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Inorganics
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Women’s Special Issue Series: Inorganics
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Women’s Special Issue Series: Inorganics

A special issue of Inorganics (ISSN 2304-6740).

Deadline for manuscript submissions: closed (8 March 2024) | Viewed by 4104

Special Issue Editors

Prof. Dr. Tatjana N. Parac-Vogt

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Guest Editor
Department of Chemistry, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium
Interests: polyoxometalates (POMs); metal organic frameworks (MOFs); metal-oxo clusters; artificial metalloenzymes; bio-inspired catalysis
Prof. Dr. Sophie Hermans

E-Mail Website
Guest Editor
Molecular Chemistry, Materials and Catalysis (MOST), Institute of Condensed Matter and Nanosciences (IMCN), UCLouvain, Place Louis Pasteur 1, B-1348 Louvain-la-Neuve, Belgium
Interests: carbon-supported catalysts; biomass valorization; carbohydrate transformations; (nano-)carbon functionalization; nanoparticles synthesis; nanomaterials chemistry
Special Issues, Collections and Topics in MDPI journals
Prof. Dr. Sandra Luber

E-Mail Website
Guest Editor
Department of Chemistry, University of Zurich, CH-8057 Zurich, Switzerland
Interests: development and application of computational methods at the interface of chemistry, (bio-)physics, and materials science; spectroscopy; catalysis; static and dynamic ab initio methods; light-driven processes; chirality; liquids; interfaces; machine learning; in silico design
Special Issues, Collections and Topics in MDPI journals
Dr. Christelle Hureau

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Guest Editor
Laboratoire de Chimie de Coordination (LCC), CNRS UPR 8241, 205 Route de Narbonne, CEDEX 09, 31062 Toulouse, France
Interests: bio-inorganic chemistry; metal-peptide interactions; metals as therapeutic targets; inorganic compounds as therapeutic agents; amyloid-forming peptides; EPR spectroscopy; electrochemistry
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

We are delighted to present this special collection of articles that highlight the achievements of female scientists in (bio)inorganic chemistry, coordination chemistry, organometallic chemistry and inorganic materials, from all around the world. This Special Issue is devoted to presenting research performed by early and advanced career female scientists.

Inorganics is an open access journal that covers all aspects of inorganic chemistry research. Its primary areas of research interests include, but are not limited to, the following:

  • Inorganic compounds, complexes and materials;
  • Structures and bonding;
  • Spectroscopic, magnetic, physical and chemical properties;
  • Chemical reactivity, physical properties and applications;
  • Mechanisms of inorganic reactions;
  • Organometallic compounds;
  • Inorganic cluster chemistry and nanoparticles;
  • Heterogenous and homogeneous catalytic reactions;
  • Thermodynamics and kinetics;
  • Supramolecular systems and coordination polymers;
  • Bio-inorganic chemistry and applications in biological systems;
  • Environmental and sustainable energy applications.

Original research articles and comprehensive review papers where the lead authors are women, or that are completely authored by women, are encouraged. We welcome submissions from all authors, irrespective of gender.

Prof. Dr. Tatjana N. Parac-Vogt
Prof. Dr. Sophie Hermans
Prof. Dr. Sandra Luber
Dr. Christelle Hureau
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Inorganics is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Published Papers (2 papers)

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Research

18 pages, 2053 KiB  
Article
Deciphering Interactions Involved in Immobilized Metal Ion Affinity Chromatography and Surface Plasmon Resonance for Validating the Analogy between Both Technologies
by Rachel Irankunda, Jairo Andrés Camaño Echavarría, Cédric Paris, Katalin Selmeczi, Loïc Stefan, Sandrine Boschi-Muller, Laurence Muhr and Laetitia Canabady-Rochelle
Inorganics 2024, 12(1), 31; https://0-doi-org.brum.beds.ac.uk/10.3390/inorganics12010031 - 16 Jan 2024
Cited by 2 | Viewed by 1389
Abstract
Various peptides can be obtained through protein enzymatic hydrolysis. Immobilized metal ion affinity chromatography (IMAC) is one of the methods which can be used to separate metal chelating peptides (MCPs) in a hydrolysate mixture. In this context, this work aims to understand deeply [...] Read more.
Various peptides can be obtained through protein enzymatic hydrolysis. Immobilized metal ion affinity chromatography (IMAC) is one of the methods which can be used to separate metal chelating peptides (MCPs) in a hydrolysate mixture. In this context, this work aims to understand deeply the interactions in IMAC and surface plasmon resonance (SPR) in order to validate experimentally the analogy between both technologies and to be further able to perform IMAC modeling in the next work using peptide sorption isotherm parameters obtained from SPR. Indeed, chromatography modeling can be used to predict separation of MCPs in IMAC and the knowledge of peptide sorption isotherm obtained from SPR is a crucial step. For this purpose, 22 peptides were selected and investigated in IMAC using HisTrap X-Ni2+ and HiFliQ NTA-Ni2+ columns and were also studied in SPR as well. Results showed that peptides with histidine residues had good affinity to Ni2+, while the high positive charge of peptides was responsible of ionic interactions. Further, most of the peptides with good retention time in IMAC showed a good affinity in SPR as well, which validated experimentally the SPR-IMAC analogy. Full article
(This article belongs to the Special Issue Women’s Special Issue Series: Inorganics)
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19 pages, 3504 KiB  
Article
How Metal Nuclearity Impacts Electrocatalytic H2 Production in Thiocarbohydrazone-Based Complexes
by Michael Papadakis, Alexandre Barrozo, Léa Delmotte, Tatiana Straistari, Sergiu Shova, Marius Réglier, Vera Krewald, Sylvain Bertaina, Renaud Hardré and Maylis Orio
Inorganics 2023, 11(4), 149; https://0-doi-org.brum.beds.ac.uk/10.3390/inorganics11040149 - 31 Mar 2023
Viewed by 1407
Abstract
Thiocarbohydrazone-based catalysts feature ligands that are potentially electrochemically active. From the synthesis point of view, these ligands can be easily tailored, opening multiple strategies for optimization, such as using different substituent groups or metal substitution. In this work, we show the possibility of [...] Read more.
Thiocarbohydrazone-based catalysts feature ligands that are potentially electrochemically active. From the synthesis point of view, these ligands can be easily tailored, opening multiple strategies for optimization, such as using different substituent groups or metal substitution. In this work, we show the possibility of a new strategy, involving the nuclearity of the system, meaning the number of metal centers. We report the synthesis and characterization of a trinuclear nickel-thiocarbohydrazone complex displaying an improved turnover rate compared with its mononuclear counterpart. We use DFT calculations to show that the mechanism involved is metal-centered, unlike the metal-assisted ligand-centered mechanism found in the mononuclear complex. Finally, we show that two possible mechanisms can be assigned to this catalyst, both involving an initial double reduction of the system. Full article
(This article belongs to the Special Issue Women’s Special Issue Series: Inorganics)
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