Converting Plastic Waste into Useful Products

A special issue of Processes (ISSN 2227-9717). This special issue belongs to the section "Environmental and Green Processes".

Deadline for manuscript submissions: closed (10 October 2023) | Viewed by 5939

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Guest Editor
Department of Plastics Engineering, University of Massachusetts Lowell, Lowell, MA 01854, USA
Interests: chemical recycling; microplastics; biodegradable materials; ocean plastic waste; hydrothermal processing
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Special Issue Information

Dear Colleagues,

About six billion tons of plastic waste have accumulated in landfills and the natural environment over the past 50 years. The plastic produced and the plastic waste in the landfills and oceans have continued to rise exponentially over the past 50 years (Jambeck, Geyer et al. 2015). The majority (76%) of the waste was landfilled, 12% was incinerated, and 3% ended up in the oceans (Geyer, Jambeck et al. 2017, Rochman 2018). Current global recycle rates indicate that only 9% of the total plastic waste is being recycled. If the current trend continues, the planet will have more plastics than fish in the oceans by 2050 (MacArthur 2017). Huge gyres of floating plastics trash (twice the size of Texas) are already circulating in the world’s oceans (Lavers and Bond 2017). Most plastics take hundreds of years to degrade in the environment. As they degrade slowly, they release toxic particles and chemicals into the environment (Rochman, Browne et al. 2013). This pollution poses serious threats to our ecosystems, drinking water, food supply, and human health (Rochman 2018).  

To resolve this serious environmental issue, it is critical to research and develop novel methods to valorize plastic waste. In addition to generating fuels/energy, converting plastic waste into other useful products is strongly encouraged as the current fuel/energy price is volatile. Analyses such as techno-economic and lifecycle analyses would be helpful to identify valuable co-products (e.g., special chemicals) that can make the waste-to-fuel conversion economical.  

This Special Issue will concentrate on highlighting timely research studies aiming to reuse and repurpose these plastic wastes. Topics include but are not limited to:

  • Chemical recycling of plastic wastes;
  • Role of catalysts in chemical recycling;
  • Impact of pollutants on chemical recycling of plastics;
  • Physical, thermochemical, chemical, or electrochemical methods as the support of chemical recycling process.
  • Techno-economic and lifecycle analyses of chemical recycling;

Dr. Wan-Ting Chen
Guest Editor

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Keywords

  • plastic waste
  • pyrolysis
  • gasification
  • hydrothermal processes
  • chemical recycling
  • fuels
  • energy
  • monomers
  • catalysis
  • circular economy

Published Papers (2 papers)

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Research

16 pages, 1298 KiB  
Article
Effect of Acidic Hydrochar on Plastic Crude Oil Produced from Hydrothermal Liquefaction of Waste PVC
by Vahab Ghalandari, Hunter Smith, Maurizio Volpe, Antonio Messineo and Toufiq Reza
Processes 2022, 10(12), 2538; https://0-doi-org.brum.beds.ac.uk/10.3390/pr10122538 - 29 Nov 2022
Cited by 5 | Viewed by 1855
Abstract
In this study, the effect of hydrothermal liquefaction (HTL) of waste PVC was investigated in the presence of acidic hydrochar. The hydrochar was prepared by hydrothermal carbonization of pineapple waste at 250 °C and at 1 h in the presence of citric acid. [...] Read more.
In this study, the effect of hydrothermal liquefaction (HTL) of waste PVC was investigated in the presence of acidic hydrochar. The hydrochar was prepared by hydrothermal carbonization of pineapple waste at 250 °C and at 1 h in the presence of citric acid. Hydrochar was acidic, stable, and porous and contained acidic functional groups. Hydrochar was co-fed with PVC during HTL to enhance HTL conversion and quality of the plastic crude oil. HTL experiments were performed at 300–350 °C, 0.25–4 h of reaction times, and 0–20 wt% hydrochar-to-PVC ratio. The plastic crude oil was separated from the solid residue to evaluate HTL conversion and to analyze elemental compositions, boiling point distribution, alteration of chemical bonds, and chemical compositions. The results showed that acidic hydrochar enhances HTL conversion with a maximum value of 28.75 at 5 wt% hydrochar content at 350 °C and 0.5 h. Furthermore, plastic crude oils contained no chloride but contained significantly high carbon and hydrogen, resulting in a higher heating value of up to 36.43 MJ/kg. The major component of the plastic crude oil was 3, 5 dimethylphenol produced ranging from 61.4 to 86.4% (percentage of total identified area) according to gas chromatography mass spectroscopy (GCMS) data. Full article
(This article belongs to the Special Issue Converting Plastic Waste into Useful Products)
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14 pages, 2150 KiB  
Article
Statistical Optimization of Pyrolysis Process for Thermal Destruction of Plastic Waste Based on Temperature-Dependent Activation Energies and Pre-Exponential Factors
by Ali O. Alqarni, Rao Adeel Un Nabi, Faisal Althobiani, Muhammad Yasin Naz, Shazia Shukrullah, Hassan Abbas Khawaja, Mohammed A. Bou-Rabee, Mohammad E. Gommosani, Hesham Abdushkour, Muhammad Irfan and Mater H. Mahnashi
Processes 2022, 10(8), 1559; https://0-doi-org.brum.beds.ac.uk/10.3390/pr10081559 - 09 Aug 2022
Cited by 8 | Viewed by 1872
Abstract
The massive increase in disposable plastic globally can be addressed through effective recovery methods, and one of these methods is pyrolysis. R software may be used to statistically model the composition and yield of pyrolysis products, such as oil, gas, and waxes to [...] Read more.
The massive increase in disposable plastic globally can be addressed through effective recovery methods, and one of these methods is pyrolysis. R software may be used to statistically model the composition and yield of pyrolysis products, such as oil, gas, and waxes to deduce an effective pyrolysis mechanism. To date, no research reports have been documented employing the Arrhenius equation in R software to statistically forecast the kinetic rate constants for the pyrolysis of high-density plastics. We used the Arrhenius equation in R software to assume two series of activation energies (Ea) and pre-exponential factors (Ao) to statistically predict the rate constants at different temperatures to explore their impact on the final pyrolysis products. In line with this, MATLAB (R2020a) was used to predict the pyrolysis products of plastic in the temperature range of 370–410 °C. The value of the rate constant increased with the temperature by expediting the pyrolysis reaction due to the reduced frequency factor. In both assumed series of Ea and Ao, a significantly larger quantity of oil (99%) was predicted; however, the number of byproducts increased in the first series analysis compared to the second series analysis. It was revealed that an appropriate combination of Ea, Ao, and the predicted rate constants could significantly enhance the efficiency of the pyrolysis process. The major oil recovery in the first assumed series occurred at 390 °C to 400 °C, whereas the second assumed series of Ea and Ao occurred at 380 °C to 390 °C. In the second series at 390 °C to 400 °C, the predicted kinetic rate constants behaved aggressively after 120 min of the pyrolysis process. The second assumed series and anticipated rate constants at 380 °C to 390 °C can be applied commercially to improve oil production while saving energy and heat. Full article
(This article belongs to the Special Issue Converting Plastic Waste into Useful Products)
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