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Properties and Application of Alloys Prepared by Mechanical Alloying and Spark Plasma Sintering

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Manufacturing Processes and Systems".

Deadline for manuscript submissions: closed (15 July 2020) | Viewed by 4460

Special Issue Editor


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Guest Editor
Department of Metals and Corrosion Engineering, University of Chemistry and Technology, Prague, Czech Republic
Interests: powder metallurgy; high entropy alloys; intermetallics; structural properties; tribology
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Special Issue Information

Dear Colleagues,

In many cases, the properties of alloys prepared by conventional techniques seem to be lacking in their expected purposes. Therefore, more advanced techniques leading to significant microstructural refinement improving the mechanical properties are of high interest. Since the mechanical properties are closely connected with the microstructure, mostly techniques like rapid solidification or techniques employing intensive plastic deformation are suitable for this purpose. However, the rapid solidification is only capable of refining the microstructure due to a high volume fraction of stable nucleation cores.

Although microstructure refinement is beneficial for many reasons, only mechanical alloying is capable of further increasing the mechanical properties far beyond the values commonly obtained by rapid solidification. Among the formation of solid solutions a tremendous increase in the lattice defects actively also contributes to the overall strengthening. Besides, the process itself might result in a formation of finely dispersed oxidic particles, further strengthening the material at laboratory and elevated temperatures.

However, these positive characteristics are partially offset by undesirable contamination of the alloy with the material from milling elements and the jar itself. Due to this, an optimal mix between process conditions, e.g. duration, speed, ball-to-powder weight ratio, and the consequential compaction via SPS shall be established to produce materials with superior properties.

This Special Issue focuses on the materials prepared by a combination of mechanical alloying and spark plasma sintering that retains the beneficial character of the microstructure.

We kindly invite you to submit a manuscript for this Special Issue. Full papers, communications, and reviews are all welcome.

Dr. Filip Průša
Guest Editor

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Keywords

  • Mechanical alloying
  • Spark plasma sintering
  • Microstructure
  • Phase composition
  • Mechanical properties

Published Papers (2 papers)

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Research

13 pages, 4333 KiB  
Article
Bimodal Microstructure in an AlZrTi Alloy Prepared by Mechanical Milling and Spark Plasma Sintering
by Orsolya Molnárová, Jan Duchoň, Esther de Prado, Štefan Csáki, Filip Průša and Přemysl Málek
Materials 2020, 13(17), 3756; https://0-doi-org.brum.beds.ac.uk/10.3390/ma13173756 - 25 Aug 2020
Cited by 3 | Viewed by 1934
Abstract
The aim of this study was to prepare a low porosity bulk sample with a fine-grained structure from an AlZrTi alloy. Nanostructured powder particles were prepared by mechanical milling of gas atomized powder. The mechanically milled powder was consolidated using spark plasma sintering [...] Read more.
The aim of this study was to prepare a low porosity bulk sample with a fine-grained structure from an AlZrTi alloy. Nanostructured powder particles were prepared by mechanical milling of gas atomized powder. The mechanically milled powder was consolidated using spark plasma sintering technology at 475 °C for 6 min using a pressure of 100 MPa. Sintering led to a low porosity sintered sample with a bimodal microstructure. The sintered sample was revealed to be composed of non-recrystallized grains with an approximate size of about 100 nm encompassed by distinct clusters of coarser, micrometer-sized grains. Whereas the larger grains were found to be lean on second phase particles, a high density of second phase particles was found in the areas of fine grains. The microhardness of the milled powder particles was established to be 163 ± 15 HV0.01, which decreased to a slightly lower value of 137 ± 25 HV0.01 after sintering. Full article
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13 pages, 3158 KiB  
Article
Phase, Composition and Structure Changes of CoCrNi-Based Concentrated Alloys Resulting from High Temperature Oxidation
by Monika Vilémová, Hynek Hadraba, Zdeněk Weiss, František Lukáč, Štefan Csáki, Zdeněk Chlup, Jiří Matějíček and Tomáš Chráska
Materials 2020, 13(10), 2276; https://0-doi-org.brum.beds.ac.uk/10.3390/ma13102276 - 15 May 2020
Cited by 6 | Viewed by 2224
Abstract
In this work, CoCrNi, FeCoCrNi and CoCrFeMnNi concentrated alloys with a Y-Ti oxide particle dispersion were prepared by mechanical alloying and Spark Plasma Sintering. The alloy consists of an FCC Ni-based matrix with a Y-Ti oxide dispersion and additional phases of Cr23 [...] Read more.
In this work, CoCrNi, FeCoCrNi and CoCrFeMnNi concentrated alloys with a Y-Ti oxide particle dispersion were prepared by mechanical alloying and Spark Plasma Sintering. The alloy consists of an FCC Ni-based matrix with a Y-Ti oxide dispersion and additional phases of Cr23C6 and Cr2O3. The effect of Fe, Mn, and Y-Ti oxide particles on the formation of oxide scales and the composition of the adjacent CoCrNi and FeCoCrNi alloys was studied. It was found that alloys without Mn in their composition form a protective Cr2O3 scale. The Cr23C6 particles provide an alternative mechanism for balancing the chromium loss during the oxidation. Y and Ti from the oxide particles participate in the formation of the protective oxide scales. Fe promotes Y and especially Ti diffusion through the Cr2O3 scale, resulting in the formation of Ti-depleted regions in the alloy. The findings will serve for the further development of these new materials. Full article
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