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Progressive Materials and Methods in Voltammetric Analysis of Complex Samples

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Electrochemistry".

Deadline for manuscript submissions: closed (15 April 2021) | Viewed by 2646

Special Issue Editor


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Guest Editor
Electroanalytical Chemistry Laboratory, Department of Chemistry and Physics, Faculty of Education, Catholic University in Ružomberok, Hrabovská cesta 1, SK-034 01 Ružomberok, Slovakia
Interests: charge transfer characterization; electroanalysis; voltammetric sensors; microelectrode arrays; electrocatalysis; electrodes based on carbon structures

Special Issue Information

Dear Colleagues,

 The genial invention of polarography in 1922 by Czech electrochemist Jaroslav Heyrovský (Nobel prize in 1959) not only opened up various applications of electrochemical methods in analytical chemistry, but it also influenced all branches of chemistry. In the second half of the 20th century, it was observed that polarography is fully compatible with computers and information technologies, which allowed extremely fast data acquisition and current-potential dependence recording. This modification of polarography (voltammetry) is able to use stationary working electrodes from various solid materials, making it fully compatible also with nanotechnologies. These electrodes may be used as cheap, fast, and sensitive detectors, bringing information about content of certain analytes in samples from pharmacy, biology, and environment or from food and commercial product control. Voltammetric detection techniques have reasonably high selectivity, but in the case of complex samples, the selectivity and possibility to correctly determine the content of certain analytes could be a problem. However, in contemporary electroanalysis, many successful sensors and/or methodologies for highly sensitive and highly selective determination of important analytes in complex samples have been introduced using progressive electrode material and/or novel detection strategies.

I believe that those of you who contribute to this Special Issue will enhance the number of successful applications of voltammetric techniques in sensitive and highly selective determinations in complex samples.

Prof. Dr. Peter Tomčík
Guest Editor

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Molecules is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • voltammetric sensors, detection platform
  • complex matrix
  • graphene, carbon, diamond
  • biology, pharmacy, environment, food control, personal care, and commercial product control

Published Papers (1 paper)

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Review

12 pages, 936 KiB  
Review
Electroanalytical Techniques for the Detection of Selenium as a Biologically and Environmentally Significant Analyte—A Short Review
by Miroslav Rievaj, Eva Culková, Damiána Šandorová, Zuzana Lukáčová-Chomisteková, Renata Bellová, Jaroslav Durdiak and Peter Tomčík
Molecules 2021, 26(6), 1768; https://0-doi-org.brum.beds.ac.uk/10.3390/molecules26061768 - 22 Mar 2021
Cited by 6 | Viewed by 2215
Abstract
This short review deals with the properties and significance of the determination of selenium, which is in trace amounts an essential element for animals and humans, but toxic at high concentrations. It may cause oxidative stress in cells, which leads to the chronic [...] Read more.
This short review deals with the properties and significance of the determination of selenium, which is in trace amounts an essential element for animals and humans, but toxic at high concentrations. It may cause oxidative stress in cells, which leads to the chronic disease called selenosis. Several analytical techniques have been developed for its detection, but electroanalytical methods are advantageous due to simple sample preparation, speed of analysis and high sensitivity of measurements, especially in the case of stripping voltammetry very low detection limits even in picomoles per liter can be reached. A variety of working electrodes based on mercury, carbon, silver, platinum and gold materials were applied to the analysis of selenium in various samples. Only selenium in oxidation state + IV is electroactive therefore the most of voltammetric determinations are devoted to it. However, it is possible to detect also other forms of selenium by indirect electrochemistry approach. Full article
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