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Carbon Nanomaterials for Imaging and Sensing Applications

A special issue of Sensors (ISSN 1424-8220). This special issue belongs to the section "Sensor Materials".

Deadline for manuscript submissions: closed (20 November 2022) | Viewed by 4937

Special Issue Editor


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Guest Editor
Department of Chemistry and Biochemistry, Concordia University, Montreal, QC H3G 1M8, Canada
Interests: fluorescent nanomaterials; carbon dots; metallic nanoparticles; plasmonic nanomaterials; sensors; pH sensors; biosensors; nanothermometry; imaging probes; drug delivery vehicles; catalysis
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Special Issue Information

Dear Colleagues,

Over the past decade, carbon nanomaterials have emerged as sustainable and cost-effective tools at the nanoscale. These materials have garnered significant attention owing to their versatile physico-chemical and optical properties. Carbon nanomaterials have found widespread use in a myriad of applications most importantly as imaging tools and sensing probes.

Sensors is dedicated to the publication of cutting edge research in imaging and sensing applications. Given the rise in interest in carbon nanomaterials in these areas, the guest issue will fall perfectly within the scope of the journal’s mandate, i.e., the communication of top level and urgent science.

Prof. Dr. Rafik Naccache
Guest Editor

Manuscript Submission Information

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Keywords

  • carbon nanomaterials
  • carbon dots
  • carbon nanotubes
  • graphene dots
  • imaging
  • sensing
  • chemical sensing
  • biosensing

Published Papers (2 papers)

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Research

10 pages, 3327 KiB  
Article
Highly Sensitive and Selective Formaldehyde Gas Sensors Based on Polyvinylpyrrolidone/Nitrogen-Doped Double-Walled Carbon Nanotubes
by Thanattha Chobsilp, Thotsaphon Threrujirapapong, Visittapong Yordsri, Alongkot Treetong, Saowaluk Inpaeng, Karaked Tedsree, Paola Ayala, Thomas Pichler, Lei Shi and Worawut Muangrat
Sensors 2022, 22(23), 9329; https://0-doi-org.brum.beds.ac.uk/10.3390/s22239329 - 30 Nov 2022
Cited by 2 | Viewed by 1739
Abstract
A highly sensitive and selective formaldehyde sensor was successfully fabricated using hybrid materials of nitrogen-doped double-walled carbon nanotubes (N-DWCNTs) and polyvinylpyrrolidone (PVP). Double-walled carbon nanotubes (DWCNTs) and N-DWCNTs were produced by high-vacuum chemical vapor deposition using ethanol and benzylamine, respectively. Purified DWCNTs and [...] Read more.
A highly sensitive and selective formaldehyde sensor was successfully fabricated using hybrid materials of nitrogen-doped double-walled carbon nanotubes (N-DWCNTs) and polyvinylpyrrolidone (PVP). Double-walled carbon nanotubes (DWCNTs) and N-DWCNTs were produced by high-vacuum chemical vapor deposition using ethanol and benzylamine, respectively. Purified DWCNTs and N-DWCNTs were dropped separately onto the sensing substrate. PVP was then dropped onto pre-dropped DWCNT and N-DWCNTs (hereafter referred to as PVP/DWCNTs and PVP/N-DWCNTs, respectively). As-fabricated sensors were used to find 1,2-dichloroethane, dichloromethane, formaldehyde and toluene vapors in parts per million (ppm) at room temperature for detection measurement. The sensor response of N-DWCNTs, PVP/DWCNTs and PVP/N-DWCNTs sensors show a high response to formaldehyde but a low response to 1,2-dichloroethane, dichloromethane and toluene. Remarkably, PVP/N-DWCNTs sensors respond sensitively and selectively towards formaldehyde vapor, which is 15 times higher than when using DWCNTs sensors. This improvement could be attributed to the synergistic effect of the polymer swelling and nitrogen-sites in the N-DWCNTs. The limit of detection (LOD) of PVP/N-DWCNTs was 15 ppm, which is 34-fold higher than when using DWCNTs with a LOD of 506 ppm. This study demonstrated the high sensitivity and selectivity for formaldehyde-sensing applications of high-performance PVP/N-DWCNTs hybrid materials. Full article
(This article belongs to the Special Issue Carbon Nanomaterials for Imaging and Sensing Applications)
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23 pages, 8748 KiB  
Article
Extraction and Back-Extraction Behaviors of La(III), Ce(III), Pr(III), and Nd(III) Single Rare Earth and Mixed Rare Earth by TODGA
by Lina Qiu, Jiandi Li, Weiwei Zhang, Aijun Gong, Xiaotao Yuan and Yang Liu
Sensors 2021, 21(24), 8316; https://0-doi-org.brum.beds.ac.uk/10.3390/s21248316 - 12 Dec 2021
Cited by 5 | Viewed by 2625
Abstract
N,N,N′,N′-Tetraoctyl diglycolamide (TODGA), as a new extraction agent, is effective for its excellent performance and low environmental hazard, and it is very welcome for the rare earth separation process. In this paper, by controlling the extraction [...] Read more.
N,N,N′,N′-Tetraoctyl diglycolamide (TODGA), as a new extraction agent, is effective for its excellent performance and low environmental hazard, and it is very welcome for the rare earth separation process. In this paper, by controlling the extraction time, diluent type, acid type and its concentration, rare earth concentration, etc., the optimum extraction and back-extraction effects of TODGA on La(III), Ce(III), Pr(III), and Nd(III) and mixed rare earths were obtained. The experiment showed that 0.10 mol·L−1 TODGA had the best extraction effect on single rare earth under the conditions of using petroleum ether as diluent, 5 mol·L−1 nitric acid, 20 min extraction time, and 0.01 mol·L−1 rare earth. In the mixed rare earth extraction, the percentage concentrations of La(III), Ce(III), Pr(III), and Nd(III) could be achieved from 21.7%, 19.9%, 30.8%, and 22.2% at the initial stage to 90.5%, 37%, 51%, and 62% after extraction, respectively, by controlling the number of back-extraction cycles and the concentrations of hydrochloric acid and nitric acid in the back-extraction system. The TODGA–rare earth carrier system showed the best back-extraction effect when the hydrochloric acid concentration was 1 mol·L−1 and the back-extraction time was 20 min. At the same time, the mixed rare earth liquid system with low initial concentration was selected for extraction and separation of mixed rare earth. The separation effect was better, and the recovery rate was higher than that of mixed rare earth liquid system with a high initial concentration. Full article
(This article belongs to the Special Issue Carbon Nanomaterials for Imaging and Sensing Applications)
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