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Article

Cu- and Fe-Doped Ni-Mn-Sn Shape Memory Alloys with Enhanced Mechanical and Magnetocaloric Properties

by
Siyao Ma
1,2,
Xuexi Zhang
1,*,
Guangping Zheng
2,*,
Mingfang Qian
1 and
Lin Geng
1
1
School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
2
Department of Mechanical Engineering, The Hong Kong Polytechnic University, Hong Kong, China
*
Authors to whom correspondence should be addressed.
Submission received: 7 June 2024 / Revised: 23 June 2024 / Accepted: 26 June 2024 / Published: 28 June 2024
(This article belongs to the Special Issue Physical Metallurgy of Metals and Alloys (3rd Edition))

Abstract

Ni-Mn-Sn-based ferromagnetic shape memory alloys (FSMAs) are multifunctional materials that are promising for solid-state refrigeration applications based on the magnetocaloric effect (MCE) and elastocaloric effect (eCE). However, a combination of excellent multi-caloric properties, suitable operating temperatures, and mechanical properties cannot be well achieved in these materials, posing a challenge for their practical application. In this work, we systematically study the phase transformations and magnetic properties of Ni50xMn38Sn12Cux (x = 0, 2, 3, 4, 5, and 6) and Ni50yMn38Sn12Fey (y = 0, 1, 2, 3, 4, and 5) alloys, and the magnetic-structural phase diagrams of these alloy systems are reported. The influences of the fourth-element doping on the phase transitions and magnetic properties of the alloys are elucidated by first-principles calculations. This work demonstrates that the fourth-element doping of Ni-Mn-Sn-based FSMA is effective in developing multicaloric refrigerants for practical solid-state refrigeration.
Keywords: Ni-Mn-Sn alloys; magnetic properties; mechanical properties; magnetocaloric effect; first-principles calculation Ni-Mn-Sn alloys; magnetic properties; mechanical properties; magnetocaloric effect; first-principles calculation

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MDPI and ACS Style

Ma, S.; Zhang, X.; Zheng, G.; Qian, M.; Geng, L. Cu- and Fe-Doped Ni-Mn-Sn Shape Memory Alloys with Enhanced Mechanical and Magnetocaloric Properties. Materials 2024, 17, 3172. https://0-doi-org.brum.beds.ac.uk/10.3390/ma17133172

AMA Style

Ma S, Zhang X, Zheng G, Qian M, Geng L. Cu- and Fe-Doped Ni-Mn-Sn Shape Memory Alloys with Enhanced Mechanical and Magnetocaloric Properties. Materials. 2024; 17(13):3172. https://0-doi-org.brum.beds.ac.uk/10.3390/ma17133172

Chicago/Turabian Style

Ma, Siyao, Xuexi Zhang, Guangping Zheng, Mingfang Qian, and Lin Geng. 2024. "Cu- and Fe-Doped Ni-Mn-Sn Shape Memory Alloys with Enhanced Mechanical and Magnetocaloric Properties" Materials 17, no. 13: 3172. https://0-doi-org.brum.beds.ac.uk/10.3390/ma17133172

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