Innovative Hydrothermal Systems to Valorize Agricultural Residuals for Sustainable Crop Production and Environmental System

A special issue of Agronomy (ISSN 2073-4395).

Deadline for manuscript submissions: 30 September 2024 | Viewed by 4401

Special Issue Editors


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Guest Editor
Soil and Water Quality Management, Red River Research Station, LSU AgCenter, Bossier City, LA 71112, USA
Interests: nonpoint source pollution; greenhouse gas emission; biochar/hydrochar
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Department of Civil and Environmental Engineering, University of South Carolina, 300 Main Street, Columbia, SC 29208, USA
Interests: improving our understanding of how physical, chemical, and biological processes can be manipulated to promote sustainable waste treatment techniques that lead to carbon sequestration, energy generation, and/or value-added product production

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Guest Editor
Department of Chemistry, Seoul Women's University, 621, Hwarang-ro, Nowon-gu, Seoul 01797, Republic of Korea
Interests: hydrothermal carbonization; biomass conversion; development of analytical methods for trace analysis; hydrochar applications

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Guest Editor
Leibniz-Institut für Agrartechnik und Bioökonomie e.V. (ATB), Potsdam, Germany
Interests: thermochemical conversion technologies; applications of biochar and hydrochar; cascading use of agricultural residues

Special Issue Information

Dear Colleagues,

Current global challenges in agriculture include sustainably producing crops and livestock while mitigating greenhouse gas emissions, recycling nutrients, and increasing soil fertility. A key strategy to meet these challenges is the propagation of thermochemical conversion technologies for the cascading use of agricultural residues to return carbon and nutrients to soils for long-term storage and mitigation of environmental pollution. Considerable research indicates that hydrothermal carbonization (HTC) technologies are an excellent selection for serving these goals. The HTC technologies have the potential to replenish nutrients, restore soil health, improve water quality, and increase agricultural production through the utilization of agricultural, municipal, and industrial byproducts. However, there is a lack of guidance on using the HTC derived from different feedstocks, conversion temperature, heating rate, and residence time for achieving both carbon sequestration and crop yield improvement. Although research related to HTC technologies has been increasing yearly, most HTC research has not been organized comprehensively to cover a wide range of conditions. The aim of the Special Issue will cover the fundamental and application research on the various feedstocks and processing conditions and demonstrate the field application of HTC products to document the beneficial effect of HTC technologies on soil carbon sequestration, improvement of crop production, and mitigation of environmental pollution.

Dr. Changyoon Jeong
Prof. Dr. Nicole Berge
Prof. Dr. Sunyoung Bae
Dr. Kyoung S. Ro
Dr. Judy Ann Libra
Guest Editors

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Keywords

  • hydrothermal carbonization
  • carbon sequestration
  • environmental pollution
  • sustainable agriculture
  • greenhouse gas emission
  • water quality
  • recycling biomass
  • carbon-based materials

Published Papers (4 papers)

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Research

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26 pages, 2365 KiB  
Article
Business and Market Analysis of Hydrothermal Carbonization Process: Roadmap toward Implementation
by Gianluigi Farru, Fabiano Bisinella Scheufele, Daniela Moloeznik Paniagua, Fritz Keller, Changyoon Jeong and Daniele Basso
Agronomy 2024, 14(3), 541; https://0-doi-org.brum.beds.ac.uk/10.3390/agronomy14030541 - 07 Mar 2024
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Abstract
This study assesses the status of hydrothermal carbonization (HTC) technology and identifies barriers hindering its commercial viability. Conducting a global survey among HTC companies (with a total of 24 surveys sent), the research evaluates the current landscape, challenges, and future prospects of large-scale [...] Read more.
This study assesses the status of hydrothermal carbonization (HTC) technology and identifies barriers hindering its commercial viability. Conducting a global survey among HTC companies (with a total of 24 surveys sent), the research evaluates the current landscape, challenges, and future prospects of large-scale HTC operations. Furthermore, it presents a detailed global inventory of existing HTC facilities, illustrating geographical distribution and trends in application. Most of the companies are located in Europe, followed by Asia and North America. With substantial participation from HTC companies, exceeding 62% in the survey (15 companies), the study provides a comprehensive overview of diverse companies, their business models, regulatory challenges, and the overall state of HTC technology. The majority of companies in this study, approximately 80%, offer services in the field of waste management. This paper also explores the potential of HTC in transforming waste management practices, carbon sequestration methodologies, and the development of new materials. Employing a thorough SWOT analysis, the paper advocates for a broader adoption of HTC, emphasizing its transformative capacity in fostering sustainable management of urban, industrial, and agricultural residues, promoting circular economy principles, mitigating climate change, and offering a robust foundation for informed decision-making and sustainable development strategies. Full article
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23 pages, 2295 KiB  
Article
Enhancing Fuel Properties of Napier Grass via Carbonization: A Comparison of Vapothermal and Hydrothermal Carbonization Treatments
by Daniela Moloeznik Paniagua, Judy A. Libra, Vera Susanne Rotter, Kyoung S. Ro, Marcus Fischer and Julia Linden
Agronomy 2023, 13(12), 2881; https://0-doi-org.brum.beds.ac.uk/10.3390/agronomy13122881 - 23 Nov 2023
Cited by 2 | Viewed by 1094
Abstract
Napier grass is a herbaceous biomass that can be used as biofuel; however, its high ash, potassium, sulfur and chlorine content may cause problems when combusted. Napier grass was submitted to vapothermal carbonization (VTC) and hydrothermal carbonization (HTC) processes at 190 and 220 [...] Read more.
Napier grass is a herbaceous biomass that can be used as biofuel; however, its high ash, potassium, sulfur and chlorine content may cause problems when combusted. Napier grass was submitted to vapothermal carbonization (VTC) and hydrothermal carbonization (HTC) processes at 190 and 220 °C to compare their ability to enhance its fuel properties. The different water distribution between phases in the two processes was verified: up to 14.5% of the water vaporized to steam in the VTC ran at 220 °C, while over 99% of the water remained in the liquid state and in contact with the solids during all HTC runs. Both processes improved the calorific value of the Napier grass (up to 20.6% for VTC220 and up to 29.8% for HTC220) due to the higher C content in the chars. Both processes reduced the sulfur content, removing up to 15.3% of it with VTC190 and 28.5% of it with HTC190 compared to that of Napier grass. In contrast, the two processes had different effects on the ash and chlorine content. While HTC removed both ash and Cl from the Napier grass, VTC concentrated it in the chars (ash: 5.6%wt. Napier grass, 3.3%wt. HTC chars, 7.1%wt. VTC; chlorine: 1.08%wt. Napier grass, 0.19%wt. HTC chars, 1.24%wt. VTC). Only the HTC process leached high percentages of Cl (up to 80%), S (up to 70%), sodium (Na, up to 80%) and potassium (K, up to 90%) into the process water. This may prevent fouling and slagging problems when burning HTC char. The biofuel qualities of the raw Napier grass, VTC, and HTC chars were evaluated using two standards: the international standard for solid biofuels, EN ISO 17225, and the Korean regulation for biomass solid recovered fuels (Bio-SRF). Napier grass and VTC chars presented problems regarding Cl content thresholds for both EN ISO 17225 and Bio-SRF. Both VTC and HTC chars along with the Napier grass fulfilled the requirements for heavy metals (Pb, Ni, Cr, and Cd) except for copper. The choice of process in practical applications will depend on the goal; HTC improves fuel quality and VTC has higher high solid, carbon and energy yields. Full article
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Review

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39 pages, 1403 KiB  
Review
Research Needs and Pathways to Advance Hydrothermal Carbonization Technology
by Chau Huyen Dang, Giovanna Cappai, Jae-Wook Chung, Changyoon Jeong, Beatrice Kulli, Filippo Marchelli, Kyoung S. Ro and Silvia Román
Agronomy 2024, 14(2), 247; https://0-doi-org.brum.beds.ac.uk/10.3390/agronomy14020247 - 24 Jan 2024
Cited by 1 | Viewed by 1056
Abstract
Hydrothermal carbonization (HTC) is a proven cost-effective and energy-efficient method for waste management and value-added product recovery. There are, however, several issues that require further improvement or research. Identifying the strengths and weaknesses of HTC in comparison to traditional pyrolysis is crucial for [...] Read more.
Hydrothermal carbonization (HTC) is a proven cost-effective and energy-efficient method for waste management and value-added product recovery. There are, however, several issues that require further improvement or research. Identifying the strengths and weaknesses of HTC in comparison to traditional pyrolysis is crucial for scientists to choose between them or use both (complementary) to achieve specific product properties. Additionally, sharing information on diverse modeling approaches and scales is crucial to enhance the robustness and universality of HTC process models. In addition, the study on the applicability of hydrochars on target applications such as soil amendment is crucial to give back nutrients to soils and face the dependence on finite specific feedstocks in this field. Also, proper management of the process by-products, especially process water, must be addressed to improve the carbon and hydric footprint of the process. Reviewing the suitability of HTC to treat specific challenging wastes, whose strength is not related to their calorific value but to their nutrient composition (i.e., manures), is also an appealing topic for HTC research. This paper aims to tackle the above-mentioned issues through an updated review and discussion of research gaps that require further investigation. Full article
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18 pages, 2710 KiB  
Review
Life Cycle Assessment of Hydrothermal Carbonization: A Review of Product Valorization Pathways
by Andrea Ogunleye, Joseph Flora and Nicole Berge
Agronomy 2024, 14(2), 243; https://0-doi-org.brum.beds.ac.uk/10.3390/agronomy14020243 - 24 Jan 2024
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Abstract
Hydrothermal carbonization (HTC) has the potential to be a sustainable and environmentally beneficial approach for organic waste treatment. It is likely that HTC product use will dictate the viability of large-scale HTC facilities; therefore, understanding the viability and environmental implications associated with HTC [...] Read more.
Hydrothermal carbonization (HTC) has the potential to be a sustainable and environmentally beneficial approach for organic waste treatment. It is likely that HTC product use will dictate the viability of large-scale HTC facilities; therefore, understanding the viability and environmental implications associated with HTC product valorization pathways is critical. The overall goal of this review is to gain an understanding of how HTC product valorization is currently being modeled in life cycle assessment studies, and to use such information to assess current research and/or data needs associated with product valorization. To accomplish this, a review of existing HTC literature was conducted and used to assess the current state of knowledge surrounding the environmental implications of HTC product use. From this review of the literature, it is clear that potential exists for HTC product valorization. To realize this potential in a full-scale application, research gaps and data needs were identified that included a system-level integration to evaluate location-specific information as well as more extensive characterization of the impact of HTC product properties on valorization impacts. Full article
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