Nanotechnologies for Environmental Remediation

A special issue of Applied Sciences (ISSN 2076-3417). This special issue belongs to the section "Nanotechnology and Applied Nanosciences".

Deadline for manuscript submissions: closed (30 March 2019) | Viewed by 5657

Special Issue Editors


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Guest Editor
Department of Civil and Environmental Engineering, University of Delaware, Newark, DE 19716, USA
Interests: advanced oxidation; electrochemical processes; interfacial processes; environmental nanotechnology; aquatic chemistry
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Guest Editor
Center for Energy and Environmental Research and Institute of Analytical and Environmental Sciences, National Tsing Hua University, 101, Section 2, Kuang Fu Road, Hsinchu 300, Taiwan
Interests: heterogeneous photoelectrocatalysis; environmental nanomaterials; water-energy nexus; low-dimensional carbon nanomaterials; porous nanomaterials; nanosensing devices; energy storage nanomaterials.
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Guest Editor
Department of Marine Environmental Engineering, National Kaohsiung University of Science and Technology, Kaohsiung City, Taiwan
Interests: water and wastewater management; aquatic and soil chemistry; soil and sediment remediation; nanomaterials for environmental applications
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Guest Editor
Research Centre of Eco-Environmental Science, Chinese Academy of Sciences, Beijing, China
Interests: adsorption, coagulation, and electro-chemical technologies for water treatment

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Guest Editor
College of Environment, Nanjing University, Nanjing, China
Interests: applied environmental nanomaterials and technology; advanced oxidation reduction technology; industrial waste management and resource recovery

Special Issue Information

Dear Colleagues,

Engineered nanomaterials (ENPs)-based environmental technologies have become increasingly competitive and, thus, important for the remediation of impaired environmental systems, namely, water, soil, and air. There have been many advances on the principles and applications of photocatalytic degradation of hazardous organic chemicals using nan-sized TiO2 since the early 1970s. Catalysts and electrodes made of nano-size particles have been around, and applied, in many industrial fields’ centuries before instruments were available for their direct observation. Environmental applications of nanomaterials and technologies, although potentially promising and feasible, generally fall behind other industries, mostly due to social–political and legal issues.

In order to achieve sustainability within the framework of environment and energy nexus, nanomaterials and nanotechnology will play the foremost role. The millennium agenda of global sustainability has arrived with excellent opportunities for the deployment and its ultimate implementation of nanotechnologies for environmental remediation. Nanomaterials require small amounts of raw materials, have unique and much enhanced surface reactivities and selectivities, and robust in-system design and operations. These are excellent attributes, and opportunities as well, for environmental remediation nanotechnologies.

Several thematic topics are of interest to this Special Issue: 1) past experiences on the design and operation of nanotechnology for the remediation of impaired water, polluted air, contaminated soil and sediment; 2) current advances on the developments and implementation of environmental nanotechnology in broader definitions; 3) new concepts and strategies on the design of “smart” nanomaterials and systems integration achieving high efficiency and high selectivity, in the separation and transformation of ions, molecules, and emerging contaminants from impacted natural and built environmental systems; 4) environmental impacts of nanomaterials and nanotechnology; and 5) devices applying nanomaterials and principles of nanotechnology for environmental sensing and monitoring. Specifically, the Special Issue welcomes manuscripts covering the following subjects: Processes and engineering applications of nanotechnologies for the treatment of impaired water, polluted air, contaminated soils and sediments; electrochemical processes applying nanocatalytic electrode materials; heterogeneous nanophotocatalysis; multiple-functional nanoadsorbents and nanocatalysts; photo-electrochemical processes; nanomembranes; environmental nanosensors; environmental implications; and impacts of nanaomaterials.

Prof. Dr. Chin-pao (C. P.) Huang
Prof. Dr. Ruey-An Doong
Prof. Dr. Cheng-Di Dong
Prof. Dr. Huijuan Liu
Prof. Dr. Bingcai Pan
Guest Editors

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Keywords

  • high-performing electrode materials
  • mutli-functional nanocomposite
  • electrochemical separation/purification
  • photoelectrochemical purification/separation
  • adsorption purification/separation
  • nanomembrane purification/separation
  • separation and purification
  • biosensors and nanosensing
  • ecological nanotoxicity
  • environmental remediation

Published Papers (1 paper)

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Research

15 pages, 3766 KiB  
Article
Carbon Dioxide Adsorption on Porous and Functionalized Activated Carbon Fibers
by Yu-Chun Chiang, Cheng-Yu Yeh and Chih-Hsien Weng
Appl. Sci. 2019, 9(10), 1977; https://0-doi-org.brum.beds.ac.uk/10.3390/app9101977 - 14 May 2019
Cited by 73 | Viewed by 5100
Abstract
Polyacrylonitrile-based activated carbon fibers (ACFs), modified using potassium hydroxide (KOH) or tetraethylenepentamine (TEPA), were investigated for carbon dioxide (CO2) adsorption, which is one of the promising alleviation approaches for global warming. The CO2 adsorption isotherms were measured, and the values [...] Read more.
Polyacrylonitrile-based activated carbon fibers (ACFs), modified using potassium hydroxide (KOH) or tetraethylenepentamine (TEPA), were investigated for carbon dioxide (CO2) adsorption, which is one of the promising alleviation approaches for global warming. The CO2 adsorption isotherms were measured, and the values of isosteric heat of adsorption were calculated. The results showed that the KOH-modified ACFs exhibited a great deal of pore volume, and a specific surface area of 1565 m2/g was obtained. KOH activation made nitrogen atoms easily able to escape from the surface of ACFs. On the other hand, the surface area and pore volume of ACFs modified with TEPA were significantly reduced, which can be attributed to the closing or blocking of micropores by the N-groups. The CO2 adsorption on the ACF samples was via exothermic reactions and was a type of physical adsorption, where the CO2 adsorption occurred on heterogeneous surfaces. The CO2 uptakes at 1 atm and 25 °C on KOH-activated ACFs reached 2.74 mmole/g. This study observed that microporosity and surface oxygen functionalities were highly associated with the CO2 uptake, implying the existence of O-C coordination, accompanied with physical adsorption. Well cyclability of the adsorbents for CO2 adsorption was observed, with a performance decay of less than 5% over up to ten adsorption-desorption cycles. Full article
(This article belongs to the Special Issue Nanotechnologies for Environmental Remediation)
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