DF increased by 30.4%, 28.6%, 58.3% and 11.0% averaged over two years, respectively, compared to the N4 treatment under FF. Therefore, drip fertilization could improve maize grain yield with a relatively lower water consumption and N application rate compared with flood irrigation with higher N fertilization, as well as increase the economic benefits. Full article

The aim of this study was to investigate covalent immobilization of horseradish peroxidase (HRP) on magnetic nanoparticles (Mag) encapsulated in calcium alginate beads (MABs) for color degradation, combining easy and fast removal of biocatalyst from the reaction mixture due to its magnetic properties and strong binding due to surface alginate functional groups. MABs obtained by extrusion techniques were analyzed by optical microscopy, FEG-SEM and characterized regarding mechanical properties, magnetization and HRP binding. HRP with initial concentration of 10 mg/g_carrier was successfully covalently bonded on MABs (diameter ~1 mm, magnetite/alginate ratio 1:4), with protein loading of 8.9 mg/g_carrier, immobilization yield 96.9% and activity 32.8 U/g. Immobilized HRP on MABs (HRP-MABs) was then used to catalyze degradation of two anthraquinonic dyes, Acid Blue 225 (AB225) and Acid Violet 109 (AV109), as models for wastewater pollutants. HRP-MABs decolorized 77.3% and 76.1% of AV109 and AB225, respectively after 15 min under optimal conditions (0.097 mM H₂O₂, 200 mg of HRP-MABs (8.9 mg/g_carrier), 0.08 and 0.1 g/mg beads/dye ratio for AV109 and AB225, respectively). Biocatalyst was used for 7 repeated cycles retaining 75% and 51% of initial activity for AB225 and AV109, respectively, showing potential for use in large scale applications for colored wastewater treatment. Full article

Wound healing is a complex biological phenomenon, having different but overlapping stages to obtained complete re-epithelization. The aim of the current study was to develop a dendrimer-based hydrogel bandage, to ameliorate full-thickness wounds. Hesperidin, a bioflavonoid found in vegetables and citrus fruits, is used for treatment of wounds; however, its therapeutic use is limited, due to poor water solubility and poor bioavailability. This issue was overcome by incorporating hesperidin in the inner core of a dendrimer. Hence, a dendrimer-based hydrogel bandage was prepared, and the wound healing activity was determined. A hemolysis study indicated that the hesperidin-loaded dendrimer was biocompatible and can be used for wound healing. The therapeutic efficacy of the prepared formulation was evaluated on a full-thickness wound, using an animal model. H&E staining of the control group showed degenerated neutrophils and eosinophils, while 10% of the formulation showed wound closure, formation of the epidermal layer, and remodeling. The MT staining of the 10% formulation showed better collagen synthesis compared to the control group. In vivo results showed that the preparation had better wound contraction activity compared to the control group; after 14 days, the control group had 79 ± 1.41, while the 10% of formulation had 98.9 ± 0.42. In a nutshell, Hsp-P-Hyd 10% showed the best overall performance in amelioration of full-thickness wounds. Full article

The distribution of water resources is usually characterized by spatial heterogeneity, resulting in different water supply and demand pressures within the basin. Therefore, the analysis of water resources supply and demand balance and the mapping of water resources spatial flow can be an effective suggestion for the regional water resources allocation to relieve the regional water pressure. The uneven distribution of water resources in the Dongjiang River Basin is significant, and how to effectively allocate water resources in the Dongjiang River Basin has become a major focus of research. Based on the multi-source data of the Dongjiang River Basin from 2005 to 2020, this paper uses the SWAT model and water demand model to establish the spatial flow model of water resources supply and demand, and uses the subbasin-scale to explore the spatial distribution and flow of water resources supply and demand, obtaining the spatial scope and flow of water resources supply and beneficiary areas in the basin. The results show that (1) the water supply in the Dongjiang River Basin has been decreasing year by year, and the water demand has been increasing from 2005 to 2015, leading to an increase in the imbalance between supply and demand, and there is a significant reduction in industrial water use from 2015 to 2020, resulting in a reduction in the imbalance between water supply and demand; (2) the supply and demand pressure of water resources in the Dongjiang River Basin has obvious spatial heterogeneity, showing that the pressure of water use in the middle and upper reaches is small, while the pressure of water use in the lower reaches is large; (3) under the framework of spatial service flows of water resources supply and demand, this paper obtains three main beneficiary area ranges, which are Dongyuan County of Heyuan City, Yuancheng District of Heyuan City, and the main urban area of Shenzhen Dongguan Huizhou, and specifies the flow of service flows. This study can not only provide reasonable suggestions for water resources allocation in the Dongjiang River Basin but it also provides references for water resources management in other basins. Full article

An increasing frequency of extreme atmospheric events is challenging our basic knowledge about the resilience mechanisms that mediate the response of small mountainous watersheds (SMW) to landslides, including production of water-derived ecosystem services (WES). We hypothesized that the demand for WES increases the connectivity between lowland and upland regions, and decreases the heterogeneity of SMW. Focusing on four watersheds in the Central Andes of Colombia and combining “site-specific knowledge”, historic land cover maps (1970s and 1980s), and open, analysis-ready remotely sensed data (GLAD Landsat ARD; 1990–2000), we addressed three questions. Over roughly 120 years, the site-specific data revealed an increasing demand for diverse WES, as well as variation among the watersheds in the supply of WES. At watershed-scales, variation in the water balances—a surrogate for water-derived ES flows—exhibited complex relationships with forest cover. Fractional forest cover (p_i) and forest aggregation (AI_i) varied between the historic and current data sets, but in general showed non-linear relationships with elevation and slope. In the current data set (1990–2000), differences in the number of significant, linear models explaining variation in p_i with time, suggest that slope may play a more important role than elevation in land cover change. We found ample evidence for a combined effect of slope and elevation on the two land cover metrics, which would be consistent with strategies directed to mitigate site-specific landslide-associated risks. Overall, our work shows strong feedbacks between lowland and upland areas, raising questions about the sustainable production of WES. Full article

Chemical crop protection agents are widely applied in modern agricultural practice. As a result of surface runoff, these insecticides penetrate into rivers, ponds, and lakes, where they become a serious threat to aquatic organisms. The aim of the study was to determine the toxicity of increasing concentrations of the insecticide Decis^® 2.5 EC to Daphnia magna and Heterocypris incongruens, which are components of freshwater zooplankton. The observed effect was immobilization of organisms, which were not able to swim after gentle agitation of the liquid for 15 sec. It was found that up to 135 min, increasing Decis^® 2.5 EC concentrations inhibited the swimming of tested organisms. Initially, up to 135 min, Heterocypris incongruens was more sensitive to the tested insecticide. After 135 min of the experiment, ostracods acclimatized to the tested xenobiotic. However, after 360 min, the immobilization of organisms increased proportionally to the concentrations of Decis^® 2.5 EC. The most toxic concentrations were 15 × 10⁻³% and 30 × 10⁻³%. The lowest observed effect concentration of Decis^® 2.5 EC that reduced the swimming of daphnia and ostracod by more than 20% was >0.91 × 10⁻³% (0.23 mg L⁻¹ of deltamethrin). This experiment demonstrated that Daphnia magna and Heterocypris incongruens are good bioindicators of freshwaters polluted with Decis^® 2.5 EC. Full article

Heavy metal contamination in coastal waters may pose a serious threat to aquatic products and human health. This study aimed to gain a better understanding of the pollution-induced by heavy metals in Haikou Bay and adjacent seas and assessed the potential ecological risk. The spatial distributions of heavy metals including Cu, Pb, Zn, Cd, Cr, Hg, and As were analyzed in the surface and bottom water, surface sediment, and five species of fish collected from Haikou Bay and adjacent seas. For seawater, the results showed that the horizontal distribution of the seven heavy metal elements in the study area had no uniform pattern due to the influence of complex factors, such as land-based runoff, port shipping, and ocean current movement. In contrast, the vertical distribution of these heavy metal elements, except for Zn and Cd, showed high concentrations in the surface water and low concentrations in the bottom water. Due to the symbiotic relationship between Zn and Cd, the distributions of these two elements were similar in the study areas. Different from the complex distribution of heavy metals in water, the highest concentrations of these elements in surface sediment all occurred at station 11 except for Pb. Our study revealed that organic carbon and sulfide are important factors affecting the heavy metal concentrations in the surface sediments. Heavy metals in waters and surface sediment were lower than the quality standard of class I according to the China National Standard for Seawater Quality and the sediment quality, except for Zn in water, suggesting that the seawater and surface sediment in Haikou Bay and adjacent seas has not been polluted by heavy metals. Additionally, the heavy metal As was the main element affecting the quality of fish in this study area, and attention should be paid in the future. The target hazard quotient (THQ) values of seven heavy metal elements in fish were all lower than 1.0, indicating that eating fish in this area will not pose a risk to human health. These results provide valuable information for further understanding the status of heavy metal pollution in Haikou Bay and adjacent seas and the development of targeted conversation measures for the environment and fish consumers. Full article

Climate change and human activities have been heavily affecting oceanic and inland waters, and it is critical to have a comprehensive understanding of the aquatic optical properties of lakes. Since many key watercolor parameters of Qinghai Lake are not yet available, this paper aims to study the spatial and temporal variations of the water clarity (i.e., Secchi-disk depth, $Z_{\mathrm{SD}}$) and suspended particulate matter concentration ($C_{\mathrm{SPM}}$) in Qinghai Lake from 2001 to 2020 using MODIS images. First, the four atmospheric correction models, including the NIR–SWIR, MUMM, POLYMER, and C2RCC were tested. The NIR–SWIR with decent accuracy in all bands was chosen for the experiment. Then, four existing models for $Z_{\mathrm{SD}}$ and six models for $C_{\mathrm{SPM}}$ were evaluated. Two semi-analytical models proposed by Lee (2015) and Jiang (2021) were selected for $Z_{\mathrm{SD}}$ ($R^2$ = 0.74) and $C_{\mathrm{SPM}}$ ($R^2$ = 0.73), respectively. Finally, the distribution and variation of the $Z_{\mathrm{SD}}$ and $C_{\mathrm{SPM}}$ were derived over the past 20 years. Overall, the water of Qinghai Lake is quite clear: the monthly mean $Z_{\mathrm{SD}}$ is 5.34 ± 1.33 m, and $C_{\mathrm{SPM}}$ is 2.05 ± 1.22 mg/L. Further analytical results reveal that the $Z_{\mathrm{SD}}$ and $C_{\mathrm{SPM}}$ are highly correlated, and the relationship can be formulated with $Z_{\mathrm{SD}}=8.072e^{-0.212C_{\mathrm{SPM}}}$ ($R^2$ = 0.65). Moreover, turbid water mainly exists along the edge of Qinghai Lake, especially on the northwestern and northeastern shores. The variation in the lakeshore exhibits some irregularity, while the main area of the lake experiences mild water quality deterioration. Statistically, 81.67% of the total area is dominated by constantly increased $C_{\mathrm{SPM}}$, and the area with decreased $C_{\mathrm{SPM}}$ occupies 4.56%. There has been distinct seasonal water quality deterioration in the non-frozen period (from May to October). The water quality broadly deteriorated from 2001 to 2008. The year 2008 witnessed a sudden distinct improvement, and after that, the water quality experienced an extremely inconspicuous degradation. This study can fill the gap regarding the long-time monitoring of water clarity and total suspended matter in Qinghai Lake and is expected to provide a scientific reference for the protection and management of the lake. Full article

Hyperuricemia (HUA) is a metabolic disease that threatens human health. Tea is a healthy beverage with an abundance of benefits. This study revealed the uric acid-lowering efficacy of six types of tea water extracts (TWEs) on HUA in mice. The results revealed that under the intervention of TWEs, the expression of XDH, a key enzyme that produces uric acid, was significantly downregulated in the liver. TWE treatment significantly upregulated the expression of uric acid secretion transporters ABCG2, OAT1, and OAT3, and downregulated the expression of uric acid reabsorption transporter URAT1 in the kidney. Furthermore, HUA-induced oxidative stress could be alleviated by upregulating the Nrf2/HO-1 pathway. The intervention of TWEs also significantly upregulated the expression of the intestinal ABCG2 protein. On the other hand, TWE intervention could significantly upregulate the expression of intestinal ABCG2 and alleviate HUA by modulating the gut microbiota. Taken together, tea can comprehensively regulate uric acid metabolism in HUA mice. Interestingly, we found that the degree of fermentation of tea was negatively correlated with the uric acid-lowering effect. The current study indicated that tea consumption may have a mitigating effect on the HUA population and provided a basis for further research on the efficacy of tea on the dosage and mechanism of uric acid-lowering effects in humans. Full article

The relationships between environmental factors and fish density are closely related, and species distribution models (SDMs) have been widely used in exploring these relationships and predicting the spatial distribution of fishery resources. When exploring the prediction of the spatial distribution of species in different seasons, the method of choosing the appropriate approach to the season will help to improve the predictive performance of the model. Based on data collected from 2015 to 2020 during a survey off southern Zhejiang, the Tweedie-GAM was used to establish the relationship between the density of Decapterus maruadsi and environmental factors at different modeling approaches. The results showed that water temperature, salinity and depth were the main factors influencing D. maruadsi, and they operated through different mechanisms and even resulted in opposite trends of density in different seasons. Spatially, the two modeling approaches also differed in predicting the spatial distribution of D. maruadsi, with the seasonal model showing a higher density trend in inshore waters than in offshore waters in spring but showing the opposite trend in summer and autumn, which was more consistent with the actual spatial distribution of the resource. By analyzing the effects of two different approaches on the prediction of fishery resources, this study aims to provide research ideas and references for improving the predictive performance of SDMs. Full article

This study explored the application of whole and defatted Moringa oleifera seed-derived coagulants in powder (P-MOS and DP-MOS), aqueous extraction (AEP-MOS and AEDP-MOS), and saline extraction (SEP-MOS and SEDP-MOS) in the treatment of a synthetic turbid water by coagulation, flocculation, and sedimentation in a jar test apparatus. The performance of M. oleifera seed-derived coagulants was quantified and compared with alum in terms of the ability to neutralize and restabilize the suspension charge, turbidity removal, effect on pH and electrical conductivity, residual organic matter, as well as cytotoxicity in the treated water. All evaluated forms of M. oleifera seed-derived coagulants were able to neutralize and restabilize (in overdose) the particles charges in the suspension. Saline extractions obtained the best turbidity removal results (90%) between the M. oleifera seed-derived coagulants, while alum removed 98% of turbidity. Differently from alum, increased dosage of M. oleifera seed-derived coagulants did not change pH value. Saline extractions and, to a lesser extent, alum increased the electrical conductivity with increasing coagulant dosage. M. oleifera seed-derived coagulants increased residual organic matter (DOC), unlike alum, which did not change this property with increasing dosage. Saline extractions at high dosages enhanced the cytotoxicity to mammalian cells. On the other hand, defatted seeds reduced water cytotoxicity when compared to whole seeds. Despite not being able to reduce the residual organic matter, the previous oil extraction proved to be an important step in the processing of M. oleifera seed-derived coagulants, not changing the turbidity removal capacity and reducing the cytotoxicity of the treated water in addition to generating a significant by-product (Ben oil). Although saline extractions have shown the best turbidity removal results, they should be used with caution due to increased electrical conductivity and cytotoxicity of the treated water at high dosages. Full article

In slab continuous-casting machines, the quality of the finished product mainly depends on the hydrodynamic behavior of the molten steel in the cavity of the continuous-casting mold, where the submerged entry nozzle is the central element. Recently, a nontraditional nozzle design was reported, where a solid barrier attached to the inner bottom wall of the nozzle divides its internal volume, particularly around the outlet ports. The solid barrier was named a flow divider. In this work, the effect of the flow divider is analyzed by comparing the performance of traditional nozzles with the performance of nozzles altered with the flow divider. The performance of the nozzles was evaluated experimentally, employing a scaled model of the mold section, using cold water as the working fluid. The shape of the nozzle outlet jets and the fluid flow pattern in the mold cavity were used to determine the performance of the nozzles. In addition, several factors affecting the process stability and the quality of the product were analyzed: the casting speed, the tilt of the nozzle outlet ports, and the injection of gas in the liquid stream entering the nozzle. The analysis showed that for the nozzles with the flow divider, (i) the outlet jets are narrow and symmetric, (ii) the symmetrical double-roll flow pattern in the mold cavity is obtained, (iii) the liquid-free surface is stable and has low distortions, and (iv) the flow divider neither increases the bubble breakage nor the coalescence between them. Full article

From the mid-1990s onwards, the concept of competitiveness was introduced to firms at the level of countries, regions, and cities. It was used as an index of the success and superiority of places. The present study used quantitative (survey) and qualitative methods in the framework of the exploratory paradigm to achieve key driving variables affecting the competitiveness of Kermanshah. The present study was applied in terms of its purpose and descriptive–analytical nature and research method. The study’s statistical population consisted of experts related to the Kermanshah competitiveness index, which studied 30 experts using the snowball method. MICMAC software was used to analyze the research data. Findings indicated that out of a total of 54 variables affecting the competitiveness of Kermanshah, 11 variables were in this group, which were the role of Kermanshah city in the power structure (MIN1); geographical and strategic location (MIN4); national, regional, and local plans (MIN5); management (MIN6); clean and healthy air (ENV1); potential sources of soil and water (ENV2); security of space (SEC2); the agricultural sector (ECO7); domestic tourism (ECO16); foreign tourism (ECO17); and sustainable sources of income (ECO19). The final model of Kermanshah’s future competitiveness will be that in the first stage, if the government (administration and government structure), in the form of national, regional, and local programs, pays attention to the competitive advantages of places. Especially, in large cities, and eliminating regional inequalities and in the next stage, local government (officials, managers, and all planners as the executive department) will need to act in order to operationalize the competitiveness of the city. With the correct use of opportunities and potentials (economic, socio-cultural, environmental, and security), in the 20-year horizon, Kermanshah will be a city with national and even transnational competitiveness. Otherwise, in addition to burning opportunities and destroying the capabilities of Kermanshah, other places adjacent to Kermanshah province will gradually be involved in challenges; tensions; and economic, cultural, social, environmental, security, and other crises. Full article

China, particularly the cotton-growing province of Xinjiang, is experiencing acute agricultural water shortages, stifling the expansion of the cotton sector. Discovering drought resistance genes in cotton and generating high-quality, drought-resistant cotton varieties through molecular breeding procedures are therefore critical to the cotton industry’s success. The drought-resistant cotton variety Xinluzhong No. 82 and the drought-sensitive cotton variety Kexin No. 1 were utilised in this study to uncover a batch of drought-resistant candidate genes using whole transcriptome sequencing. The following are the key research findings: A competing endogenous RNA network (ceRNA) was built using complete transcriptional sequencing to screen the core genes in the core pathway, and two drought-related candidate genes were discovered. It was found that γ-aminobutyric acid aminotransferase (GhGABA-T, Gohir.A11G156000) was upregulated at 0 h vs. 12 h and downregulated at 12 h vs. 24 h. L-Aspartate oxidase (GhAO, Gohir.A07G220600) was downregulated at 0 h vs. 12 h and upregulated at 12 h vs. 24 h. GABA-T is analogous to a pyridoxal phosphate-dependent transferase superfamily protein (POP2) in Arabidopsis thaliana and influences plant drought resistance by controlling γ-aminobutyric acid (GABA) concentration. The analogue of GhAO in A. thaliana is involved in the early steps of nicotinamide adenine dinucleotide (NAD) production as well as in plant antioxidant responses. This study revealed that gene expression regulatory networks can be used for rapid screening of reliable drought resistance genes and then utilised to validate gene function. Full article

The multiphase flow in the mold has a significant impact on the surface quality of the slab. In this paper, the multiphase flow in the mold is studied by establishing a one-quarter scale water mold, with the aid of a high-speed camera and particle image velocimetry (PIV). The oil phase will make the liquid surface velocity around the nozzle smaller. The greater the viscosity of the oil, the greater the critical water model casting speed and the shallower the critical immersion depth of submerged entry nozzle (SEN). Blowing will enhance the turbulence of the flow field in the mold and have a suppressing effect on the surface velocity. However, the vertical velocity of the narrow surface does not change significantly. The randomness of the bubble entering the mold from the nozzle can easily cause asymmetry of the instantaneous flow. The number of bubbles with a diameter less than 1 mm increase with the increase in gas flow rate. The larger the bubble size, the more buoyant around the nozzle when it escapes. The larger the diameter of bubble, the closer the vortex center of the upper circulation is to the nozzle and the closer the center of the lower circulation is to the narrow surface. Full article

Quinoa is a potential alternative crop for an adaptation strategy for salinization and climate change effects in dryland. A sowing date of February practiced in the Rehamna region, Morocco, resulted in stunted plants and low yields due to insufficient precipitations and high temperatures around the flowering stage. For this reason, a field experiment was conducted to investigate the effect of sowing date on quinoa water use efficiency, growth, and yield. The experiment was conducted at the UM6P experimental farm to evaluate five sowing dates for two short cycle quinoa cultivars. The results showed that the most early suitable sowing date of quinoa in the Rehamna region was December. Late sowing dates resulted in a significant decrease in WUE, growth and yield. The highest grain yield (0.84 t ha⁻¹) was obtained by ICBA-Q5 sown in December. Full article

Resin-based binders are one of the main materials used in foundry molding and core sands. This work adds to the research on self-curing sands with furfuryl resin, which dominates in the production of large-size castings. The work concerns the possibility of using biodegradable polymers as a component of resin-based binders. Biodegradable or partially biodegradable polymers are a group of materials which have an increasing level of importance in many areas of life and technology. This is mainly due to the increase in waste deposited in landfills, water and soil. This problem also concerns waste from the casting production process with the use of disposable molds with resin-based binders, which are mainly residues from their mechanical regeneration process. The aim of the research presented in this paper was to determine the effect of polycaprolactone (PCL) on the structure of post-regeneration dust from molding sands before and after the biodegradation process carried out in a water environment. Structure studies were carried out by Fourier transform infrared spectroscopy (FTIR) and the changes in the mass by TG/DTA-QMS analysis. The article also presents the results of the research of the morphology carried out by scanning electron microscopy (SEM) and the chemical oxygen demand index (COD) in water extracts of dust samples. Full article

Arbuscular mycorrhizal fungi (AMF) form a symbiotic relationship with plants; a symbiotic relationship is one in which both partners benefit from each other. Fungi benefit plants by improving uptake of water and nutrients, especially phosphorous, while plants provide 10–20% of their photosynthates to fungus. AMF tend to make associations with 85% of plant families and play a significant role in the sustainability of an ecosystem. Plants’ growth and productivity are negatively affected by various biotic and abiotic stresses. AMF proved to enhance plants’ tolerance against various stresses, such as drought, salinity, high temperature, and heavy metals. There are some obstacles impeding the beneficial formation of AMF communities, such as heavy tillage practices, high fertilizer rates, unchecked pesticide application, and monocultures. Keeping in view the stress-extenuation potential of AMF, the present review sheds light on their role in reducing erosion, nutrient leaching, and tolerance to abiotic stresses. In addition, recent advances in commercial production of AMF are discussed. Full article

The Straits of Messina (Southern Italy, Mediterranean Sea) are a very complex area: they connect two basins (Tyrrhenian and Ionian) with different hydrographic features and is characterised by upwelling and mixing phenomena. The aim of the study was to evaluate if and how the physical and chemical water conditions and hydrodynamics influenced the phytoplankton and bacterial patterns and the functioning of this ecosystem. During a late winter survey, size-fractionated phytoplankton (from 0.2 to 200 μm) biomass (chlorophyll a), cell densities and species composition as well as total picoplankton abundances, morphotype composition, and activity levels of the enzymes leucine aminopeptidase, β-glucosidase, and alkaline phosphatase were investigated. The obtained results showed a marked diversification among the water masses identified within the Straits area. The analyses of the phytoplankton diversity indices, particularly those based on phylogenetic relationships between species (indices of taxonomic diversity and distinctness), confirmed our findings. In conclusion, the patterns of phytoplankton and bacterial communities provide a suitable approach to evaluate how microbial communities respond to changing environmental scenarios. This tool could be applied to other temperate Mediterranean ecosystems. Full article

Based on the criteria importance through inter-criteria correlation (CRITIC) and the multi-attributive border approximation area comparison (MABAC), a decision-making algorithm was developed to select the optimal biocomposite material according to several conflicting attributes. Poly(lactic acid) (PLA)-based binary biocomposites containing wood waste and ternary biocomposites containing wood waste/rice husk with an overall additive content of 0, 2.5, 5, 7.5 and 10 wt.% were manufactured and evaluated for physicomechanical and wear properties. For the algorithm, the following performance attributes were considered through testing: the evaluated physical (density, water absorption), mechanical (tensile, flexural, compressive and impact) and sliding wear properties. The water absorption and strength properties were found to be the highest for unfilled PLA, while modulus performance remained the highest for 10 wt.% rice husk/wood-waste-added PLA biocomposites. The density of PLA biocomposites increased as rice husk increased, while it decreased as wood waste increased. The lowest and highest density values were recorded for 10 wt.% wood waste and rice husk/wood-waste-containing PLA biocomposites, respectively. The lowest wear was exhibited by the 5 wt.% rice husk/wood-waste-loaded PLA biocomposite. The experimental results were composition dependent and devoid of any discernible trend. Consequently, prioritizing the performance of PLA biocomposites to choose the best one among a collection of alternatives became challenging. Therefore, a decision-making algorithm, called CRITIC–MABAC, was used to select the optimal composition. The importance of attributes was determined by assigning weight using the CRITIC method, while the MABAC method was employed to assess the complete ranking of the biocomposites. The results achieved from the hybrid CRITIC–MABAC approach demonstrated that the 7.5 wt.% wood-waste-added PLA biocomposite exhibited the optimal physicomechanical and wear properties. Full article

The adverse impact of climate change on different regionally important sectors such as agriculture and hydropower is a serious concern and is currently at the epicentre of global interest. Despite the extensive efforts to project the future climate and assess its potential impact, it is surrounded by uncertainties. This study aimed to assess climate models’ performance and associated uncertainties in rainfall projection over the eastern Nile basin, Ethiopia. Seventeen climate models from Coordinated Regional Climate Downscaling Experiment (CORDEX) and their four ensemble models were evaluated in terms of their historical prediction performance (1986–2005) and future simulation skill (2006–2016) at rainfall station (point location), grid-scale (0.44° × 0.44°) and basin scale. Station-based and spatially interpolated observed rainfall data were used as a reference during climate model performance evaluation. In addition, CRU data was used as an alternative reference data to check the effect of the reference data source on the climate models evaluation process. As the results showed, climate models have a large discrepancy in their projected rainfall and hence prior evaluation of their performance is necessary. For instance, the bias in historical mean annual rainfall averaged over the basin ranges from +760 mm (wet bias) to −582 mm (dry bias). The spatial pattern correlation (r) of climate models output and observed rainfall ranges from −0.1 to 0.7. The ensemble formed with selected (performance-based) member models outperforms the widely used multi-model ensemble in most of the evaluation metrics. This showed the need for reconsidering the widely used multi-model approach in most climate model-based studies. The use of CRU data as a reference resulted in a change in the magnitude of climate model bias. To conclude, each climate model has a certain degree of uncertainty in the rainfall projection, which potentially affects the studies on climate change and its impact (e.g., on water resources). Therefore, climate-related studies have to consider uncertainties in climate projections, which will help end-users (decision-makers) at least to be aware of the potential range of deviation in the future projected outcomes of interest. Full article

Hebei Province of China is facing a severe water resource shortage, making it urgent to formulate economical and effective water conservation policies. However, few studies have focused on analyzing the resource and economic impacts of a water policy. This study developed an improved computable general equilibrium (CGE) model with an extended water resources module as a policy analysis tool. The extended water resources module includes different water resources as commodities and water sectors, and introduces a substitution mechanism among the water resources. Policy scenarios containing different policy types and policy objects were established, including water price, technology (tech) improvement, structure adjustment, and water reuse policies in primary, secondary, and tertiary sectors. The impact on the water resource and economy of the scenarios was analyzed using the CGE model. The recommended policies include: an agricultural technology improvement policy that decreases groundwater usage by 240 hm³; an industrial technology improvement policy under which water usage per 10,000 CNY of industrial added value decreases by 13%; an industrial water reuse policy that increases unconventional water usage by 20%; and a structure adjustment policy to increase the proportion of the tertiary sector. The study provides an analysis tool for simulating and evaluating a water resource policy. Full article

Liquid–liquid membrane contactors (LLMCs) were studied as a sustainable technology for ammonia recovery from wastewater. Ammonia can be valorized by LLMCs as a potential nutrient and produce liquid fertilizers. Thus, this work aims for the study of different experimental LLMC conditions to produce ammonium salts by an acid stripping stream. The experiments were conducted using two 3M^TMLiqui-Cell^TM LLMC in a series, located in the vertical position and using HNO₃ as the acid stripping solution. The flow rates for the feed and stripping sides were fixed during the tests, and two steps were conducted based on previous works. However, different experimental conditions were evaluated to determine its effect on the overall performance: (i) replacing the feed or stripping solution between the steps, (ii) the initial ammonia concentration of the feed solution, (iii) feed volume and (iv) feed temperature. The results demonstrated that better achievements were obtained replacing the acid stripping solution between steps, whereas the feed temperature did not substantially affect the overall performance. Additionally, a high initial ammonia concentration provided more ammonia recovery, although the concentration factor achieved was higher for the low initial ammonia concentration. Finally, a high feed volume afforded better results for the fertilizer side, whereas more NH₃ recovery was achieved using less feed volume. Full article

This research estimates the efficiency of domestic wastewater treatment in the removal of organic pollutants and nitrogen compounds with a two-stage treatment sequence (an activated sludge reactor in the first stage, and a trickling filter in the second stage), and with the application of floating carriers in the activated sludge reactor. The materials “Polyvom”, “Polystyrene” and “Bioballs” were adopted as floating carriers with previously determined filling ratios in the reactor volume of 10%, 20% and 20%, respectively. After the first stage of the study, it was found that the most effective treatment was achieved using the “Polyvom” material. Therefore, only this floating carrier was considered in the second and third stages of the study. Within the stages of the research, lab-scale benches operated under different operation modes of the treatment sequence. At the end of the study, it was possible to achieve the following levels of purification: BOD₅ (2.1 mg/L), NH₄ (0.4 mg/L), NO₂ (1.0 mg/L), and NO₃ (25 mg/L). The mean values of the concentrations of BOD, NH₄, and NO₃ met the requirements, but the concentration of NO₂ exceeded the requirements (1.0 mg/L vs. 0.08 mg/L). These results were achieved under a hydraulic retention time in the activated sludge reactor of 8 h, and the MLSS for the free-floating and immobilized activated sludge was 0.2 and 0.9 g/L, respectively. Full article