Magnetochemistry, Volume 7, Issue 1 (January 2021) – 16 articles
Cover Story (view full-size image): The hydrothermal reaction of lanthanide(III) nitrates and pyrimidine-4,6-dicarboxylic acid gives rise to five different families of isostructural coordination polymers (CPs). These compounds contain oxalate anions, generated as a byproduct, or nitrate anions when the synthesis is carried out in the absence of solvent, both of which participate as co-ligands. The analysis of the alternating current measurements shows field-induced SMM behavior in the Dy-based counterparts, among which higher energy barriers are achieved for those compounds containing the polyhedron that best approaches to an ideal shape. Moreover, these CPs present intense and quite long-lived photoluminescence in solid state at room temperature with characteristic emissions of the corresponding lanthanide, among which one of the Eu-based CPs shows an absolute quantum yield of 25.0%. View this paper.
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