Thin Film Based Sensors II

A special issue of Chemosensors (ISSN 2227-9040). This special issue belongs to the section "Electrochemical Devices and Sensors".

Deadline for manuscript submissions: closed (31 December 2021) | Viewed by 6330

Special Issue Editors


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Laboratory for Instrumentation, Biomedical Engineering and Radiation Physics (LIBPhys-NOVA), Department of Physics, NOVA School of Science and Technology, NOVA University of Lisbon, Campus FCT-NOVA, 2829-516 Caparica, Portugal
Interests: disease diagnosis; biosensors; biomarker; human health monitoring
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Departamento de Física, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Portugal
Interests: thin films; functional molecular systems; sensors and transducers; electrical and optical properties of materials; biomedical sciences
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

An increasing number of fields in everyday life require development and application of ever more modern and efficient chemical sensors and biosensors, from drug detection to clinical diagnosis, from control of industrial quality and safety and combating bioterrorism to health and environmental monitoring. However, the general way to develop these sensors is by using hierarchical assembly of nanoscale building blocks as thin films sensing structures to adsorb each of the molecules to be detected typically by different methods such as potentiometry, amperometry, cyclic voltammetry, impedance spectroscopy, and also by other methods, for example, microcantilevers and surface acoustic waves, among others, and fiber optic-based sensor devices. The goal of this Special Issue on Thin Film-Based Sensor Devices is to give a survey of the state-of-the-art on organic and inorganic thin films sensor-based devices, which allow the detection of a determined molecular specie or set of molecules on a complex media, in order to compile, criticize, and systematize the achieved knowledge and to provide guidelines for a next generation of quantifying and selective sensor devices. Under this compliance, we are launching the challenge for the submission of review-like contributions covering both theoretical and practical aspects in the field of thin films sensor devices made of functional molecular layers, capable of detection and quantification particularly in complex media. A wide range of experimental techniques for the obtention of molecular layers can be envisaged herein, as, for example, Langmuir–Blodgett, self-assembly, layer-by-layer, molecularly imprinted polymers, sol–gel, casting, spin-coating, vacuum evaporating, plasma assisted deposition, electron beam deposition, chemical vapor deposition or molecular beam epitaxy.

Dr. Maria Raposo
Dr. Paulo A. Ribeiro
Guest Editors

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Keywords

  • Thin film sensor devices 
  • Chemistry and physics of thin film deposition 
  • Chemistry and physics detection mechanisms 
  • Selective thin film sensors
  • Quantifying thin film sensors 
  • Thin film sensor arrays 
  • Multicomponent detection thin film sensors
  • Thin films for detection in complex systems 
  • Thin film-based electronic tongue and nose 
  • Lab-on-a-chip thin film sensor devices

Published Papers (2 papers)

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Research

16 pages, 30649 KiB  
Article
Nonenzymatic Lactic Acid Detection Using Cobalt Polyphthalocyanine/Carboxylated Multiwalled Carbon Nanotube Nanocomposites Modified Sensor
by Wenqing Shao, Jiayu Mai and Zhenbo Wei
Chemosensors 2022, 10(2), 83; https://0-doi-org.brum.beds.ac.uk/10.3390/chemosensors10020083 - 15 Feb 2022
Cited by 9 | Viewed by 2623
Abstract
In this study, a novel cobalt polyphthalocyanine/carboxylic acid functionalized multiwalled carbon nanotube nanocomposite (CoPPc/MWCNTs-COOH) to detect lactic acid was successfully fabricated. The nanocomposite was systematically characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, ultraviolet–visible absorption spectroscopy, and X-ray photoelectron spectroscopy. The nanocomposite [...] Read more.
In this study, a novel cobalt polyphthalocyanine/carboxylic acid functionalized multiwalled carbon nanotube nanocomposite (CoPPc/MWCNTs-COOH) to detect lactic acid was successfully fabricated. The nanocomposite was systematically characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, ultraviolet–visible absorption spectroscopy, and X-ray photoelectron spectroscopy. The nanocomposite provided excellent conductivity for effective charge transfer and avoided the agglomeration of MWCNTs-COOH. The electrochemical surface area, diffusion coefficient and electron transfer resistance of the CoPPc/MWCNTs-COOH glassy carbon electrode (CoPPc/MWCNTs-COOH/GCE) were calculated as A = 0.49 cm2, D = 9.22 × 10−5 cm2/s, and Rct = 200 Ω, respectively. The lactic acid sensing performance of the CoPPc/MWCNTs-COOH was evaluated using cyclic voltammetry in 0.1 M PBS (pH 4). The results demonstrated that the novel electrode exhibited excellent electrochemical performance toward lactic acid reduction over a wide concentration range (10 to 240 μM), with a low detection limit (2 μM (S/N = 3)), and a reasonable selectivity against various interferents (ascorbic acid, uric acid, dopamine, sodium chloride, glucose, and hydrogen peroxide). Additionally, the electrode was also successfully applied to quantify lactic acid in rice wine samples, showing great promise for rapid monitoring applications. Full article
(This article belongs to the Special Issue Thin Film Based Sensors II)
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11 pages, 3402 KiB  
Article
Application of Ba0.5Sr0.5TiO3 (Bst) Film Doped with 0%, 2%, 4% and 6% Concentrations of RuO2 as an Arduino Nano-Based Bad Breath Sensor
by Irzaman, Ridwan Siskandar, Brian Yuliarto, Mochammad Zakki Fahmi and Ferdiansjah
Chemosensors 2020, 8(1), 3; https://0-doi-org.brum.beds.ac.uk/10.3390/chemosensors8010003 - 25 Dec 2019
Cited by 7 | Viewed by 3224
Abstract
Ba0.5Sr0.5TiO3 (BST) film doped with variations in RuO2 concentration (0%, 2%, 4%, and 6%) has been successfully grown on a type-p silicon substrate (100) using the chemical solution deposition (CSD) method and spin-coating at a speed of [...] Read more.
Ba0.5Sr0.5TiO3 (BST) film doped with variations in RuO2 concentration (0%, 2%, 4%, and 6%) has been successfully grown on a type-p silicon substrate (100) using the chemical solution deposition (CSD) method and spin-coating at a speed of 3000 rpm for 30 s. The film on the substrate was then heated at 850 °C for 15 h. The sensitivity of BST film + RuO2 variations as a gas sensor were characterized. The sensitivity characterization was assisted by various electronic circuitry with the purpose of producing a sensor that is very sensitive to gas. The responses from the BST film + RuO2 variation were varied, depending on the concentration of the RuO2 dope. BST film doped with 6% RuO2 had a very good response to halitosis gases; therefore, this film was applied as the Arduino-Nano-based bad-breath detecting sensor. Before it was integrated with the microcontroller, the voltage output of the BST film was amplified using an op-amp circuit to make the voltage output from the BST film readable to the microcontroller. The changes in the voltage response were then shown on the prototype display. If the voltage output was ≤12.9 mV, the display would read “bad breath”. If the voltage output >42.1 mV, the display would read “fragrant”. If 12.9 mV < voltage output ≤ 42.1 mV, the display would read “normal”. Full article
(This article belongs to the Special Issue Thin Film Based Sensors II)
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