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Nanocomposites: Structure, Properties and Application

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Advanced Nanomaterials and Nanotechnology".

Deadline for manuscript submissions: closed (20 September 2023) | Viewed by 1139

Special Issue Editor


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Guest Editor
Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, 119991 Moscow, Russia
Interests: polymers; liquid crystals; nanoparticles; nanocomposites
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

This Special Issue is devoted to recent advances in nanocomposite research. The development of structural and functional nanocomposites is addressed in the context of different materials as well as their synthesis, properties, and functionality necessary for applications in different areas. The list of matrix materials to be considered contains polymers, ceramics, rubber, materials for organic photovoltaics, electrochemical materials, dyes, etc. As for fillers providing nanocomposite characteristics, we summarize semiconductor quantum dots, noble metals, metal oxides, carbon nanotubes, etc. Significant attention will be devoted to the physical and chemical properties of nanocomposites as well as their application, including devices of different kinds.

Prof. Dr. Raisa V. Talroze
Guest Editor

Manuscript Submission Information

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Keywords

  • polymer
  • liquid crystals
  • rubber
  • ceramics
  • nanostructures
  • nanoparticles
  • nanotubes
  • nanowires

Published Papers (2 papers)

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Research

14 pages, 11758 KiB  
Article
Fe-Co Alloy Nanoparticles Dispersed in Polymer-Derived Carbon Support: Effect of Initial Polymer Nature on the Size, Structure and Magnetic Properties
by Andrey Vasilev, Mikhail Efimov, Dmitry Muratov, Petr Chernavskii, Kirill Cherednichenko, Ella Dzidziguri and Galina Karpacheva
Materials 2023, 16(20), 6694; https://0-doi-org.brum.beds.ac.uk/10.3390/ma16206694 - 14 Oct 2023
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Abstract
Fe-Co alloy nanoparticles with different sizes, supported by carbon derived from several polymers, namely polyacrylonitrile, polyvinyl alcohol and chitosan, have been synthesized by a one-pot method involving simultaneous metal nanoparticle formation and polymer carbonization. The method involves the joint dissolution of metal salts [...] Read more.
Fe-Co alloy nanoparticles with different sizes, supported by carbon derived from several polymers, namely polyacrylonitrile, polyvinyl alcohol and chitosan, have been synthesized by a one-pot method involving simultaneous metal nanoparticle formation and polymer carbonization. The method involves the joint dissolution of metal salts and a polymer, followed by annealing of the resulting dried film. Detailed XRD analysis confirmed the formation of Fe-Co alloy nanoparticles in each sample, regardless of the initial polymer used. Transmission electron microscopy images showed that the Fe-Co nanoparticles were all spherical, were homogeneously distributed within the carbon support and varied by size depending on the initial polymer nature and synthesis temperature. Fe-Co nanoparticles supported by polyacrylonitrile-derived carbon exhibited the smallest size (6–12 nm), whereas nanoparticles on chitosan-derived carbon support were characterized by the largest particle size (13–38 nm). The size dependence of magnetic properties were studied by a vibrating sample magnetometer at room temperature. For the first time, the critical particle size of Fe-Co alloy nanoparticles with equiatomic composition has been experimentally determined as 13 nm, indicating the transition of magnetic properties from ferromagnetic to superparamagnetic. Full article
(This article belongs to the Special Issue Nanocomposites: Structure, Properties and Application)
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17 pages, 9784 KiB  
Article
Role of New Chiral Additives on Physical-Chemical Properties of the Nematic Liquid Crystal Matrix
by Alexey S. Merekalov, Oleg N. Karpov, Georgiy A. Shandryuk, Olga A. Otmakhova, Alexander V. Finko, Artem V. Bakirov, Vladimir S. Bezborodov and Raisa V. Talroze
Materials 2023, 16(17), 6038; https://0-doi-org.brum.beds.ac.uk/10.3390/ma16176038 - 02 Sep 2023
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Abstract
We have synthesized and studied three new chiral substances as additives to a nematic liquid crystal. The difference in the optical activity and chemical structure of additive molecules results in the appearance of the chiral nematic phase and the change in both the [...] Read more.
We have synthesized and studied three new chiral substances as additives to a nematic liquid crystal. The difference in the optical activity and chemical structure of additive molecules results in the appearance of the chiral nematic phase and the change in both the compatibility of the mixture components and temperature range of the liquid crystal phase. The role of additives with fundamentally different structures and optical activities is shown. The increase in the TNI that is observed in mixtures with 4-[(2S)-(+)-2-Methylbutoxy]benzoic acid indicate the possibility of the increase in order caused by the formation of molecularly rigid and elongated dimers of the additive, which was confirmed using infrared spectra. The doping of the nematic liquid crystal with (2R)-(+)-2-[4-[2-Chloro-4-(4-hexylphenyl)phenyl]phenoxy]propanoic acid causes the lowering of TNI. The binol derivative S-(+)-6-[1-[2-(5-Carboxypentoxy)naphthalen-1-yl]naphthalen-2-yl] oxyhexanoic acid has the highest chirality among the additives used. One can explain the effects observed in terms of the role of size, shape, and compatibility with the nematic matrix as shown by the molecules that are used as additives. Full article
(This article belongs to the Special Issue Nanocomposites: Structure, Properties and Application)
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