Novel Photocatalysts for Decomposition of Organic and Inorganic Pollutants

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Photocatalysis".

Deadline for manuscript submissions: closed (30 September 2022) | Viewed by 7687

Special Issue Editors


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Guest Editor
Poznan University of Technology, Faculty of Chemical Technology, Institute of Chemical Technology and Engineering, Berdychowo 4, PL-60965 Poznan, Poland
Interests: titanium dioxide; titania-based multicomponent oxide and hybrid systems; surface chemistry; inorganic pigments; photocatalysts; photocatalysis; electrode materials; environmental protection
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Co-Guest Editor
Poznan University of Technology, Faculty of Chemical Technology, Institute of Chemical Technology and Engineering, Berdychowo 4, PL-60965 Poznan, Poland
Interests: photocatalysis, nanomaterials, faceted nanoparticles, solar energy, advanced oxidation technologies
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

This Special Issue is dedicated to new trends in research focused on synthesis of novel materials used in the degradation of organic and inorganic pollutants.

The increasing concentration of industrial waste, which is a major threat to the natural environment and living organisms, imposes the necessity to develop methods for their removal or neutralization. It is well known that removal of organic and inorganic pollutants by conventional physicochemical and biochemical methods, such as adsorption, oxidation, ozonation, membrane separation, coagulation, and flocculation, is expensive and ineffective. That is why, in recent years, an increased interest in new wastewater treatment technologies which are based on heterogeneous semiconductor photocatalysis can be observed. This fact is confirmed by the growing number of literature reports regarding the technology of materials, which, when used under appropriate conditions, exhibit the ability to decompose some of the chemicals that are often hazardous to human life and animals. The photocatalytic degradation of pollutants in air and water, carried out in the presence of semiconductor materials, creates new, more effective possibilities of removing pollutants (detergents, pharmaceuticals, pesticides, organic dyes, metal ions, etc.) from the natural environment. Moreover, photocatalytic degradation process is a very promising method of removing contaminants due to low costs and mild operating conditions (temperature and pressure). It is well known that photocatalysts play a fundamental role in the photocatalysis process. There are many semiconductor materials available on the market used in the photocatalysis process; however, there is a constant drive to obtain new materials which would be highly active in the visible and near ultraviolet range, biologically inert, photostable (nonphotocorrosive), resistant to environmental conditions in which they are used, and relatively cheap. Many research centers around the world are conducting studies focused on the development of an effective production method of photocatalytic materials with unique physicochemical properties, including a specific phase composition, crystallite size or BET surface area, which determine their high and constantly growing popularity in many fields of technology. The physicochemical properties of photocatalysts, such as morphology, crystalline structure, crystallite size or textural properties, depend strictly on the selection of their synthesis method and the final thermal treatment.

The proposed scope of this Special Issue includes:

  • Synthesis of novel photocatalysts;
  • Surface treatment and enhancement of photocatalyss properties (modification/grafting/doping/immobilization),
  • Surface chemistry and functionality,
  • Physicochemical characterization of photocatalysts,
  • degradation of harmful inorganic and/or organic pollutants (for example: metal ions, detergents, pesticides, pharmaceuticals, organic dyes, etc.) using novel, synthesized photocatalysts.
Dr. Katarzyna Siwińska-Ciesielczyk
Dr. Marcin Janczarek
Guest Editors

Manuscript Submission Information

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Keywords

  • Heterogeneous photocatalysis
  • UV and visible-light active photocatalysts
  • Organic impurities
  • Inorganic pollutants
  • Surface chemistry
  • Morphological and chemical modification
  • Characterization techniques
  • Environmental protection
  • Water and air contamination

Published Papers (2 papers)

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Research

26 pages, 7512 KiB  
Article
Comparison of Ag and AgI-Modified ZnO as Heterogeneous Photocatalysts for Simulated Sunlight Driven Photodegradation of Metronidazole
by Chao Ding, Kun Fu, Yishuai Pan, Jia Liu, Huiping Deng and Jun Shi
Catalysts 2020, 10(9), 1097; https://0-doi-org.brum.beds.ac.uk/10.3390/catal10091097 - 22 Sep 2020
Cited by 22 | Viewed by 3078
Abstract
Ag and AgI-modified ZnO composites (Ag/ZnO and AgI/ZnO) were synthesized in facile ways. The photocatalysts were used for the photodegradation of metronidazole (MNZ) under the irradiation of simulated sunlight. The results of experiments showed that both Ag/ZnO and AgI/ZnO had a specific molar [...] Read more.
Ag and AgI-modified ZnO composites (Ag/ZnO and AgI/ZnO) were synthesized in facile ways. The photocatalysts were used for the photodegradation of metronidazole (MNZ) under the irradiation of simulated sunlight. The results of experiments showed that both Ag/ZnO and AgI/ZnO had a specific molar ratio to reach the best performance. Ag/ZnO performed better in the photodegradation of MNZ than AgI/ZnO under the same conditions. The reaction rate constant of AgI/ZnO was less affected by the variation of initial concentration of MNZ or pH values. The main reactive oxygen species of the photocatalytic process are OH, O2 and h+, but the free radicals which play the most critical part differ in Ag/ZnO and AgI/ZnO. Several intermediates were revealed by LC–MS/MS analysis. The stability of the photocatalysts was evaluated by a series of repeated MNZ photodegradation experiments. The results showed that AgI/ZnO had better stability than Ag/ZnO. Full article
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24 pages, 18991 KiB  
Article
Synthesis of Titanium Dioxide via Surfactant-Assisted Microwave Method for Photocatalytic and Dye-Sensitized Solar Cells Applications
by Adam Kubiak, Zuzanna Bielan, Aleksandra Bartkowiak, Elżbieta Gabała, Adam Piasecki, Maciej Zalas, Anna Zielińska-Jurek, Marcin Janczarek, Katarzyna Siwińska-Ciesielczyk and Teofil Jesionowski
Catalysts 2020, 10(5), 586; https://0-doi-org.brum.beds.ac.uk/10.3390/catal10050586 - 23 May 2020
Cited by 28 | Viewed by 3841
Abstract
In this study, titania nanoparticles were obtained using the microwave-assisted technique. Moreover, different surfactants (PEG (Mn = 400), Pluronic P123 and Triton X−100) were used during the synthesis in order to determine their impact on the crystallinity and morphology of the final [...] Read more.
In this study, titania nanoparticles were obtained using the microwave-assisted technique. Moreover, different surfactants (PEG (Mn = 400), Pluronic P123 and Triton X−100) were used during the synthesis in order to determine their impact on the crystallinity and morphology of the final products. Subsequently, techniques such as XRD, SEM and TEM (performed in high contrast and high-resolution mode), diffuse reflectance spectroscopy (DRS), low temperature N2 sorption (BET model), FTIR and TGA were carried out. Based on the crystallinity analysis of the obtained materials, it was established that the addition of surfactants results in greater (PEG and Triton X−100) or smaller (Pluronic P123) average crystallite size. The main purpose of this study was to use the synthesized nanomaterials in the photodegradation process (in the UV light range) of the model organic pollutants – phenol (20 mg/L) and etodolac (15 mg/L). Furthermore, it was also pointed out that the dye-sensitized solar cells can be a second application for the synthesized titania nanomaterials. The photo-oxidation and photovoltaic tests have shown that the titanium dioxide obtained using the surfactant-assisted microwave method is characterized not only by better photodegradation efficiency of phenol and etodolac, but also by higher photocurrent density compared to the reference titania samples—the pristine TiO2 and commercial P25. Full article
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