Advances in Methanol Production from Biomass

A special issue of Applied Sciences (ISSN 2076-3417). This special issue belongs to the section "Chemical and Molecular Sciences".

Deadline for manuscript submissions: closed (15 June 2019) | Viewed by 4978

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Dipartimento di Chimica, Università degli Studi di Milano, 20133 Milano, Italy
Interests: heterogeneous catalysis; process simulation; environmental chemistry; separations; scale-up; photocatalysis
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Guest Editor
Dipartimento di Chimica, Università degli Studi di Milano, 20133 Milano, Italy
Interests: catalysis; environmental chemistry; process simulation; distillation; life cycle assessment; photocatalysis

Special Issue Information

 Dear Colleagues,

One of the biggest challenges today is to realize new chemical processes that are sustainable both from an economic and environmental point of view for the production of basic materials starting from renewable resources. Biomass utilization to produce chemicals and energy vectors represents the most appealing way to reduce the use of fossil resources and decrease pollution and the green-house effect.

In particular, methanol is a key compound as a building block in chemical industry, as an energy vector, and as fuel. Traditional fossil raw materials, natural gas, and coal are nowadays the most used raw materials for the synthesis of this highly valuable compound.

Intensive research in academia and industry is devoted to the application of renewable biomass-based sources for methanol production. Methanol synthesis is a well-consolidated technology, but important improvements concerning new catalysts, new process configurations, new reactors, and new ideas are urgently required to solve all the practical problems arising from the use of biomass instead of fossil sources. The final cost of bio-methanol is, nowadays, not competitive with methanol produced from fossil sources.

In this context, we are pleased to announce an upcoming Special Issue entitled “Advances in Methanol Production from Biomass”. It our pleasure to invite you and members of your research team to submit original research or review papers for this Special Issue.

Potential topics for this Special Issue include, but are not restricted to, the following:

  • Innovative catalysts for methanol production
  • New synthetic procedures for catalysts synthesis
  • Kinetics and thermodynamic analysis involving biomass gasification and methanol production
  • Experimental data regarding methanol synthesis in the presence of CO2 and/or other impurities
  • Automatic control of water and wastewater treatment processes for nitrogen and/phosphorus
  • Economic analysis of methanol-from-biomass production, or of a specific, related unit operation
  • A Life Cycle Analysis (LCA) study concerning methanol production using traditional and innovative raw materials
  • Strategy for improving the sustainability of biomass transformation into methanol

Prof. Carlo Pirola
Dr. Federico Galli
Guest Editors

Manuscript Submission Information

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Keywords

  • methanol from biomass
  • catalysis and kinetics
  • process design and simulation
  • LCA
  • carbon dioxide

Published Papers (1 paper)

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Research

15 pages, 2282 KiB  
Article
Combination of Chemo- and Biocatalysis: Conversion of Biomethane to Methanol and Formic Acid
by Benny Kunkel, Dominik Seeburg, Tim Peppel, Matthias Stier and Sebastian Wohlrab
Appl. Sci. 2019, 9(14), 2798; https://0-doi-org.brum.beds.ac.uk/10.3390/app9142798 - 12 Jul 2019
Cited by 2 | Viewed by 4378
Abstract
In the present day, methanol is mainly produced from methane via reforming processes, but research focuses on alternative production routes. Herein, we present a chemo-/biocatalytic oxidation cascade as a novel process to currently available methods. Starting from synthetic biogas, in the first step [...] Read more.
In the present day, methanol is mainly produced from methane via reforming processes, but research focuses on alternative production routes. Herein, we present a chemo-/biocatalytic oxidation cascade as a novel process to currently available methods. Starting from synthetic biogas, in the first step methane was oxidized to formaldehyde over a mesoporous VOx/SBA-15 catalyst. In the second step, the produced formaldehyde was disproportionated enzymatically towards methanol and formic acid in equimolar ratio by formaldehyde dismutase (FDM) obtained from Pseudomonas putida. Two processing routes were demonstrated: (a) batch wise operation using free formaldehyde dismutase after accumulating formaldehyde from the first step and (b) continuous operation with immobilized enzymes. Remarkably, the chemo-/biocatalytic oxidation cascades generate methanol in much higher productivity compared to methane monooxygenase (MMO) which, however, directly converts methane. Moreover, production steps for the generation of formic acid were reduced from four to two stages. Full article
(This article belongs to the Special Issue Advances in Methanol Production from Biomass)
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