The Structure and Properties of Polymer Blends and Their Applications

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Analysis and Characterization".

Deadline for manuscript submissions: closed (10 April 2022) | Viewed by 7886

Special Issue Editor


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Guest Editor
Department of Chemical Engineering, Tsinghua University, Beijing, China
Interests: polymer blends; melt grafting of polymers; nanocomposites; recycling and value-added reuse of plastics; super tough hydrogels; confined crystallization of polymers
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Special Issue Information

Dear Colleagues,

The field of polymer blends has led the development of polymer materials and expanded significantly in the last several decades. Their potential applications are ever-growing, especially in the recycling of polymer materials. To highlight the recent advances in this field and the significant contributions that chemists around the world have made in these areas, Polymers is publishing a Special Issue called “The Structure and Properties of Polymer Blends and Their Applications”.

It is our pleasure to invite you to submit a communication, full paper, or minireview to this Special Issue. We would be delighted if you could accept this invitation and would be grateful if you could let us know, at your earliest convenience, if you plan to contribute to this collection.

We look forward to hearing from you soon. 

With kind regards,

Dr. Xu-Ming Xie
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Polymers is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • polymer blends
  • structure
  • property
  • recycling
  • compatibilizer
  • high performance
  • phase morphology

Published Papers (2 papers)

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Research

19 pages, 4226 KiB  
Article
Thermal and Rheological Characterization of Recycled PET/Virgin HDPE Blend Compatibilized with PE-g-MA and an Epoxy Chain Extender
by Raquel M. Santos, Anna R. M. Costa, Yêda M. B. Almeida, Laura H. Carvalho, João M. P. Q. Delgado, Elisiane S. Lima, Hortência L. F. Magalhães, Ricardo S. Gomez, Boniek E. Leite, Fagno D. Rolim, Maria J. Figueiredo and Antonio G. B. Lima
Polymers 2022, 14(6), 1144; https://0-doi-org.brum.beds.ac.uk/10.3390/polym14061144 - 12 Mar 2022
Cited by 6 | Viewed by 3368
Abstract
In this work, recycled poly(ethylene terephthalate) (PETR) was blended with virgin high-density polyethylene (HDPE) in an internal mixer in an attempt to obtain a material with improved properties. A compatibilizer (PE-g-MA) and a chain extender (Joncryl) were added to the PETR/HDPE blend and [...] Read more.
In this work, recycled poly(ethylene terephthalate) (PETR) was blended with virgin high-density polyethylene (HDPE) in an internal mixer in an attempt to obtain a material with improved properties. A compatibilizer (PE-g-MA) and a chain extender (Joncryl) were added to the PETR/HDPE blend and the rheological and thermal properties of the modified and unmodified blends as well as those of virgin PET with virgin HDPE (PETV/HDPE). All the blends were characterized by torque rheometry, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The data obtained indicate that the incorporation of either the chain extender or the compatibilizer agent led to increases in torque (and hence in viscosity) of the blend compared to that of the neat polymers. The joint incorporation of the chain extender and compatibilizer further increased the viscosity of the systems. Their effect on the crystallinity parameters of HDPE was minimal, but they reduced the crystallinity and crystallization temperature of virgin and recycled PET in the blends. The thermal stability of the PETR/HDPE blend was similar to that of the PETV/HDPE blend, and it was not affected by the incorporation of the chain extender and/or compatibilizer. Full article
(This article belongs to the Special Issue The Structure and Properties of Polymer Blends and Their Applications)
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13 pages, 2888 KiB  
Article
Experimental Determination of Molecular Weight-Dependent Miscibility of PBAT/PLA Blends
by Shen Su, Rodion Kopitzky and Christian Berrenrath
Polymers 2021, 13(21), 3686; https://0-doi-org.brum.beds.ac.uk/10.3390/polym13213686 - 26 Oct 2021
Cited by 7 | Viewed by 3419
Abstract
Blends of poly(butylene adipate-co-terephthalate) (PBAT) and polylactide (PLA) have attracted the attention of academia and industry as a sustainable material. Unfortunately, this combination results in problems related to poor miscibility on the molecular level. This study mainly aims to determine the [...] Read more.
Blends of poly(butylene adipate-co-terephthalate) (PBAT) and polylactide (PLA) have attracted the attention of academia and industry as a sustainable material. Unfortunately, this combination results in problems related to poor miscibility on the molecular level. This study mainly aims to determine the influence of molecular weights on the miscibility of PBAT/PLA blends. First, polymers with various molecular weights were obtained by the hydrolysis of PBAT and methanolysis of PLA. Second, the two components were solution-blended with different molecular weights and weight ratios. Third, each blend was heated to the molten state and subsequently stored at room temperature. Finally, the samples were tested using DSC and SEM. The thermal analysis indicated that the difference in glass transition temperature between both components decreased from about 91 °C to 57 °C and 0 °C, as the number-average molecular weights (Mn) decreased from 52/127 to 9.4/9 and 6.3/6.6 kg/mol. Moreover, the morphology changed from phase-separated with dispersed large particles gradually to uniform and homogeneous. This experimental work validated the trends predicted in the previous study, namely that PBAT/PLA blends changed the state from immiscible to partially miscible to fully miscible with decreasing Mn values. Moreover, we discussed the influencing factors such as weight ratio, temperature, and molecular structure on the miscibility. Based on the results, this work contributes to developing partially miscible and compatible blends without additives. Full article
(This article belongs to the Special Issue The Structure and Properties of Polymer Blends and Their Applications)
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