Mineral Composition through Soil-Wine System of Portuguese Vineyards and Its Potential for Wine Traceability
Abstract
:1. Introduction
2. Materials and Methods
2.1. Vineyards
2.2. Soil and Grape Berries Sampling
2.3. Winemaking and Wine Sampling
2.4. Sample Processing
2.5. Multi-Elemental Analysis
2.6. Statistical Analysis
3. Results and Discussion
3.1. Mineral Composition of Vineyard Soils
3.2. Mineral Elements Concentration during Vinification Processes
3.2.1. Alkaline and Alkaline Earth Elements
3.2.2. Contaminant Elements
3.2.3. Rare Earth Elements
3.3. Mineral Composition of Wines
3.4. Vineyards and Vintage Year
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Vineyard/ Portuguese DO | Area of the Vineyard (ha) | Year of Planting | Rootstock | Vine Spacing (m) | Row Orientation | Training System |
---|---|---|---|---|---|---|
AL vineyard/Palmela | 3.0 | 1990 | 1103P | 2.8 × 1.2 | N-S | bi-lateral cordon |
SF vineyard/Óbidos | 5.0 | 2001 | R110 | 2.7 × 1.0 | N-S and E-W | bi-lateral cordon |
SA vineyard/Óbidos | 2.6 | 2000 | R110 | 2.7 × 1.0 | N-S | bi-lateral cordon |
QC vineyard/Dão | 2.5 | 1995 | 1103P | 2.0 × 1.2 | NE-SW | bi-lateral cordon |
Element | Vineyard Effect | AL Vineyard /Palmela | SF Vineyard /Óbidos | SA Vineyard /Óbidos | QC Vineyard /Dão |
---|---|---|---|---|---|
Li | ** | 23 ± 6 | 33 ± 7 | 39 ± 7 | 224 ± 50 |
Be | ** | 1.1 ± 0.3 | 2 ± 1 | 2.0 ± 0.4 | 31 ± 10 |
Na | ** | 4043 ± 1134 | 1555 ± 317 | 2561 ± 471 | 2570 ± 1081 |
Mg | ** | 737 ± 214 | 3226 ± 1839 | 1612 ± 430 | 5690 ± 898 |
Al | ** | 41,987 ± 9113 | 76,330 ± 19,270 | 49,982 ± 6832 | 149,501 ± 14,233 |
Ca | ** | 1759 ± 427 | 1775 ± 970 | 1046 ± 513 | 1850 ± 1126 |
Ti | ** | 5 ± 2 | 10 ± 3 | 8 ± 2 | 9 ± 1 |
V | ** | 20 ± 6 | 75 ± 29 | 40 ± 9 | 69 ± 12 |
Cr | ** | 17 ± 4 | 63 ± 27 | 29 ± 7 | 52 ± 12 |
Mn | ** | 87 ± 24 | 1147 ± 662 | 1166 ± 477 | 514 ± 105 |
Fe | ** | 6530 ± 2060 | 27,390 ± 11,737 | 12,580 ± 2877 | 40,450 ± 5543 |
Co | ** | 2 ± 1 | 15 ± 7 | 8 ± 2 | 9 ± 2 |
Cu | * | 82 ± 39 | 87 ± 29 | 117 ± 61 | 79 ± 30 |
Ga | ** | 9 ± 2 | 19 ± 5 | 13 ± 2 | 38 ± 4 |
Ge | ** | 0.26 ± 0.06 | 0.31 ± 0.05 | 0.29 ± 0.05 | 0.52 ± 0.07 |
As | ** | 6 ± 3 | 11 ± 4 | 9 ± 3 | 46 ± 12 |
Rb | ** | 165 ± 43 | 190 ± 23 | 188 ± 27 | 333 ± 52 |
Sr | ** | 59 ± 15 | 57 ± 6 | 57 ± 17 | 34 ± 4 |
Sn | ** | 7 ± 3 | 6 ± 1 | 6 ± 2 | 25 ± 3 |
Sb | ** | 1.4 ± 0.9 | 0.8 ± 0.2 | 0.8 ± 0.3 | 0.38 ± 0.07 |
I | ** | 0.2 ± 0.1 | 0.6 ± 0.4 | 0.5 ± 0.4 | 0.5 ± 0.2 |
Cs | ** | 5 ± 1 | 9 ± 2 | 8 ± 1 | 55 ± 10 |
Ba | ** | 663 ± 316 | 591 ± 375 | 501 ± 57 | 305 ± 41 |
La | * | 19 ± 5 | 22 ± 8 | 16 ± 7 | 23 ± 11 |
Ce | ** | 44 ± 11 | 49 ± 19 | 38 ± 15 | 59 ± 26 |
Pr | * | 5 ± 1 | 6 ± 2 | 5 ± 2 | 7 ± 3 |
Nd | ** | 20 ± 4 | 22 ± 8 | 19 ± 7 | 28 ± 13 |
Sm | ** | 3.7 ± 0.9 | 5 ± 1 | 4 ± 1 | 6 ± 2 |
Eu | ** | 0.6 ± 0.1 | 1.0 ± 0.3 | 0.7 ± 0.1 | 1.0 ± 0.3 |
Gd | ** | 3 ± 1 | 4 ± 1 | 4 ± 1 | 6 ± 2 |
Tb | ** | 0.36 ± 0.08 | 0.6 ± 0.2 | 0.5 ± 0.1 | 0.9 ± 0.3 |
Dy | ** | 1.8 ± 0.4 | 3 ± 1 | 2.6 ± 0.6 | 5 ± 2 |
Ho | ** | 0.31 ± 0.08 | 0.6 ± 0.2 | 0.5 ± 0.1 | 0.9 ± 0.3 |
Er | ** | 0.9 ± 0.2 | 1.9 ± 0.6 | 1.4 ± 0.3 | 2.5 ± 0.8 |
Tm | ** | 0.13 ± 0.04 | 0.27 ± 0.08 | 0.21 ± 0.04 | 0.4 ± 0.1 |
Yb | ** | 1.0 ± 0.3 | 1.8 ± 0.6 | 1.5 ± 0.3 | 2.4 ± 0.6 |
Lu | ** | 0.14 ± 0.04 | 0.27 ± 0.08 | 0.23 ± 0.04 | 0.35 ± 0.08 |
W | ** | 0.004 ± 0.001 | 0.007 ± 0.002 | 0.006 ± 0.001 | 0.045 ± 0.015 |
Tl | ** | 0.9 ± 0.3 | 1.1 ± 0.1 | 1.3 ± 0.2 | 2.4 ± 0.3 |
Element | Vineyard Effect | AL Vineyard/Palmela | SF Vineyard/Óbidos | SA Vineyard/Óbidos | QC Vineyard/Dão |
---|---|---|---|---|---|
Li | ** | 3049 ± 345 a | 6323 ± 241 b | 8084 ± 230 c | 10,550 ± 1017 d |
Be | * | 251 ± 7 | 358 ± 17 | 222 ± 18 | 539 ± 139 |
Na | ** | 14,633 ± 639 c | 15,640 ± 1166 c | 10,706 ± 200 b | 6480 ± 724 a |
Mg | ** | 91,990 ± 5101 b | 100,454 ± 6075 b | 76,962 ± 1268 a | 99,038 ± 10,380 b |
Al | ** | 597 ± 51 c | 198 ± 25 b | 112 ± 6 a | 129 ± 18 a |
Ca | ** | 45,368 ± 3069 ab | 56,819 ± 4786 c | 41,245 ± 472 a | 50,980 ± 4935 bc |
Cr | * | 24,997 ± 3286 | 18,189 ± 120 | 114,734 ± 1530 | 20,166 ± 2344 |
Mn | ** | 407 ± 21 a | 1356 ± 94 d | 1184 ± 14 c | 1008 ± 98 b |
Fe | * | 1043 ± 65 | 1689 ± 111 | 1095 ± 8 | 186 ± 30 |
Ni | ** | 11,841 ± 1442 b | 16,100 ± 3393 c | 9177 ± 1085 ab | 6838 ± 1563 a |
Cu | * | 16 ± 1 | 78 ± 3 | 92 ± 1 | 78 ± 16 |
Zn | ** | 940 ± 17 d | 414 ± 33 c | 259 ± 24 b | 320 ± 32 a |
Ga | * | 841 ± 9 | 704 ± 16 | 984 ± 14 | 870 ± 100 |
Rb | * | 4037 ± 320 | 2694 ± 209 | 2638 ± 46 | 7228 ± 761 |
Sr | ** | 309 ± 18 b | 322 ± 22 b | 222 ± 9 a | 219 ± 24 a |
Mo | ** | 1039 ± 75 b | 317 ± 45 a | 329 ± 80 a | 1073 ± 73 b |
Sn | * | 137 ± 39 | 205 ± 27 | 934 ± 336 | 1032 ± 43 |
Sb | ** | 442 ± 54 b | 250 ± 32 a | 410 ± 74 b | 161 ± 48 a |
Cs | * | 3543 ± 294 | 2344 ± 158 | 2686 ± 15 | 64,716 ± 6609 |
Ba | ** | 194 ± 23 bc | 222 ± 21 c | 167 ± 4 ab | 138 ± 26 a |
La | * | 209 ± 79 | 193 ± 18 | 186 ± 9 | 634 ± 84 |
Ce | * | 177 ± 144 a | 207 ± 20 ab | 123 ± 26 a | 347 ± 73 b |
Pr | ** | 20 ± 14 a | 40 ± 8 b | 31 ± 6 ab | 85 ± 10 c |
Nd | * | 58 ± 57 | 161 ± 5 | 111 ± 9 | 347 ± 65 |
Sm | ** | 7 ± 9 a | 26 ± 4 b | 12 ± 6 a | 46 ± 6 c |
Eu | * | 40 ± 6 a | 50 ± 2 b | 49 ± 2 ab | 44 ± 8 ab |
Gd | ** | 16 ± 12 a | 34 ± 5 a | 23 ± 3 a | 85 ± 14 b |
Tb | ** | 2 ± 3 a | 9 ± 3 b | 3 ± 1 a | 11 ± 1 b |
Dy | ** | 17 ± 15 a | 43 ± 3 b | 20 ± 3 a | 65 ± 16 b |
Ho | ** | 5 ± 2 a | 13 ± 1 b | 6 ± 2 a | 16 ± 0 c |
Er | ** | 16 ± 4 a | 44 ± 7 b | 23 ± 6 a | 47 ± 2 b |
Tm | * | 3 ± 2 a | 9 ± 4 b | 6 ± 1 ab | 9 ± 2 b |
Yb | ** | 33 ± 4 a | 59 ± 5 c | 31 ± 3 a | 47 ± 7 b |
Lu | * | 7 ± 3 a | 13 ± 4 b | 8 ± 1 a | 9 ± 1 a |
W | * | 2 ± 1 ab | 0.3 ± 0.2 a | 1 ± 1 a | 3 ± 2 b |
Tl | * | 1174 ± 56 | 206 ± 14 | 659 ± 6 | 1173 ± 109 |
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Catarino, S.; Madeira, M.; Monteiro, F.; Caldeira, I.; Bruno de Sousa, R.; Curvelo-Garcia, A. Mineral Composition through Soil-Wine System of Portuguese Vineyards and Its Potential for Wine Traceability. Beverages 2018, 4, 85. https://0-doi-org.brum.beds.ac.uk/10.3390/beverages4040085
Catarino S, Madeira M, Monteiro F, Caldeira I, Bruno de Sousa R, Curvelo-Garcia A. Mineral Composition through Soil-Wine System of Portuguese Vineyards and Its Potential for Wine Traceability. Beverages. 2018; 4(4):85. https://0-doi-org.brum.beds.ac.uk/10.3390/beverages4040085
Chicago/Turabian StyleCatarino, Sofia, Manuel Madeira, Fernando Monteiro, Ilda Caldeira, Raúl Bruno de Sousa, and António Curvelo-Garcia. 2018. "Mineral Composition through Soil-Wine System of Portuguese Vineyards and Its Potential for Wine Traceability" Beverages 4, no. 4: 85. https://0-doi-org.brum.beds.ac.uk/10.3390/beverages4040085