Geological and Mineralogical Control on the Environmental Risk of Potentially Toxic Elements in Mine Waste Heaps: A Risk Mitigation Perspective

A special issue of Minerals (ISSN 2075-163X). This special issue belongs to the section "Environmental Mineralogy and Biogeochemistry".

Deadline for manuscript submissions: closed (15 November 2022) | Viewed by 1884

Special Issue Editors


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Guest Editor
Department of Applied Chemistry, Szent István University, 1118 Budapest, Hungary
Interests: environmental geochemistry; toxic element contamination; contamination risk assessment; mine waste risk assessment; geochemical mapping; digital spatial and temporal modeling; monitoring
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Guest Editor
Hungarian University of Agriculture and Life Sciences, 2100 Godollo, Hungary
Interests: environmental analytical chemistry; elemental and speciation analysis of soil/water/atmosphere systems

Special Issue Information

Dear Colleagues,

Mining produces the second largest waste stream in the world. Modern mines, as well as abandoned mines, are responsible for significant environmental damage throughout the world and can pollute air and drinking water, harm wildlife and habitat, and permanently scar natural landscapes. Acid mine drainage carrying high concentrations of potentially toxic elements (PTEs) such as Pb, As, Cd, Zn and Ni is the primary source of water and soil pollution from mining. Acid mine drainage chemistry has been thoroughly studied and modelled with a view to developing treatment and remediation technology. The environmental risk of PTEs depends on their mobility: liberation from the weathering host primary minerals and capture by the precipitated secondary mineral phases. These processes have recently been received increasing attention in relation to the extreme weather conditions induced by climate change. The environmental risk of PTEs also depends on their form: their speciation to various pools and solid phases such as the labile exchangeable phase, the iron oxyhydroxide phase, or organic compounds. The due consideration of the rock and mineralogical conditions as PTE sources, and the proper view on climate-related weathering conditions, such as geo-environmental models, may offer risk mitigation solutions adaptable to site-specific conditions.

This Special Issue aims at bringing together state-of-the-art studies on PTE behavior in mine waste (waste rock and tailings) heaps whose focus is on the geological and mineralogical control on PTE mobility, liberation by weathering and deposition by secondary geochemical processes with a risk mitigation perspective under various climatic conditions and on effective remediation control.

Dr. Gyozo Jordan
Prof. Dr. Gyorgy Heltai
Guest Editors

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Keywords

  • mine waste
  • heavy metals
  • mineralogy
  • rock
  • potentially toxic elements
  • modelling
  • mobility
  • speciation
  • fractionation
  • remediation control

Published Papers (1 paper)

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Research

23 pages, 2200 KiB  
Article
A Study on the Possible Relationship between Physico-Chemical Properties of the Covering Soil and the Mobility of Radionuclides and Potentially Toxic Elements in a Recultivated Spoil Bank
by Márk Horváth, György Heltai, András Várhegyi and Lamlile Mbokazi
Minerals 2022, 12(12), 1534; https://0-doi-org.brum.beds.ac.uk/10.3390/min12121534 - 29 Nov 2022
Cited by 2 | Viewed by 1378
Abstract
This study is part of the ongoing environmental monitoring program of the abandoned Mecsek uranium mine. On the mine’s recultivated spoil deposit No. I, anomalies that refer to possible migration alongside the slope were detected. The present study was conducted to supplement the [...] Read more.
This study is part of the ongoing environmental monitoring program of the abandoned Mecsek uranium mine. On the mine’s recultivated spoil deposit No. I, anomalies that refer to possible migration alongside the slope were detected. The present study was conducted to supplement the ongoing monitoring study with a sampling strategy and analytical methods that can characterize the mobility of potentially toxic elements and radionuclides. A sampling strategy was developed: the vegetation and soil core samples were collected from the slope from top to bottom of the deposit, and nearby this spoil deposit, water samples were collected. Elemental analyses were conducted: the pseudo-total analysis, a total concentration of uranium in water, and the BCR sequential extraction analysis. The radionuclides were determined by gamma spectrometry and alphaGUARD. Additionally, the soil and plant moisture content, soil organic matter, pH, and cation exchange capacity (CEC) were determined. The Pearson correlation analysis and the principal component analysis, considering all possible influencing factors, verified that the elemental concentration increase from the top to the bottom direction of the deposit is strongly influenced by the soil pH, CEC, and Ca content. The mobility of Cd, Co, Mn, Pb, and U is relatively high and significantly migrates down the slope. Full article
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