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Advanced Nanostructured Materials for Catalytic Applications towards Fine Chemicals Production

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Advanced Nanomaterials and Nanotechnology".

Deadline for manuscript submissions: closed (20 February 2022) | Viewed by 4654

Special Issue Editors


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Guest Editor
Department of Physical and Chemical Sciences (DSFC), University of L'Aquila, via Vetoio-Coppito Due, 67100 L'Aquila, Italy
Interests: heterogeneous catalysis; homogeneous catalysis; organometallic chemistry; hybrid organic/inorganic nanostructures; oxy/deoxy functionalization; oxidative desulfurization; fine-chemistry
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
Department of Physical and Chemical Sciences (DSFC), University of L'Aquila, via Vetoio-Coppito Due, 67100 L'Aquila, Italy
Interests: operando characterization; industrial catalysis; spectroscopy; nanoparticles; catalyst modification
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Modern chemical industry is progressively focusing its attention on more advanced and specific chemical moieties and molecules within the challenging field of the production of high-added-value products. Furthermore, new environmental challenges are capturing the attention of the scientific community and pushing its efforts towards the direction of a greener chemistry. In order to achieve these targets, we need to improve the efficiency of industrial processes rationally designing brand new catalysts as well as modifying existing catalysts. The aim of this Special Issue on “Advanced Nanostructured Materials for Catalytic Applications towards Fine Chemicals Production” is to gather the state of the art knowledge about novel nanomaterials and/or their novel preparation methods, innovative characterization techniques and catalyst testing, proving the novelty of the obtained material in the direction of a better catalytic performance, such as in the case of multisite catalytic materials, thus producing a clear improvement in economic and environmental terms. Submissions to this Special Issue of original research about bottom–up/top–down synthetic methodologies that are selectively effective on specific functional groups at the surface of the catalysts, characterization techniques in both in situ and in operando conditions devoted to demonstrating the nature of the active phase, studies about structure–activity relationships, and elucidation of catalytic reaction mechanisms will be gladly considered.

This Special Issue will cover but will not be limited to the following topics:

  • Engineered nanomaterials;
  • Metal organic framework;
  • Carbon nanoparticles;
  • Porous organic polymers;
  • Multisite hybrid organic–inorganic nanospheres;
  • Chiral hybrid catalysts;
  • Multifunctional lamellar hybrid materials;
  • Metallic nanoclusters;
  • Composite polyoxometalate materials;
  • Operando characterization;
  • Reaction mechanism.

It is our pleasure to invite you to submit a manuscript for this Special Issue. Research papers, communications or short reviews are welcome.

Prof. Marcello Crucianelli
Dr. Andrea Lazzarini
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • Engineered nanomaterials
  • Metal organic framework
  • Carbon nanoparticles
  • Porous organic polymers
  • Multisite hybrid organic–inorganic nanospheres
  • Chiral hybrid catalysts
  • Multifunctional lamellar hybrid materials
  • Metallic nanoclusters
  • Composite polyoxometalate materials
  • Operando characterization
  • Reaction mechanism

Published Papers (2 papers)

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Review

44 pages, 7991 KiB  
Review
Support–Activity Relationship in Heterogeneous Catalysis for Biomass Valorization and Fine-Chemicals Production
by Andrea Lazzarini, Roberta Colaiezzi, Francesco Gabriele and Marcello Crucianelli
Materials 2021, 14(22), 6796; https://0-doi-org.brum.beds.ac.uk/10.3390/ma14226796 - 11 Nov 2021
Cited by 4 | Viewed by 2329
Abstract
Heterogeneous catalysts are progressively expanding their field of application, from high-throughput reactions for traditional industrial chemistry with production volumes reaching millions of tons per year, a sector in which they are key players, to more niche applications for the production of fine chemicals. [...] Read more.
Heterogeneous catalysts are progressively expanding their field of application, from high-throughput reactions for traditional industrial chemistry with production volumes reaching millions of tons per year, a sector in which they are key players, to more niche applications for the production of fine chemicals. These novel applications require a progressive utilization reduction of fossil feedstocks, in favor of renewable ones. Biomasses are the most accessible source of organic precursors, having as advantage their low cost and even distribution across the globe. Unfortunately, they are intrinsically inhomogeneous in nature and their efficient exploitation requires novel catalysts. In this process, an accurate design of the active phase performing the reaction is important; nevertheless, we are often neglecting the importance of the support in guaranteeing stable performances and improving catalytic activity. This review has the goal of gathering and highlighting the cases in which the supports (either derived or not from biomass wastes) share the worth of performing the catalysis with the active phase, for those reactions involving the synthesis of fine chemicals starting from biomasses as feedstocks. Full article
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18 pages, 4074 KiB  
Review
Dendrimeric Structures in the Synthesis of Fine Chemicals
by Bruno Mattia Bizzarri, Angelica Fanelli, Lorenzo Botta, Claudio Zippilli, Silvia Cesarini and Raffaele Saladino
Materials 2021, 14(18), 5318; https://0-doi-org.brum.beds.ac.uk/10.3390/ma14185318 - 15 Sep 2021
Cited by 2 | Viewed by 1703
Abstract
Dendrimers are highly branched structures with a defined shape, dimension, and molecular weight. They consist of three major components: the central core, branches, and terminal groups. In recent years, dendrimers have received great attention in medicinal chemistry, diagnostic field, science of materials, electrochemistry, [...] Read more.
Dendrimers are highly branched structures with a defined shape, dimension, and molecular weight. They consist of three major components: the central core, branches, and terminal groups. In recent years, dendrimers have received great attention in medicinal chemistry, diagnostic field, science of materials, electrochemistry, and catalysis. In addition, they are largely applied for the functionalization of biocompatible semiconductors, in gene transfection processes, as well as in the preparation of nano-devices, including heterogeneous catalysts. Here, we describe recent advances in the design and application of dendrimers in catalytic organic and inorganic processes, sustainable and low environmental impact, photosensitive materials, nano-delivery systems, and antiviral agents’ dendrimers. Full article
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