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Magnetic Methods in Metal–Organic Materials and Environmental Science

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Materials Physics".

Deadline for manuscript submissions: closed (31 December 2021) | Viewed by 5282

Special Issue Editors


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Department of Physics, Faculty of Mechanical Engineering, University of Technology and Humanities in Radom, Stasieckiego 54, 26-600 Radom, Poland
Interests: solid state physics; physics of magnetic materials
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Special Issue Information

Dear Colleagues,

In recent years, various magnetic methods typical for characterization of standard magnetics have been recognized as an efficient research tool in the case of many other groups of materials. These include, among others, intentionally synthesized organometallic compounds (usually based on iron) and industrial side-products (such as fly ashes, air-borne particulate matter, and street dusts), recognized not only as pollutants but also as potential recycling materials. Several questions are crucial and still not entirely understood, e.g.:

  • Thermal hysteresis of spin crossover in magneto-organic compounds;
  • Relation between spin crossover and the thermochromatic effect;
  • Circulation of technogenic magnetic particles in a natural environment;
  • Correlation between magnetic iron oxides concentration and heavy metal content.

In dealing with these problems, the magnetic methods—both standard and very specific—seem to be very helpful, such as thermal and frequency scanning of magnetic susceptibility, magneto-optics, magnetic hysteresis decomposition, Day–Dunlop diagrams, and first‐order reversal curve (FORC) analysis. Moreover, a very good supplement to magnetic methods is iron-based Mössbauer spectrometry.

This Special Issue of the Materials journal on "Magnetic Methods in Metalo-Organic Materials and Environmental Science" is intended to be a helpful guide in this comprehensive subject. It will comprise articles with fresh original results, reviews of recent research, short communications, as well as reports on industrial and environmental applications. The topics of submitted contributions can range from fundamental magnetic phenomena in metalo-organic materials and various kinds of environmental samples, via synthesis as well as advanced magnetic and spectroscopic characterization, up to innovative applications and recycling procedures.

Assoc. Prof. Tadeusz Szumiata
Prof. Roman Szewczyk
Guest Editors

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • Metal-organic materials
  • Magneto-organic compounds
  • Spin crossover
  • Thermochromatic effect
  • Technogenic magnetic particles
  • Environmental dusts and ashes
  • Magnetic hysteresis decomposition
  • FORC method
  • Mössbaurer spectrometry

Published Papers (2 papers)

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Research

10 pages, 1848 KiB  
Article
Application of Mössbauer Spectroscopy for Identification of Iron-Containing Components in Upper Silesian Topsoil Being under Industrial Anthropopressure
by Patrycja Kierlik, Aneta Hanc-Kuczkowska, Marzena Rachwał, Ryszard Męczyński and Izabela Matuła
Materials 2020, 13(22), 5206; https://0-doi-org.brum.beds.ac.uk/10.3390/ma13225206 - 18 Nov 2020
Cited by 5 | Viewed by 1705
Abstract
The main objective of the presented preliminary study was the identification of iron-containing phases. Iron-containing phases had accumulated in organic topsoil horizons collected from an area that has long been affected by the steel industry and emissions from power plants. X-ray diffraction and [...] Read more.
The main objective of the presented preliminary study was the identification of iron-containing phases. Iron-containing phases had accumulated in organic topsoil horizons collected from an area that has long been affected by the steel industry and emissions from power plants. X-ray diffraction and Mössbauer spectroscopy methods were used for the determination of the iron-containing mineral phases in topsoil subsamples which, after two-staged separation, varied in terms of magnetic susceptibility and granulometry. The Mössbauer spectra were recorded using paramagnetic and magnetic components, although the latter occurred only in the strongly magnetic fraction. The central part of spectra was fitted by two doublets (D1 and D2), which were identified as aluminosilicates. Simultaneously, the experimental spectra were described using several Zeeman sextets (Z1, Z2, and Z3) corresponding to the occurrence of hematite and magnetite-like phases with iron in tetrahedral and octahedral sites. Identification of magnetic phases in the tested material, including hematite, led to the conclusion that soil contamination in the studied area was presumably caused by emissions from a nearby power plant. Magnetite-like phases with a different iron content detected in topsoil samples could be related to metallurgical and coking processes, reflecting the specificity of the industrial area from which the samples were taken. The specific composition of the iron-containing aluminosilicates also illustrated the intense and long-lasting impact of the steel and coking industries on the studied area. Full article
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16 pages, 8392 KiB  
Article
Performance of Maraging Steel Sleeves Produced by SLM with Subsequent Age Hardening
by Piotr Tyczyński, Zbigniew Siemiątkowski, Piotr Bąk, Krzysztof Warzocha, Mirosław Rucki and Tadeusz Szumiata
Materials 2020, 13(15), 3408; https://0-doi-org.brum.beds.ac.uk/10.3390/ma13153408 - 02 Aug 2020
Cited by 8 | Viewed by 2771
Abstract
In the paper, the researches on sleeves made out of maraging steel 1.2709 using selective laser melting (SLM) technology are presented. This additive technology is recognized as favorable for the environment, due to 100% use of material and durability of manufactured details. The [...] Read more.
In the paper, the researches on sleeves made out of maraging steel 1.2709 using selective laser melting (SLM) technology are presented. This additive technology is recognized as favorable for the environment, due to 100% use of material and durability of manufactured details. The fabricated sleeves underwent subsequent tests, in particular, microhardness, porosity and homogeneity of the material was examined before and after heat treatment and salt bath nitrocarburizing process. Two kinds of fatigue tests were performed. The first consisted of the typical sinusoidal alternating load, the other was the high pressure pulse load test close to the real work conditions. It is of high importance that the fatigue strength of the tested sleeves is considerably higher than that of the similarly produced details shaped as a standard samples for tensile stress. The Mössbauer spectrometry analysis of hyperfine magnetic field distributions proved that SLM did not change considerably the martensite structure at atomic level. Full article
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