materials-logo

Journal Browser

Journal Browser

Corrosion Behaviors of Metallic Materials in Extreme Environments

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Metals and Alloys".

Deadline for manuscript submissions: closed (30 April 2023) | Viewed by 4514

Special Issue Editor


E-Mail Website
Guest Editor
School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, China
Interests: environmental degradation of nuclear materials; stress corrosion cracking; oxidation; crack initiation; grain boundary migration; crack tip; irradiation damage; irradiation assisted stress corrosion cracking

Special Issue Information

Dear Colleagues,

The challenges for structure materials in hostile environments have been baffling the development of many important industrial fields such as nuclear energy. In addition to acceptable mechanical properties, the compatibility with the environments is also a crucial requirement for the structure materials. In current light water reactors, the coolant, i.e. high temperature water, is hostile enough for many structure materials. As the nuclear reactor is being developed to the next generation, the service environment for materials will inevitably get harsher and even go to extreme. For example, the typical coolants used in generation Ⅳ reactor are supercritical water, high temperature gas, supercritical CO2, liquid metal and molten salt. Not only will the ranges of operating temperature and the irradiation damage accumulated in materials greatly expand, but also the corrosiveness of environment will be drastically aggravated. These extreme environments pose great challenges to the materials available at present and demand the development of advanced structure material.

Metallic materials are still the basis for the implement of advanced reactors. Great research efforts have been made worldwide to develop metallic materials suitable for use in those extreme environments. In particular, high entropy alloys (HEAs) show some promising features such as high resistances to irradiation damage and corrosion. Additively manufactured materials have also received intensive attention due to the efficiency in manufacturing complex component as well as enhanced performance.

This special issue aims to compile recent progress in the corrosion behaviors of metallic materials in extreme environments (not limited to the above-mentioned coolants). The topic covers general corrosion, localized corrosion, oxidation, stress corrosion cracking, liquid metal embrittlement, and irradiation-assisted corrosion. Articles about corrosion test technique and corrosion simulation are also encouraged.

Prof. Dr. Wenjun Kuang
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • metallic material
  • high-entropy alloys
  • additive manufacturing
  • oxidation
  • stress corrosion cracking
  • irradiation-assisted corrosion
  • liquid metal embrittlement
  • extreme environments
  • nuclear energy

Published Papers (2 papers)

Order results
Result details
Select all
Export citation of selected articles as:

Research

Jump to: Review

12 pages, 5606 KiB  
Article
Crevice Corrosion Behavior of Alloy 690 in High-Temperature Aerated Chloride Solution
by Fangqiang Ning, Jibo Tan, Ziyu Zhang, Xiang Wang, Xinqiang Wu, En-Hou Han and Wei Ke
Materials 2022, 15(15), 5434; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15155434 - 07 Aug 2022
Cited by 3 | Viewed by 1245
Abstract
Crevice corrosion behavior of Alloy 690 in high-temperature aerated chloride solution was studied using a self-designed crevice device. The SEM, EDS, XRD, and XPS analyses results indicated that the oxide films outside the crevice consisted of Ni-Cr oxides containing a small amount of [...] Read more.
Crevice corrosion behavior of Alloy 690 in high-temperature aerated chloride solution was studied using a self-designed crevice device. The SEM, EDS, XRD, and XPS analyses results indicated that the oxide films outside the crevice consisted of Ni-Cr oxides containing a small amount of hydroxides, and the oxide films on crevice mouth consisted of a (Ni,Fe)(Fe,Cr)2O4 spinel oxides outer layer and a Cr(OH)3 inner layer, and the oxide films inside the crevice consisted of a α-CrOOH outer layer and a Cr(OH)3 inner layer. When crevice corrosion occurred, the hydrolysis of Cr3+ led to the formation of Cr(OH)3 inside the crevice, and caused the pH value of crevice solution to decrease, and Cl migrated from outside the crevice into inside the crevice due to electrical neutrality principle and accumulation. When the water chemistry inside the crevice reached the critical value of active dissolution of metal, the active dissolution of metal inside the crevice occurred. In addition, (Ni,Fe)(Fe,Cr)2O4 spinel oxides on the crevice mouth were formed by the deposition of metal ions migrated from inside the crevice. The mechanism of crevice corrosion and the formation mechanism of oxide films at different regions were also discussed. Full article
(This article belongs to the Special Issue Corrosion Behaviors of Metallic Materials in Extreme Environments)
Show Figures

Figure 1

Review

Jump to: Research

35 pages, 13370 KiB  
Review
Corrosion Behaviors of Heat-Resisting Alloys in High Temperature Carbon Dioxide
by Liujie Yang, Hongchen Qian and Wenjun Kuang
Materials 2022, 15(4), 1331; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15041331 - 11 Feb 2022
Cited by 15 | Viewed by 2756
Abstract
The supercritical carbon dioxide Brayton cycle is a promising power conversion option for green energies, such as solar power and nuclear reactors. The material challenge is a tremendous obstacle for the reliable operation of such a cycle system. A large body of research [...] Read more.
The supercritical carbon dioxide Brayton cycle is a promising power conversion option for green energies, such as solar power and nuclear reactors. The material challenge is a tremendous obstacle for the reliable operation of such a cycle system. A large body of research indicates that high-temperature corrosion of heat-resisting alloys by CO2 results in severe oxidation and, in many cases, concurrent internal carburization. This paper mainly reviews the oxidation behavior, carburization behavior and stress corrosion behavior of heat-resisting alloys in high temperature CO2. Specifically, the main factors affecting the oxidation behavior of heat-resistant alloys, such as environmental parameters, surface condition and gaseous impurity, are discussed. Then, carburization is explored, especially the driving force of carburization and the consequences of carburization. Subsequently, the effects of the environmental parameters, alloy type and different oxide layers on the carburizing behavior are comprehensively reviewed. Finally, the effects of corrosion on the mechanical behavior and stress corrosion cracking behavior of heat-resisting alloys are also summarized. The corrosion performances of heat-resisting alloys in high temperature CO2 are systematically analyzed, and new scopes are proposed for future material research. The information provided in this work is valuable for the development of structural material for the supercritical carbon dioxide Brayton cycle. Full article
(This article belongs to the Special Issue Corrosion Behaviors of Metallic Materials in Extreme Environments)
Show Figures

Figure 1

Back to TopTop