Polymer Foams: Relationship between Structure and Properties

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Processing and Engineering".

Deadline for manuscript submissions: closed (30 November 2021) | Viewed by 2606

Special Issue Editor


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Guest Editor
1. CellMat Technologies SL, Edificio Parque Científico-UVa. Paseo de Belen 9-A, 47011, Valladolid, Spain
2. Cellular Materials Laboratory (CellMat), Universidad de Valladolid, 47011 Valladolid, Spain
Interests: structure-properties relationship in polymeric foams; foaming processes; development of advanced materials; polyolefin-based foams; multifunctional foams; tailored formulations; foamability

Special Issue Information

Dear Colleagues,

The analysis of the structure–properties relationship of polymeric foams is one of the pillars of understanding the performance of these outstanding materials and encourage the production and development of novel and advanced polymeric foams and foaming processes.

The structure and the properties of cellular materials are the consequence of two main factors: the base formulation (i.e., chemical composition) and the foaming process employed to generate the material. The characteristics of the formulation, mainly its foamability, determine, for a specific foaming process, the density that it is possible to achieve, and condition the morphology of the cellular structure. On the other hand, at a fixed target density and formulation, the selected foaming technology plays a vital role in the morphology of the cellular structure and, therefore, in the properties of the obtained materials.

The interconnection between all these relevant aspects makes it necessary to deepen the understanding of the relationship between the structure and the properties of cellular materials and how they both relate to the chemical composition of the material and the selected processing technologies.

The analysis of the structure–properties relationship is critical for any new development in terms of polymeric matrices, additives, blowing agents, foaming processes, or analytical models accounting for the performance of foams.

Facing the challenges defined by the end-users surrounding the main fields of applications of cellular materials requires a strong commitment regarding this particulartopic. Therefore, this Special Issue aims to contribute to the connection between the structure and properties of different types of polymeric foams and how they relate to other relevant aspects, such as their chemical composition or the selected foaming process. 

Dr. Cristina Saiz-Arroyo
Guest Editor

Keywords

  • Structure–properties relationship
  • Density
  • Foaming processes
  • Foamability
  • Mechanical properties
  • Thermal properties
  • Acoustic properties
  • Cellular structure
  • Polymeric foams

Published Papers (1 paper)

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Research

13 pages, 6611 KiB  
Article
In-Situ Visualization of the Cell Formation Process of Foamed Polypropylene under Different Foaming Environments
by Rong Deng, Tuanhui Jiang, Chun Zhang, Xiangbu Zeng, Bujin Liu, Jingkui Yang, Shengnan Li, Jun Gu, Wei Gong and Li He
Polymers 2021, 13(9), 1468; https://0-doi-org.brum.beds.ac.uk/10.3390/polym13091468 - 01 May 2021
Cited by 7 | Viewed by 2130
Abstract
In this paper, the dynamic foaming process of micro-foaming polypropylene (PP) in different foaming environments in real time was obtained via a visualization device. The relationship curve between cell number (n) and foaming time (t) was plotted, and then [...] Read more.
In this paper, the dynamic foaming process of micro-foaming polypropylene (PP) in different foaming environments in real time was obtained via a visualization device. The relationship curve between cell number (n) and foaming time (t) was plotted, and then the nucleation kinetics of foam cells was analyzed. Results showed that the formation rate of cells changed obviously with the variation of melt temperature and the content of the foaming agent. The n-t curves presented a typical “S” shape, which indicated that the appearance of the cell number increased slowly in the initial foaming period, then increased rapidly in a short time, and finally maintained a certain value. When a certain pressure was applied to the PP melt, the external force had a great influence on the n-t curve. With the increasing external force, the rate of cell formation increased rapidly, and the shape of the n-t curve changed from “S” to “semi-S” without an obvious slow increase. The investigation of the n-t relationship in the PP dynamic foaming process under different foaming environments could provide effective bases for improving the foaming quality of injection molding foaming materials. Full article
(This article belongs to the Special Issue Polymer Foams: Relationship between Structure and Properties)
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