Organics, Volume 1, Issue 1 (December 2020) – 5 articles
Cover Story (view full-size image): New discoveries require a fundamental revision of the view on the mechanism of the 32CAreaction (according to the older nomenclature defined as 1,3-dipolar cycloaddition reactions). The view of the one-step, “concerted” mechanism of such processes developed in the 20th century is extremely popular today, both in academic literature and among organic chemists who do not specialize in such transformations. Meanwhile, more and more reports bring examples of reactions that clearly cannot be treated as processes without intermediates. Our work is a critical analysis of these cases. We dedicate this work to rats in whose rescue the community of our team is involved. View this paper.
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